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High-temperature hydrothermal method for improving biogas generated by landscape wastes

A technology of garden waste and high-temperature water heating, applied in the field of high-temperature water heating, can solve the problems of low biochemical conversion efficiency of biomass, achieve good sustainability, good biocompatibility, and improve fermentation efficiency

Active Publication Date: 2019-04-16
GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to provide a high-temperature hydrothermal method for increasing the gas produced by garden waste, which can remove lignin to the greatest extent while retaining fermentable sugars such as cellulose and hemicellulose, and does not require detoxification And other follow-up treatment, significantly improve the fermentation efficiency of its biogas, and then realize the efficient energy conversion of garden waste, solve the problem of low biochemical conversion efficiency of biomass in the existing technology, and the problem of detoxification in follow-up treatment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] 1) Using water as the reaction medium, add the branches and leaves of Safflower safflower as the substrate in the high-pressure reactor, so that the substrate mass concentration is 5%, react at 180°C for 30min, and then follow the water mass ratio of 2:1 Add choline chloride to prepare a new reaction solution, continue to react at 180°C for 40 minutes to obtain a solid-liquid mixture, wherein the lignin removal rate of the substrate raw material is 70%, the cellulose retention rate is 95%, and the hemicellulose derivative Sugar yield was 85%.

[0019] 2) The solid-liquid mixture obtained in step 1) was directly inserted into the anaerobic fermentation strain according to the method reported in the literature (Bioresour.Technol.2018, 55, 205-212), and fermented for 30 days to obtain biogas. Compared to untreated feedstock, its total biogas production is increased by about 380%;

Embodiment 2

[0021] 1) Using water as the reaction medium, add the mixed garden waste of Phyllostachys pubescens and Taiwan grass as the substrate in the high-pressure reactor, so that the substrate mass concentration is 10%, react at 180°C for 60min, and then according to the mass ratio with water Add choline chloride at a ratio of 1:1 to obtain a new reaction solution, continue to react at 160°C for 60 minutes to obtain a solid-liquid mixture, wherein the lignin removal rate of the substrate raw material is 65%, the cellulose retention rate is 90%, half The cellulose-derived sugar yield was 80%.

[0022] 2) The solid-liquid mixture obtained in step 1) was directly inserted into the anaerobic fermentation strain according to the method reported in the literature (Bioresour.Technol.2018, 55, 205-212), and fermented for 30 days to obtain biogas. Compared with untreated feedstock, its total biogas production is increased by about 400%.

Embodiment 3

[0024] 1) water and choline chloride are mixed according to the mass ratio of 4:1 to prepare a reaction liquid, and mixed garden wastes such as sunflower leaves, eucalyptus branches, and safflower safflower branches are added in the autoclave as substrates, The raw materials make the substrate mass concentration 20%, react at 220°C for 30min, pour off the liquid, add the same amount of pure water, and continue to react at 200°C for 30min to obtain a solid-liquid mixture, wherein the lignin removal rate of the substrate raw material It is 80%, the cellulose retention rate is 80%, and the hemicellulose-derived sugar yield is 75%.

[0025] 2) The solid-liquid mixture obtained in step 1) was directly inserted into the anaerobic fermentation strain according to the method reported in the literature (Bioresour.Technol.2018, 55, 205-212), and fermented for 30 days to obtain biogas. Compared with untreated feedstock, its total biogas production is increased by about 450%.

[0026] Th...

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PUM

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Abstract

The invention discloses a high-temperature hydrothermal method for improving biogas generated by landscape wastes. The method comprises the steps that water and choline chloride are sequentially addedto a reactor to be mixed to prepare reaction liquid, landscape waste raw materials or / and other lignocellulose mixture is added to be a substrate, and a solid-liquid mixture is obtained by performingreaction for 1-2 hours at 160-220 DEG C; an anaerobic fermentation strain is directly inoculated into the solid-liquid mixture to perform biogas fermentation to obtain biogas. According to the method, lignocellulose is removed to the maximum extent under the situation that fermentable sugars of cellulose, hemicelluloses and the like are preserved, subsequent processing of detoxification and the like are not needed to significantly improve the fermentation efficiency of the biogas to achieve high-efficient energy conversion of the landscape wastes, the problems of poor biomass biochemical conversion efficiency and the need of detoxification in subsequent processing in the prior art are solved, and the method has better sustainability and higher application potential compared with other pre-processing means.

Description

Technical field: [0001] The invention relates to the technical field of biomass conversion, in particular to a high-temperature hydrothermal method for increasing gas produced by garden waste. Background technique: [0002] Garden waste refers to green waste such as branches and leaves produced by artificial pruning and natural effects such as seasonal changes and typhoons. With the continuous advancement of my country's urbanization and urban greening construction, landscaping waste is gradually increasing. According to statistics, only Guangdong Province produces 12 million tons per year. Common treatment and reuse methods include making soil improvement substrates (CN102585836A, CN106365824A), composting (CN102295478A, CN105820011A), fiberboard (CN107323059A), biochar (CN107555414A) and the like. Garden waste has a typical lignocellulosic biomass structure, and its main components are cellulose, hemicellulose and lignin, so it can be used as a raw material for bioenergy ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C12P5/02
CPCC12P5/023Y02E50/30
Inventor 余强孔晓英孙永明李连华
Owner GUANGZHOU INST OF ENERGY CONVERSION - CHINESE ACAD OF SCI