Preparation method of gamma-Fe2O3-doped hollow carbon nanofiber membrane material

A carbon nanofiber, membrane material technology, applied in the direction of iron oxide, iron oxide/iron hydroxide, etc., can solve the problems of uneven dispersion of metal nanoparticles, unsatisfactory material morphology, complex preparation process, etc. The effect of non-variable performance and simple process

Inactive Publication Date: 2019-03-12
QIQIHAR UNIVERSITY
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  • Description
  • Claims
  • Application Information

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Problems solved by technology

For the preparation of one-dimensional metal-doped carbon-based materials, the preparation process is complicated, the material morphology is not ideal, and the difficulty of agglomeration is easy. The doped metal nanoparticles are not uniformly dispersed, and the metal doping and synthesis of one-dimensional carbon are completed in one step. The base material provides a method for preparing a metal-doped hollow carbon nanofiber membrane material with a simple process, and uses the product to prepare γ-Fe 2 o 3 Doped Carbon Nano Hollow Fiber Membrane

Method used

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  • Preparation method of gamma-Fe2O3-doped hollow carbon nanofiber membrane material
  • Preparation method of gamma-Fe2O3-doped hollow carbon nanofiber membrane material
  • Preparation method of gamma-Fe2O3-doped hollow carbon nanofiber membrane material

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Effect test

Embodiment 1

[0034] (1) Weigh 10.00g of ferrous gluconate solid with an analytical balance, put it into a small beaker, add 100.00mL of deionized water, put it in an ultrasonic cleaner for 30 minutes to let the solid particles completely dissolve and mix evenly, and place it for use;

[0035] (2) Put the dried anodized template in a self-made vacuum experimental device, and assemble the precursor prepared in step (1) into the nanopore of the template by vacuum pressure induction, and then put the experimental device in an ultrasonic cleaner Sonicate for 30 minutes, take out the assembled template with tweezers, put it in a watch glass, add the precursor every half an hour, let it stand for 4-5 hours at room temperature, and then dry the template in an oven at 50°C for 24 hours.

[0036] (3) Put the anodized aluminum template assembled with the precursor in the tube furnace N 2 Calcination under protection. Calcined at 500°C for 3h, put the calcined AAO template in 6mol L -1 The anodized ...

Embodiment 2

[0040] (1) Weigh 10.00g of ferrous gluconate solid with an analytical balance, put it into a small beaker, add 100.00mL of deionized water, put it in an ultrasonic cleaner for 30 minutes to let the solid particles completely dissolve and mix evenly, and place it for use;

[0041] (2) Put the dried anodized template in a self-made vacuum experimental device, and assemble the precursor prepared in step (1) into the nanopore of the template by vacuum pressure induction, and then put the experimental device in an ultrasonic cleaner Sonicate for 30 minutes, take out the assembled template with tweezers, put it in a watch glass, add the precursor every half an hour, let it stand for 4-5 hours at room temperature, and then dry the template in an oven at 50°C for 24 hours.

[0042] (3) Put the anodized aluminum template assembled with the precursor in the tube furnace N 2 Calcination under protection. Calcined at 600°C for 3h, put the calcined AAO template in 6mol L -1 The anodized ...

Embodiment 3

[0046] (1) Weigh 10.00g of ferrous gluconate solid with an analytical balance, put it into a small beaker, add 100.00mL of deionized water, put it in an ultrasonic cleaner for 30 minutes to let the solid particles completely dissolve and mix evenly, and place it for use;

[0047] (2) Put the dried anodized template in a self-made vacuum experimental device, and assemble the precursor prepared in step (1) into the nanopore of the template by vacuum pressure induction, and then put the experimental device in an ultrasonic cleaner Sonicate for 30 minutes, take out the assembled template with tweezers, put it in a watch glass, add the precursor every half an hour, let it stand for 4-5 hours at room temperature, and then dry the template in an oven at 50°C for 24 hours.

[0048] (3) Put the anodized aluminum template assembled with the precursor in the tube furnace N 2 Calcination under protection. Calcined at 700°C for 3h, put the calcined AAO template in 6mol L -1 The anodized ...

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Abstract

The invention relates to a preparation method of a gamma-Fe2O3-doped hollow carbon nanofiber membrane material. The method comprises the specific steps of (1) preparing a precursor; (2) preparing an anodised aluminium AAO template with the precursor; (3) calcining the anodised aluminium AAO template assembled with the precursor to obtain gamma-Fe2O3-doped hollow carbon nanofibers in a template nanochannel, and placing the calcined AAO template in a NaOH solution to remove the anodised aluminium template; (4) preparing gamma-Fe2O3-doped hollow carbon nanofibers; (5) dispersing the prepared gamma-Fe2O3-doped hollow carbon nanofibers in an ethyl alcohol solution, using a syringe for extraction, adding liquid on a bare glassy carbon electrode surface dropwise, and obtaining the gamma-Fe2O3-doped hollow carbon nanofiber membrane material after airing and film-forming are conducted at a room temperature. Metal nanometer particles are evenly dispersed in the hollow fibers, the shape is straight, and is in accordance with that of the template channel, moreover, the hollow fibers are independent from one another, and have a high degree of graphitization, and the crystal forms of the metal particles dispersed in the hollow fibers are complete.

Description

technical field [0001] The invention relates to the field of preparation of inorganic nanomaterials, in particular to a γ-Fe material uniformly dispersed inside 2 o 3 A membrane material prepared from carbon nano hollow fibers of metal particles. Background technique [0002] Carbon nanomaterials are a new type of carbon materials with good physical, chemical and mechanical properties, and have become a research hotspot in many disciplines such as physics, chemistry, and materials. Due to these properties, they have broader application prospects in more fields such as catalysis, sensing, electronics, medical treatment and energy. Among carbon nanomaterials, one-dimensional carbon nanomaterials are an important nanomaterial. The existing research work is dedicated to the preparation and mechanism research of different methods, and to explore its electrical, optical, mechanical and other properties. In the research of one-dimensional carbon nanomaterials, there are still ma...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01G49/06
CPCC01G49/06C01P2002/72C01P2002/80C01P2002/82C01P2004/03C01P2004/04C01P2004/10
Inventor 吕仁江蔡人浩李英杰高立娣秦世丽
Owner QIQIHAR UNIVERSITY
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