Composite current collector, preparation method thereof, electrode and lithium ion battery
A technology of lithium-ion batteries and current collectors, applied in the direction of electrode carriers/collectors, battery electrodes, secondary batteries, etc., can solve problems such as explosion, and achieve the effect of reducing battery internal resistance and good battery capacity stability
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[0030] One embodiment of the present invention provides a method for preparing any one of the above composite current collectors, comprising the following steps S1-S2.
[0031] Step S1: mixing nano-bismuth, nano-bismuth oxide, a binder and a conductive agent in a solvent to obtain a slurry.
[0032] The raw materials are provided according to the composition of the surface coating of a composite current collector as described above. For example, in one of the embodiments, the mass ratio of nano-bismuth, nano-bismuth oxide, binder and conductive agent is (6-8):(0.5-1.5):(0.1-0.5):(0.1-0.5).
[0033] Among them, the solvent is preferably an organic solvent, such as N-methylpyrrolidone (NMP), DMF, ethanol, ethylene glycol, methanol, isopropanol, and the like.
[0034] It can be understood that nanobismuth can be obtained through the reaction of soluble bismuth salt and reducing agent. Specifically, for example, bismuth nitrate reacts with sodium borohydride to obtain nanobismut...
Embodiment 1
[0048] Embodiment 1 Preparation of Composite Current Collector
[0049] (1) Prepare 0.01M bismuth nitrate solution and 0.01M sodium borohydride solution respectively;
[0050] (2) According to the molar ratio of sodium borohydride and bismuth nitrate 3:1, sodium borohydride was added dropwise to the bismuth nitrate solution, and after the dropwise addition was completed, stirring was continued for 5 minutes at a speed of 1000 rpm. After the product was washed with deionized water, Dry in a drying oven at 100°C to constant weight to prepare nanobismuth.
[0051] (3) Mixing nano-bismuth, nano-bismuth oxide, a binder, and a conductive agent in a solvent at a mass ratio of 8.5:1.0:0.4:0.1 to obtain a slurry containing nano-bismuth and nano-bismuth oxide. The slurry was then coated on the surface of the copper foil, and dried in an oven at 90° C. to a constant weight to obtain a composite current collector. Wherein the coating thickness is less than 2 microns. Wherein, the binde...
Embodiment 2
[0052] Example 2 The steps for preparing the composite current collector are basically the same as in Example 1, except that the mass ratio of nanobismuth, nanobismuth oxide, binder, and conductive agent in step (3) is 6:1.5:0.5:0.5 ; The binder is styrene-butadiene latex and sodium carboxymethyl cellulose, and the conductive agent is acetylene black.
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