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Composite current collector, preparation method thereof, electrode and lithium ion battery

A technology of lithium-ion batteries and current collectors, applied in the direction of electrode carriers/collectors, battery electrodes, secondary batteries, etc., can solve problems such as explosion, and achieve the effect of reducing battery internal resistance and good battery capacity stability

Active Publication Date: 2019-04-19
SOUNDON NEW ENERGY TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current collectors of lithium-ion batteries are mostly copper foil and aluminum foil, and the battery capacity stability of lithium-ion batteries based on this needs to be improved; in addition, the current lithium-ion batteries are explosive in high-temperature environments, so their The ambient storage temperature is best below 35°C

Method used

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  • Composite current collector, preparation method thereof, electrode and lithium ion battery
  • Composite current collector, preparation method thereof, electrode and lithium ion battery
  • Composite current collector, preparation method thereof, electrode and lithium ion battery

Examples

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preparation example Construction

[0030] One embodiment of the present invention provides a method for preparing any one of the above composite current collectors, comprising the following steps S1-S2.

[0031] Step S1: mixing nano-bismuth, nano-bismuth oxide, a binder and a conductive agent in a solvent to obtain a slurry.

[0032] The raw materials are provided according to the composition of the surface coating of a composite current collector as described above. For example, in one of the embodiments, the mass ratio of nano-bismuth, nano-bismuth oxide, binder and conductive agent is (6-8):(0.5-1.5):(0.1-0.5):(0.1-0.5).

[0033] Among them, the solvent is preferably an organic solvent, such as N-methylpyrrolidone (NMP), DMF, ethanol, ethylene glycol, methanol, isopropanol, and the like.

[0034] It can be understood that nanobismuth can be obtained through the reaction of soluble bismuth salt and reducing agent. Specifically, for example, bismuth nitrate reacts with sodium borohydride to obtain nanobismut...

Embodiment 1

[0048] Embodiment 1 Preparation of Composite Current Collector

[0049] (1) Prepare 0.01M bismuth nitrate solution and 0.01M sodium borohydride solution respectively;

[0050] (2) According to the molar ratio of sodium borohydride and bismuth nitrate 3:1, sodium borohydride was added dropwise to the bismuth nitrate solution, and after the dropwise addition was completed, stirring was continued for 5 minutes at a speed of 1000 rpm. After the product was washed with deionized water, Dry in a drying oven at 100°C to constant weight to prepare nanobismuth.

[0051] (3) Mixing nano-bismuth, nano-bismuth oxide, a binder, and a conductive agent in a solvent at a mass ratio of 8.5:1.0:0.4:0.1 to obtain a slurry containing nano-bismuth and nano-bismuth oxide. The slurry was then coated on the surface of the copper foil, and dried in an oven at 90° C. to a constant weight to obtain a composite current collector. Wherein the coating thickness is less than 2 microns. Wherein, the binde...

Embodiment 2

[0052] Example 2 The steps for preparing the composite current collector are basically the same as in Example 1, except that the mass ratio of nanobismuth, nanobismuth oxide, binder, and conductive agent in step (3) is 6:1.5:0.5:0.5 ; The binder is styrene-butadiene latex and sodium carboxymethyl cellulose, and the conductive agent is acetylene black.

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Abstract

The invention relates to a composite current collector, a preparation method thereof, an electrode and a lithium ion battery. The composite current collector comprises a current collector and a surface coating formed on the current collector, and the surface coating comprises nano bismuth, nano cerium oxide, binder and conductive agent. The nano ruthenium in the surface coating of the composite current collector is of the order of nanometers, so the contact area of the active material in the current collector and the active material layer, thereby reducing the internal resistance of the interface, and improving the stability of the battery capacity. The melting point of the nano bismuth is low, so the nano bismuth can be melted when the lithium ion battery is heated, and the contact between the active materials and the current collector is cut off, thereby cutting off the conductive path to avoid further thermal runaway. The compatibility of nano bismuth and nano bismuth oxide is good.The nano bismuth oxide with the flame retardant effect in the composite current collector can cooperate with the nano bismuth so as to achieve the functions of inhibiting the combustion of the battery and preventing explosion of the lithium ion battery when the heating temperature of the lithium ion battery increases, so the safety performance of the battery is further improved.

Description

technical field [0001] The invention relates to the technical field of batteries, and specifically relates to a composite current collector, a preparation method thereof, an electrode and a lithium ion battery. Background technique [0002] With the rapid development of the new energy industry, the requirements for electrochemical equipment are also increasing. On the one hand, it requires high energy density, fast charge and discharge and other electrochemical performance; on the other hand, it pursues high safety performance. The current collector is an important part of the lithium-ion battery, which refers to the mechanical carrier that carries the positive or negative active materials, and can provide migration channels for electrons. The current collectors of lithium-ion batteries are mostly copper foil and aluminum foil, and the battery capacity stability of lithium-ion batteries based on this needs to be improved; in addition, the current lithium-ion batteries are e...

Claims

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Application Information

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IPC IPC(8): H01M4/66H01M10/0525H01M10/42
CPCH01M4/661H01M4/667H01M10/0525H01M10/4235Y02E60/10
Inventor 蒋海霞王雁生
Owner SOUNDON NEW ENERGY TECH CO LTD