Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Polyethylene multi-pore plum-shaped pipe and preparation method thereof

A plum-blossom tube and polyethylene technology, which is applied in the field of polyethylene porous plum-blossom tubes and their preparation, can solve the problems of uneven flame retardant performance of plum blossom tube walls, easy agglomeration of flame retardants and the like, and achieve uniform and stable distribution and high flame retardant ability. , the effect of increasing strength

Inactive Publication Date: 2019-03-19
安庆市悦发管业有限公司
View PDF3 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The composite flame-retardant polyvinyl alcohol of the present invention has higher flame-retardant properties, and when dispersed in a macromolecular resin, the resin has a certain flame-retardant ability, and then the prepared plum blossom tube has a higher flame-retardant ability. After the fuel is added to the polyvinyl alcohol, it is bonded by the polyvinyl alcohol. At the same time, because the polyvinyl alcohol molecular chain contains hydroxyl groups, the cross-linking and fixing between each polyvinyl alcohol molecule is realized under the cross-linking action of toluene diisocyanate, and then The composite flame retardant is coated in the cross-linked network structure, even when the polyvinyl alcohol is melted, it will not detach, so that the composite flame retardant can be evenly dispersed in the resin, and the flame retardant performance in the resin can be evenly distributed Stable, solves the problem that the flame retardant is directly added in the preparation process of the existing plum blossom tube to achieve flame retardancy, but the flame retardant is easy to agglomerate, making the flame retardancy of the plum blossom tube wall uneven

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Polyethylene multi-pore plum-shaped pipe and preparation method thereof
  • Polyethylene multi-pore plum-shaped pipe and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The specific preparation process of composite flame-retardant polyvinyl alcohol is as follows:

[0026] Step 1: Add 1kg of red phosphorus into 10L of water, add 1.2kg of sodium hydroxide to it at the same time, mix well, add 20L of magnesium chloride aqueous solution with a mass fraction of 5% to it dropwise, stir while adding, and react after the addition is complete Filter after 30-50 minutes, then use ethanol and dry to obtain a composite flame retardant;

[0027] Step 2: Weigh 1 kg of low-molecular-weight polyvinyl alcohol and add it to 80°C water to dissolve it, and at the same time add 0.53 kg of the composite flame retardant prepared in step 1, then ultrasonically disperse at 80°C for 30 minutes, and then drop by drop under constant temperature conditions Add 1.05 kg of toluene diisocyanate dropwise to the reaction vessel, react for 2 hours after the addition is complete, cool down to room temperature, filter and wash to obtain composite flame-retardant polyvinyl...

Embodiment 2

[0029] The specific preparation process of composite flame-retardant polyvinyl alcohol is as follows:

[0030] Step 1: Add 1kg of red phosphorus into 10L of water, add 1.2kg of sodium hydroxide to it at the same time, mix well, add 20L of magnesium chloride aqueous solution with a mass fraction of 5% to it dropwise, stir while adding, and react after the addition is complete Filter after 30-50 minutes, then use ethanol and dry to obtain a composite flame retardant;

[0031] Step 2: Weigh 1kg of low-molecular-weight polyvinyl alcohol and add it to 80°C water to dissolve it, and at the same time add 0.58kg of the composite flame retardant prepared in step 1, then ultrasonically disperse at 80°C for 30min, and then drop by drop under constant temperature conditions Add 1.09 kg of toluene diisocyanate dropwise to the reaction container, react for 2 hours after the dropwise addition is complete, cool down to room temperature, filter and wash to obtain composite flame-retardant poly...

Embodiment 3

[0033] A preparation method of polyethylene porous plum blossom tube, the specific preparation process is as follows:

[0034] In the first step, add 6.5kg of low-density polyethylene and 5.5kg of ethylene-vinyl acetate copolymer into the twin-screw extruder, knead at 200°C for 3-5min, and then add 1.8kg of azobisisobutyronitrile , mixed at constant temperature for 1 hour, then added 2.4 kg of polyamide and 0.3 kg of functional additives, and heated to 230 ° C for 5-10 minutes; low density polyethylene and ethylene-vinyl acetate copolymer in azobisisobutyronitrile Polymerized under the action to form a macromolecular resin, which can improve the strength and toughness of the plum blossom tube; the functional additives include talcum powder, surfactants, antioxidants and wetting agents, of which talcum powder, surfactants, antioxidants and wetting agents The mass ratio of the aerosol is 12:2:3:8;

[0035] In the second step, when the temperature in the mixer in the first step ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a polyethylene multi-pore plum-shaped pipe, which comprises the following raw materials in parts by weight: 65-70 parts of low-density polyethylene, 24-28 parts of polyamide, 55-60 parts of ethylene-vinyl acetate copolymer, 40-45 parts of composite flame-retardant polyvinyl alcohol, 14-17 parts of carbon nanotubes, 5-8 parts of plasticizers, 18-21 parts of azobisisobutyronitrile and 3-5 parts of functional auxiliary agents. In the preparation process of the plum-shaped pipe, low-density polyethylene and the ethylene-vinyl acetate copolymer are polymerized under the action of azodiisobutyronitrile to form a macromolecular resin, and thus the strength and toughness of the plum-shaped pipe can be improved; and meanwhile, the composite flame retardant polyvinyl alcoholpolymer has certain bonding performance in a high-temperature molten state, and thus the carbon nanotubes can be uniformly bonded and fixed in the macromolecular resin prepared in the first step, so that the strength of the macromolecular resin is improved.

Description

technical field [0001] The invention belongs to the field of preparation of plum-blossom pipes, and relates to a polyethylene porous plum-blossom pipe and a preparation method thereof. Background technique [0002] Plum blossom tube is a kind of plum blossom-shaped communication pipe formed by PVC particles as the main material and other formulas through a unique mold, also known as honeycomb pipe. There are three types of five holes, seven holes and nine holes. Smooth, directly wearable optical cable, can save working hours, its structure is reasonable, high use value, long life, it is mainly used for communication cable sheath tube. [0003] In the existing plum-blossom pipe preparation process, the tensile strength of the plum-blossom pipe is directly increased by adding a reinforcing agent, but the dispersion performance of the reinforcing agent will be changed by melting during the preparation process of the plum-blossom pipe, and the strength of the plum-blossom pipe d...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C08L23/06C08L23/08C08L77/00C08K9/10C08K9/02C08K3/02C08K3/04C08K3/34C08J3/24C08G18/62C08G18/76
CPCC08G18/6212C08G18/7614C08J3/246C08J2323/06C08J2423/08C08J2477/00C08K3/041C08K3/34C08K9/02C08K9/10C08K2003/026C08K2201/011
Inventor 季琨章鹤桥李明
Owner 安庆市悦发管业有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products