Slow-release nitrogen fertilizer granule and preparation method thereof

A granule, nitrogen fertilizer technology, applied in nitrogen fertilizers, inorganic fertilizers, ammonium salt fertilizers, etc., can solve problems such as unfavorable crop absorption of nutrients, negative effects on soil, and paraffin is not easy to degrade, etc. good stability

Inactive Publication Date: 2019-03-08
广西金盛农联农业科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the method of producing slow-release nitrogen fertilizer mostly uses nitrogen fertilizer as the core, and coats the coating layer on the periphery of the core. The material of the coating layer is mainly polyurethane coating material. As far as the current production process is concerned, polyurethane coating The membrane has high requirements on the core, and the surface needs to be smooth to better form the coating. The current coating material is generally paraffin, but paraffin is not easy to degrade in the soil, which will have a negative impact on the soil
In addition, the density of nitrogen fertilizer is low, for example, urea is 1.335g / cm³, while the density of soil is mostly between 1.4 and 1.6 g / cm³, and the nitrogen fertilizer is wrapped with a polyurethane layer. Polyurethane is a foaming material with a low density. Nitrogen fertilizer After the polyurethane layer is wrapped, it will float on the water surface. When these fertilizers are applied, the nitrogen fertilizer cannot absorb water because the polyurethane layer is wrapped, and then the nitrogen fertilizer slow-release fertilizer will float on the soil surface, which is not conducive to the absorption of nutrients by crops. Fertilizers are easily washed away by rainwater

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A slow-release nitrogen fertilizer granule, comprising a urea granular layer, a slow-release layer and a coating layer arranged from the inside to the outside, the weight of the slow-release layer is 3% of the weight of the urea granular layer; the weight of the coating layer is urea fertilizer layer 0.5% by weight; the weight ratio of each component in the slow-release layer is: urea: sodium carboxymethylcellulose: water-based acrylic resin: gypsum = 1:2:0.5:80; the coating layer is a polyurethane coating.

[0022] The polyurethane coating is formed by curing a polyurethane film liquid, which is made by mixing isocyanate and vegetable oil polyol, and the molar ratio of the isocyanate group in the isocyanate to the hydroxyl group in the polyether polyol is 1.5:1 .

[0023] In addition, the raw material of polyurethane film liquid also comprises anti-hydrolysis agent, and the weight of anti-hydrolysis agent is 0.4% of polyurethane film liquid weight, and wherein, anti-hy...

Embodiment 2

[0028] A slow-release nitrogen fertilizer granule, comprising an ammonium sulfate granular layer, a slow-release layer and a coating layer arranged from inside to outside, the weight of the slow-release layer is 5% of the weight of the ammonium sulfate granular layer; the weight of the coating layer is 5% of the weight of the sulfuric acid 0.3% of the ammonium fertilizer layer weight; the weight ratio of each component in the slow-release layer is: ammonium sulfate: sodium carboxymethyl cellulose: water-based acrylic resin: gypsum=1:1:1:50; the coating layer is a polyurethane coating film coating.

[0029] The polyurethane coating is formed by curing a polyurethane film liquid, which is made by mixing isocyanate and vegetable oil polyol, and the molar ratio of the isocyanate group in the isocyanate to the hydroxyl group in the polyether polyol is 1.8:1 .

[0030] In addition, the raw material of polyurethane film liquid also comprises anti-hydrolysis agent, and the weight of ...

Embodiment 3

[0035]A slow-release nitrogen fertilizer granule, comprising a urea granular layer, a slow-release layer and a coating layer arranged from inside to outside, the weight of the slow-release layer is 1% of the weight of the urea granular layer; the weight of the coating layer is urea fertilizer layer 0.8% by weight; the weight ratio of each component in the slow-release layer is: urea: sodium carboxymethylcellulose: water-based acrylic resin: gypsum = 1:3:0.2:100; the coating layer is a polyurethane coating.

[0036] The polyurethane coating is formed by curing a polyurethane film liquid, which is made by mixing isocyanate and vegetable oil polyol, and the molar ratio of the isocyanate group in the isocyanate to the hydroxyl group in the polyether polyol is 1.2:1 .

[0037] In addition, the raw material of polyurethane film liquid also comprises anti-hydrolysis agent, and the weight of anti-hydrolysis agent is 0.4% of polyurethane film liquid weight, and wherein, anti-hydrolysis...

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Abstract

The invention provides a slow-release nitrogen fertilizer granule and a preparation method thereof. The slow-release nitrogen fertilizer granule comprises a nitrogen fertilizer granule layer, a slow-release layer and a coating layer which are arranged from inside to outside, wherein the weight ratio of the components in the slow-release layer, namely the ratio of a nitrogen fertilizer to a cross-linking agent to a film-forming agent to a proportion regulator is 1:0.5-5:0.2-2:20-100, and the coating layer is a polyurethane coating. According to the slow-release nitrogen fertilizer granule and the preparation method thereof, two protective layers can be formed on the outer layer of a nitrogen fertilizer core, one is the slow-release layer, the other is the coating layer, the slow-release layer can help the nitrogen fertilizer to form the granule with the smooth surface and has the slow release effect, the proportion of the nitrogen fertilizer granule can further be changed, the coating layer can help to realize the long-acting release of the nitrogen fertilizer, and the utilization rate of the fertilizer is improved.

Description

technical field [0001] The invention relates to the technical field of agricultural fertilizers, in particular to a slow-release nitrogen fertilizer granule and a preparation method thereof. Background technique [0002] Slow-release fertilizers are also known as slow-release fertilizers or controlled-release fertilizers. The nutrient-containing compounds in the fertilizer are released slowly in the soil or the nutrient release rate can be controlled to a certain extent for the continuous absorption and utilization of crops. [0003] Nitrogen fertilizer is the type of fertilizer with the largest production and usage of chemical fertilizers in the world. Appropriate amount of nitrogen fertilizer plays an important role in increasing crop yield and improving the quality of agricultural products, but the validity period of nitrogen fertilizer is short. 55 days, the validity period of phosphate fertilizer is more than 100 days, and the validity period of potassium fertilizer is...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05G3/00
CPCC05C3/00C05C9/00C05G5/30C05D3/00
Inventor 苑立志梁淑桦
Owner 广西金盛农联农业科技有限公司
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