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Novel super heat conduction ceramic film composite material and preparation method thereof

A technology of superconducting heat and new materials, which is applied in the field of wave-absorbing functional materials, can solve problems that affect the safe operation of boilers, reduce boiler thermal efficiency, corrode metal tube walls, etc., and achieve the goal of reducing furnace coking, prolonging service life, and safe boiler operation Effect

Active Publication Date: 2019-03-29
上海欧尔塔特种印刷科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The wear and corrosion of these boilers also revealed the degree of damage to the surface of the water wall of the boiler. During the operation, due to the variety and quality of the fuel, the high temperature corrosion and wear of the boiler caused the tube wall to be significantly thinned, and a tube burst accident occurred. Seriously affect the safe operation of the boiler, and the thermal efficiency of the boiler will also be significantly reduced after long-term use, especially when the flue gas with a large concentration directly washes the tube wall, the pyrite powder in the fuel will stick together with the unburned fuel. On the pipe wall, it is decomposed by heat to generate elemental sulfur and iron sulfide. Hydrogen sulfide and sulfur dioxide adhere to the pipe wall, which will sulfide the metal pipe wall and severely corrode the metal pipe wall.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A new superconducting thermal ceramic film composite material, prepared from the following raw materials in parts by weight: 22 parts of instant sodium silicate, 30 parts of crystalline silicon, 5 parts of nano-magnesia, 15 parts of carbon fiber, 3 parts of boron fiber, silicon 3 parts of acid fiber, 10 parts of alumina powder, 25 parts of deionized water.

[0021] The particle size of the alumina powder is 150-180 mesh.

[0022] The preparation method of the above-mentioned superconducting thermal ceramic film composite new material comprises the following steps:

[0023] (1) Add deionized water to instant sodium silicate to dilute, stir at 75°C to obtain a transparent solution, dilute to 60% concentration, then add nano-magnesia and alumina powder, and stir until a clear solution is obtained;

[0024] (2) Add crystalline silicon, carbon fiber, boron fiber, and silicic acid fiber into the above clarified solution, and stir evenly to obtain a new composite material of ...

Embodiment 2

[0030] A new superconducting ceramic film composite material, prepared from the following raw materials in parts by weight: 20 parts of instant sodium silicate, 32 parts of crystalline silicon, 8 parts of nano-magnesium oxide, 17 parts of carbon fiber, 5 parts of boron fiber, silicon 5 parts of acid fiber, 12 parts of alumina powder, 23 parts of deionized water.

[0031] The particle size of the alumina powder is 150-180 mesh.

[0032] The preparation method of the above-mentioned superconducting thermal ceramic film composite new material comprises the following steps:

[0033] (1) Add deionized water to instant sodium silicate to dilute, stir at 75°C to obtain a transparent solution, dilute to 60% concentration, then add nano-magnesia and alumina powder, and stir until a clear solution is obtained;

[0034] (2) Add crystalline silicon, carbon fiber, boron fiber, and silicic acid fiber into the above clarified solution, and stir evenly to obtain a new composite material of s...

Embodiment 3

[0037] A new superconducting thermal ceramic film composite material, prepared from the following raw materials in parts by weight: 25 parts of instant sodium silicate, 28 parts of crystalline silicon, 4 parts of nano-magnesium oxide, 13 parts of carbon fiber, 2 parts of boron fiber, silicon 2 parts of acid fiber, 8 parts of alumina powder, 28 parts of deionized water.

[0038] The particle size of the alumina powder is 150-180 mesh.

[0039] The preparation method of the above-mentioned superconducting thermal ceramic film composite new material comprises the following steps:

[0040] (1) Add deionized water to the instant sodium silicate for dilution, stir at 75°C to obtain a transparent solution, dilute to a concentration of 60%, then add nano-magnesia and alumina powder, and stir until a clear solution is obtained;

[0041] (2) Add crystalline silicon, carbon fiber, boron fiber, and silicic acid fiber into the above clarified solution, and stir evenly to obtain a new comp...

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Abstract

The invention discloses a novel super heat conduction ceramic film composite material and a preparation method thereof, and belongs to the technical field of wave absorption function materials. The composite material is prepared from the following raw materials in parts by weight: 20 to 25 parts of fast soluble sodium silicate, 28 to 32 parts of crystal silicon, 4 to 8 parts of nanometer magnesia,13 to 17 parts of carbon fiber, 2 to 5 parts of boron fiber, 2 to 5 parts of silicic acid fiber, 8 to 12 parts of aluminum oxide powder and 23 to 28 parts of deionized water. The obtained material covers the surface of metal to isolate the metal from external media so as to block external high-temperature oxygen and corrosive substances; the metal pipe wall is effectively protected; the wave absorption performance is obvious; infrared radiation is generated; a good energy saving effect is achieved; the material is applied to the field of boilers; the energy is saved; the environment is protected; the operation of the boiler is safe; the boiler friction pipe blasting is reduced; the boiler hearth coking is reduced; the service life of the boiler is prolonged.

Description

technical field [0001] The invention relates to the technical field of wave-absorbing functional materials, in particular to a new superconducting heat-conducting porcelain film composite material and a preparation method thereof. Background technique [0002] With the continuous development of society, the types of boilers are also increasing rapidly, such as coal-fired boilers in power plants, fluidized bed boilers, cracking furnaces in Sinopec, steam injection boilers in PetroChina, vacuum heating furnaces, etc. The wear and corrosion of these boilers also revealed the degree of damage to the surface of the water wall of the boiler. During the operation, due to the variety and quality of the fuel, the high temperature corrosion and wear of the boiler caused the tube wall to be significantly thinned, and a tube burst accident occurred. Seriously affect the safe operation of the boiler, and the thermal efficiency of the boiler will also be significantly reduced after long-t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/26
CPCC04B28/26C04B2111/763C04B2111/00525C04B22/02C04B22/066C04B14/386C04B14/38C04B14/303
Inventor 张帅韩锋
Owner 上海欧尔塔特种印刷科技有限公司
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