Composite gel polymer electrolyte preparation method and lithium ion battery

A gel polymer and lithium-ion battery technology, applied in secondary batteries, circuits, electrical components, etc., can solve problems such as poor mechanical properties, low room temperature ionic conductivity, and application limitations, and achieve low cost and room temperature ionic conductivity The effect of high efficiency and wide electrochemical voltage window

Inactive Publication Date: 2019-05-14
SHENZHEN GPC ENERGY GRP CO LTD
View PDF13 Cites 16 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the gel electrolyte membrane prepared by this method has a high voltage window (above 5.0 V), its room temperature ionic conductivity is low and its mechanical properties are poor, which makes the application of gel polymer electrolyte in lithium-ion batteries very limited. big limit

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Composite gel polymer electrolyte preparation method and lithium ion battery
  • Composite gel polymer electrolyte preparation method and lithium ion battery
  • Composite gel polymer electrolyte preparation method and lithium ion battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0039] The specific content of the present invention will be further elaborated below in conjunction with the drawings and specific embodiments.

[0040] A kind of composite gel polymer electrolyte, its preparation method comprises the following steps:

[0041] (1) Pretreat the polymer matrix and completely dissolve it in an organic solvent;

[0042] (2) Adding a crosslinking agent to the solution obtained in step (1) for dissolution and dispersion;

[0043] (3) adding inorganic fillers to the solution obtained in step (2) and dispersing;

[0044] (4) adding lithium salt to the solution obtained in step (3) for dissolution to obtain a mixed glue;

[0045] (5) The organic solvent in the mixed glue obtained in step (4) is volatilized and dried on the substrate to form a film, and a composite gel polymer electrolyte is prepared.

[0046] In the step (1), the polymer matrix is ​​polyvinylidene fluoride-hexafluoropropylene (PVDF-HFP), polyacrylonitrile (PAN), polymethyl methacry...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
thicknessaaaaaaaaaa
pore sizeaaaaaaaaaa
Login to view more

Abstract

The invention discloses a composite gel polymer electrolyte preparation method and a lithium ion battery, wherein the preparation process of the composite gel polymer electrolyte comprises the steps of dissolution of a polymer, introduction of a cross-linking agent, dispersion of an inorganic filler, dissolution of a lithium salt, and slurry casting and film forming. By virtue of the prepared composite gel polymer electrolyte, the problems of relatively high solvent mobility and volatility, relatively poor electrochemical stability and the thermal stability, low ionic conductivity, low mechanical strength, poor electrolyte and electrode interface stability and the like of the traditional gel electrolyte are effectively improved; the composite gel polymer electrolyte has the advantages of high ionic conductivity at the room temperature, wide electrochemical voltage window, high mechanical performance and relatively high adhesion of the electrolyte to the positive electrode and the negative electrode, so that the safety performance and the electrochemical performance of the lithium ion battery are greatly improved; meanwhile, the preparation method is simple and rapid, and the cost is low; and the assembled lithium ion battery is light and thin in appearance and excellent in electrochemical performance, and has a very wide market application prospect.

Description

technical field [0001] The invention belongs to the technical field of polymer lithium ion batteries, and in particular relates to a preparation method of a composite gel polymer electrolyte and a lithium ion battery thereof. Background technique [0002] Since lithium-ion batteries have the advantages of high energy density, high output voltage, long cycle life, and low environmental pollution, since the industrialization of lithium-ion batteries in the 1990s, lithium-ion batteries have not only been used in portable electronic products and electric vehicles These fields have been widely researched and applied, and play an important role in promoting the adjustment of energy structure and the sustainable development of energy and environment. At present, lithium-ion batteries have become the standard power supply of mobile electronic devices such as mobile phones and notebook computers, and have been widely used in the fields of electric vehicles and hybrid electric vehicle...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/0525H01M10/0565
CPCY02E60/10
Inventor 李胜焦玉志李国敏胡李
Owner SHENZHEN GPC ENERGY GRP CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products