The invention relates to a comprehensive
processing method of olefin in Fischer-Tropsch-synthesized light distillate. The comprehensive
processing method comprises the following steps: carrying out
extractive distillation on
raw material which is Fischer-Tropsch-synthesized C5 light distillate, further purifying an enriched 1-amylene material obtained at the top of an
extractive distillation tower by virtue of precise
distillation to obtain a 1-amylene product, introducing a mixed material of C5 components obtained at the bottom of the
extractive distillation tower and an extraction agent into a
solvent recycling
tower, and recycling an extraction agent for circular use, wherein the extraction agent of the extractive
distillation is N,N-
dimethylformamide; carrying out olefin isomerism on C5 components obtained from the top of the
solvent recycling tower by virtue of an isomerizing reactor; mixing heterogeneous-olefin-enriched C5 components obtained from an isomerism reactor with
methanol, and adding the mixture into an etherification reactor for etherification; introducing materials at an exit of the etherification reactor into a
catalysis rectifying column, separating a product (
tert amyl methyl ether) when the etherification is carried out in the
catalysis rectifying column, wherein a
tert amyl methyl ether product reaching the industrial demands is obtained from the bottom of the
catalysis rectifying column. According to the comprehensive
processing method, high-value-added C5 olefin 1-amylene and a clean high-
octane gasoline additive (
tert amyl methyl ether) are obtained by virtue of
deep processing of the Fischer-Tropsch-synthesized C5 distillate.