Method for preparing gasoline blending composition from Fischer-Tropsch synthesis oil-phase product

A Fischer-Tropsch synthesis and product technology, which is used in the preparation of liquid hydrocarbon mixtures, the treatment of hydrocarbon oils, and the petroleum industry, and can solve the problems of difficulty in obtaining gasoline blending components with reasonable properties and inability to inherit aromatic components.

Active Publication Date: 2019-05-17
SYNFUELS CHINA TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, under the traditional catalytic cracking reaction conditions where the oil agent is exposed to high temperature, the cracking reaction of the Fischer-Tropsch synthesis oil phase product can only obtain a large amount of gas and olefins (as described in the above-m

Method used

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  • Method for preparing gasoline blending composition from Fischer-Tropsch synthesis oil-phase product
  • Method for preparing gasoline blending composition from Fischer-Tropsch synthesis oil-phase product
  • Method for preparing gasoline blending composition from Fischer-Tropsch synthesis oil-phase product

Examples

Experimental program
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Effect test

Embodiment 1

[0076] In this example, Fischer-Tropsch synthesis products greater than 350°C are used as raw materials, and the attached figure 1The fluidized bed process shown performs catalytic conversion to produce gasoline blending components. The Fischer-Tropsch synthesis product greater than 350°C is used as raw material oil 2 and preheated to 270°C, atomized by water vapor (that is, the atomization medium 3) and then sprayed upward into the fluidized bed reactor 1 for reaction, and the downstream A cracking reaction occurs when the low-activity catalyst mainly containing carbon-containing unborn catalyst contacts, and the reaction product continues to ascend, and then contacts with a regenerated catalyst-based high-activity catalyst to undergo an aromatization reaction, and the reaction product continues to ascend to the reaction settler 19 to complete After the oil agent is separated, it goes out of the reaction device and enters the fractionation system; the carbon-containing cataly...

Embodiment 2

[0078] In this embodiment, the whole cut Fischer-Tropsch synthesis oil phase product and methanol are used as raw materials, and the attached figure 1 The fluidized bed process shown performs catalytic conversion to produce gasoline blending components. After preheating the full fraction Fischer-Tropsch synthesis oil phase product to 240°C, feed it from the tube layer of the oil inlet nozzle of the fluidized bed reactor 1, and feed the vaporized methanol from the shell layer of the oil inlet nozzle of the fluidized bed reactor 1, Raw oil and vaporized methanol are mixed at the nozzle port to form small mist droplets that are injected into the fluidized bed reactor 1 at a high speed for reaction ( figure 1 The reaction section and the stripping section are connected, the dividing point is at the oil inlet nozzle, the reaction zone is above the nozzle, and the stripping zone is below the nozzle), the reaction pressure is 0.15MPa, the reaction temperature is 450°C, and the mass r...

Embodiment 3

[0080] In this example, the Fischer-Tropsch synthesis product at a temperature greater than 280°C is used as the raw material, and the liquefied gas of the cracked product is coupled to the refining process. figure 2 The fluidized bed process shown performs catalytic conversion to produce gasoline blending components. After preheating the Fischer-Tropsch synthesis product greater than 280°C to 240°C, after steam atomization, the cracking reaction occurs first in the lower fluidized bed reaction zone with the low-activity spent catalyst recycled from the spent agent circulation standpipe 11, The cracked product and the spent agent go up into the upper fluidized bed reaction zone, and then mix with the highly active regenerated catalyst sent by the regeneration inclined pipe 18 to undergo aromatization reaction, and the reaction product and catalyst continue to go up to the reaction settler 7 to complete the oil agent After separation, it enters the fractionation system, and th...

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Abstract

The invention discloses a method for preparing a gasoline blending composition from a Fischer-Tropsch synthesis oil-phase product. The method is characterized by taking the Fischer-Tropsch synthesis oil-phase product as a main raw material, injecting the Fischer-Tropsch synthesis oil-phase product into a fluidized bed reactor after preheating and atomizing the Fischer-Tropsch synthesis oil-phase product, enabling the preheated and atomized Fischer-Tropsch synthesis oil-phase product to be in contact with a low-activity catalyst to carry out cracking reaction, then carrying out aromatization reaction with a high-activity catalyst at a high temperature, and fractionating a generated oil-phase product, thus obtaining high-octane gasoline. The technology disclosed by the invention has the characteristics that a main active component of a catalyst is a molecular sieve with good aromatization performance, chain-like hydrocarbon molecules in the Fischer-Tropsch synthesis oil-phase product arefirstly subjected to the cracking reaction at a lower temperature so as to generate an olefin intermediate, the low temperature is beneficial for reducing the productivity of primary cracking gas, and the yield of gasoline is ensured; then the olefin intermediate is subjected to the aromatization reaction at the high temperature, so that the gasoline quality of a product can be improved; the technology ahs the advantages that the technology is simple, the gasoline yield of the product is high, the octane value is high, and the aromatic hydrocarbon content is high.

Description

technical field [0001] The invention belongs to the field of petrochemical industry and relates to a method for preparing gasoline blending components by catalytic conversion of Fischer-Tropsch synthesis oil phase products. Background technique [0002] With the sustained and rapid development of my country's social economy, the people's economic conditions have been greatly improved, and the number of automobiles is increasing day by day, forming a huge demand for oil products. However, my country's crude oil supply capacity is increasingly stretched, and crude oil imports are increasing year by year. Restricted by the quality of crude oil from self-owned oilfields and import channels, the crude oil processed in my country is becoming increasingly heavy and highly vulcanized. The increase in the use of automobiles has led to increasingly serious environmental pollution problems in our country. The high sulfur content and high olefin content in commercial vehicle gasoline ...

Claims

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Application Information

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IPC IPC(8): C10G57/00C10G3/00
CPCY02P30/20
Inventor 郝坤陶智超徐智郭艳尹烁姜大伟高军虎张丽杨勇李永旺
Owner SYNFUELS CHINA TECH CO LTD
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