The invention relates to a comprehensive 
processing method of olefin in Fischer-Tropsch-synthesized light distillate. The comprehensive 
processing method comprises the following steps: carrying out 
extractive distillation on 
raw material which is Fischer-Tropsch-synthesized C5 light distillate, further purifying an enriched 1-amylene material obtained at the top of an 
extractive distillation tower by virtue of precise 
distillation to obtain a 1-amylene product, introducing a mixed material of C5 components obtained at the bottom of the 
extractive distillation tower and an extraction agent into a 
solvent recycling 
tower, and recycling an extraction agent for circular use, wherein the extraction agent of the extractive 
distillation is N,N-
dimethylformamide; carrying out olefin isomerism on C5 components obtained from the top of the 
solvent recycling tower by virtue of an isomerizing reactor; mixing heterogeneous-olefin-enriched C5 components obtained from an isomerism reactor with 
methanol, and adding the mixture into an etherification reactor for etherification; introducing materials at an exit of the etherification reactor into a 
catalysis rectifying column, separating a product (
tert amyl methyl ether) when the etherification is carried out in the 
catalysis rectifying column, wherein a 
tert amyl methyl ether product reaching the industrial demands is obtained from the bottom of the 
catalysis rectifying column. According to the comprehensive 
processing method, high-value-added C5 olefin 1-amylene and a clean high-
octane gasoline additive (
tert amyl methyl ether) are obtained by virtue of 
deep processing of the Fischer-Tropsch-synthesized C5 distillate.