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Acid and alkali resistant latex glove and preparation process thereof

A latex glove and a preparation technology, applied to gloves, other household utensils, household components, etc., can solve the problems of poor compactness, poor corrosion resistance, solvent leakage, etc., achieve good compactness, excellent permeability resistance, and improve durability The effect of acidity and alkalinity

Active Publication Date: 2019-04-16
BEIJING REAGENT LATEX PRODS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Conventional nitrile rubber gloves produced in the prior art contain substances such as sulfur and zinc oxide, and need to undergo high-temperature vulcanization molding to produce small defects. When exposed to chemical solvents and other substances, these defects are likely to cause the risk of solvent leakage
In addition, conventional nitrile rubber gloves have poor compactness and poor corrosion resistance, and these defects easily cause the risk of solvent leakage

Method used

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  • Acid and alkali resistant latex glove and preparation process thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Preparation of surfactant aqueous solution: 1Kg of anionic surfactant Dowfax2A1 and 9Kg of soft water were uniformly mixed to obtain surfactant aqueous solution.

[0038] Preparation of sodium aluminate aqueous solution: 1.58Kg of sodium chlorate, 4.85Kg of ammonia water with a concentration of 26% by weight and 23.57Kg of soft water were uniformly mixed to obtain sodium aluminate aqueous solution.

[0039] Preparation of coagulant aqueous solution: Soak 383.84Kg of calcium nitrate in 1472.116Kg of soft water until completely melted, raise the temperature to 85°C under stirring and keep it warm for 30 minutes, then drop to normal temperature, add 120Kg of light calcium and 8Kg of 810 epoxy resin curing agent and Sunmide315 polyamide epoxy curing agent 16Kg, stirred for 24 hours to obtain a coagulant aqueous solution.

[0040] Preparation of vulcanization accelerator dispersion: the mixture comprising zinc dibutyl dithiocarbamate 175Kg, potassium hydroxide 3.5Kg, sodium ...

Embodiment 2

[0051] Preparation of surfactant aqueous solution: 1Kg of anionic surfactant Dowfax2A1 and 8Kg of soft water were uniformly mixed to obtain surfactant aqueous solution.

[0052] Preparation of sodium aluminate aqueous solution: 1.5Kg of sodium chlorate, 4.9Kg of ammonia water with a concentration of 25.95% by weight and 23Kg of soft water were uniformly mixed to obtain sodium aluminate aqueous solution.

[0053] Preparation of coagulant aqueous solution: Soak 380Kg of calcium nitrate in 1475Kg of soft water until completely melted, raise the temperature to 90°C with stirring and keep it warm for 20 minutes, then drop to room temperature, add 123Kg of light calcium, 7Kg of 810 epoxy resin curing agent and Sunmide315 14Kg of polyamide epoxy curing agent was stirred for 20 hours to obtain a coagulant aqueous solution.

[0054] Preparation of vulcanization accelerator dispersion: the mixture comprising 170Kg of zinc dibutyldithiocarbamate, 4Kg of potassium hydroxide, 25Kg of sodiu...

Embodiment 3

[0065] Preparation of surfactant aqueous solution: 2Kg of anionic surfactant Dowfax2A1 and 9Kg of soft water were uniformly mixed to obtain surfactant aqueous solution.

[0066] Preparation of sodium aluminate aqueous solution: 1.6Kg of sodium chlorate, 4.8Kg of ammonia water with a concentration of 26.05% by weight and 24Kg of soft water were uniformly mixed to obtain sodium aluminate aqueous solution.

[0067] Preparation of coagulant aqueous solution: Soak 385Kg of calcium nitrate in 1470Kg of soft water until completely melted, raise the temperature to 80°C with stirring and keep it warm for 40 minutes, then drop to normal temperature, add 117Kg of light calcium, 9Kg of 810 epoxy resin curing agent and Sunmide315 18Kg of polyamide epoxy curing agent was stirred for 30 hours to obtain a coagulant aqueous solution.

[0068] Preparation of vulcanization accelerator dispersion: the mixture comprising 180Kg of zinc dibutyldithiocarbamate, 3Kg of potassium hydroxide, 21Kg of sod...

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PUM

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Abstract

The invention relates to a preparation process of acid and alkali resistant latex glove, which comprises the following steps of: immersing a pretreated hand mold into latex at a temperature of 25-27 DEG C, shaping the soaked hand mold at a temperature of 50-65 DEG C to form an adhesive film, leaching the hand mold with the adhesive film by using ammonia water with a temperature of 23-25 DEG C anda pH value of 9-10, and then drying at a temperature of 55-70 DEG C; vulcanizing at 75-90 DEG C, sequentially soaking the hand mold in cold water at a temperature not higher than 35 DEG C, chlorine water at a temperature not higher than 45 DEG C, and a potassium hydroxide aqueous solution at a temperature not higher than 45 DEG C and a pH value of 8-10, and demoulding to obtain the acid and alkaliresistant latex glove. The invention also relates to an acid and alkali resistant latex glove which is prepared by the preparation process of the acid and alkali resistant latex glove. The acid and alkali resistant latex glove has good compactness and still has excellent permeability resistance after being soaked in strong acid and strong alkali.

Description

technical field [0001] The invention relates to a heavy industry glove, more specifically, it relates to an acid and alkali resistant latex glove and a preparation process thereof. Background technique [0002] Heavy industry gloves refer to a kind of labor protection gloves used in high-intensity labor or environments with special needs. They are generally used in heavy industries, such as petrochemical, mining, etc., and will also be used in some environments with special needs. For example: laboratories, hospitals, etc. The glove emphasizes the comprehensive protection of the hands, so while it needs to have good wear resistance, tear resistance, penetration resistance and puncture resistance, it also has higher requirements for oil resistance and chemical resistance. [0003] The common practice of existing nitrile latex gloves is mainly to use single nitrile rubber latex as raw material, carry out pre-vulcanization by adding a certain amount of pre-vulcanizing agent, u...

Claims

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Application Information

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IPC IPC(8): C08L9/02C08L83/08C08K13/06C08K9/04C08K9/02C08K3/26C08K3/22C08K3/24C08G77/24C08G77/06A41D19/015B29C41/14
CPCA41D19/0055B29C41/14B29L2031/4864C08G77/06C08G77/24C08K2003/2241C08K2003/2296C08K2003/265C08L9/02C08L2205/03C08L83/08C08K13/06C08K9/04C08K9/02C08K3/26C08K3/22C08K3/24
Inventor 侯福新孙喜民高健刘强
Owner BEIJING REAGENT LATEX PRODS
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