676results about "Ether preparation by compound addition" patented technology

The present inventions are (A) a solvent comprising at least one cycloalkyl alkyl ether (1) represented by the general formula: R1-O-R2 (wherein R1 is cyclopentyl or the like; and R2 is C1-10 alkyl or the like); (B) a method of preparations the ethers (1) characterized by reacting an alicyclic olefin with an alcohol in the presence of an acid ion-exchange resin having a water content of 5 wt % or less. The solvent is useful as cleaning solvent for electronic components, precision machinery components or the like, reaction solvent using various chemical reactions, extraction solvent for extracting objective organic substances, solvent or remover for electronic and electrical materials, and so on. The process enables industrially advantageous production of the objective cycloalkyl alkyl ethers (1).

Isobutene in isobutenic hydrocarbon mixtures is oligomerized over a solid acidic ion exchange resin, said acidic ion exchange resin containing, for example, sulfonic acid groups, some of whose protons have been exchanged for metal ions.

The invention relates to a comprehensive use method of mixed C-4, which mainly aims at solving the problem that the comprehensive utilization ratio of mixed C-4 by-products generated by a steam cracking device and an FCC device is low in the prior art. The method comprises the following steps: (1) adopting an extract technology to obtain butadiene through separation; (2) adopting an etherificationtechnology to synthesize MTBE by using isobutene remained in the C-4 undergoing the extraction in the first step; (3) separating water, ether and alcohol in the C-4 undergoing the etherification in the second step by adopting a refining and separating technology; (4) producing propylene through the disproportionating reaction between the mixed C-4 which is purified in the third step and ethyleneby adopting an olefine disproportionation technology; and (5) cyclically taking the mixed C-4 which is left after the reaction in the fourth step as the raw material of a cracking furnace. Such a technical scheme better solves the problem and can be used in the industrial production for increasing the propylene production and the comprehensive value of the mixed C-4.

A method for forming propylene wherein ethylene is employed as a primary feed material in a combination of steps comprising dehydration, skeletal isomerization, and metathesis to form a versatile product mix that can contain one or more of propylene, gasoline, MTBE, and propylene oxide.

Disclosed is a process for production of a carboxylic acid ester from a carboxylic acid and an olefin or production of an ether compound from an alcohol and an olefin at low cost and with high yield in an industrially advantageous manner. The process comprises the step of reacting a carboxylic acid with an olefin to yield a corresponding carboxylic acid ester or reacting an alcohol with an olefin to yield a corresponding ether compound. In the process, a catalyst comprising a combination of (i) at least one metal compound selected from an iron compound, a cobalt compound and a nickel compound and (ii) an acidic compound is used.

The invention is a process for preparing lower olefins comprising: a) steam cracking a paraffinic feedstock to obtain a cracker effluent comprising olefins and saturated and unsaturated C4 hydrocarbons; b) contacting an oxygenate feedstock with a molecular sieve-comprising catalyst, at a temperature in the range of from 350 to 1000° C. to obtain an oxygenate conversion effluent comprising olefins and saturated and unsaturated C4 hydrocarbons; c) subjecting the cracker effluent and the oxygenate conversion effluent to one or more separation steps such that an olefin product stream comprising ethylene and/or propylene, and a stream comprising saturated and unsaturated C4 hydrocarbons are obtained; and d) subjecting part of the stream comprising C4 hydrocarbons from both the cracker effluent and the oxygenate conversion effluent to extractive distillation to obtain a stream enriched in unsaturated C4 hydrocarbons and a stream enriched in saturated C4 hydrocarbons.

The invention discloses a preparation method of hydrofluoroether. The preparation method comprises the following steps of: mixing a solvent, a catalyst, olefin and alcohol to have reaction, wherein the mole ratio of the solvent to the alcohol is (1-6):1, the mole ratio of the catalyst to the alcohol is (0.01-0.15):1, the mass ratio of the olefin to the alcohol is (0.5-5):1, the reaction temperature is 20-60 DEG C, the reaction pressure is 0.05-0.6MPa, and the reaction time is 0.5-3 hours; and rectifying after the reaction is accomplished, so as to obtain a hydrofluoroether product. The preparation method has the advantages that the reaction condition is gentle, the operation is simple, products are easy to separate, and less wastewater, waste gas and waste residue are discharged.

The invention relates to a process for preparing 1-octene by reacting 1,3-butadiene with a telogen of the formula H—X—Y—H, where X is O, N, S or P and Y is C, N or Si and X and Y bear, depending on their valence, further substituents, in the presence of a telomerization catalyst to form a telomer of the formula H₂C═CH—CH₂—CH₂—CH₂—CH═CH—CH₂—X—Y—H, partially hydrogenating the telomer to form a 1-substituted 2-octene of the formula H₃C—CH₂—CH₂—CH₂—CH₂—CH═CH—CH₂—X—Y—H and dissociating the 1-substituted 2-octene to give 1-octene.

Isobutene is prepared by dissociation of MTBE in the gas phase, by a) fractional distillation of an MTBE-containing stream comprising feed MTBE (I) and a recycle stream (VIII) to give an MTBE-containing overhead stream (II) and a bottom stream (III) having a boiling point higher than MTBE, b) catalytic dissociation of the overhead stream (II) obtained in step a) to give a dissociation product (IV), c) separation by distillation of the dissociation product (IV) obtained in step b) into an overhead stream (V) comprising more than 90% by mass of isobutene and a bottom stream (VI) comprising diisobutene, MTBE and more than 50% of the methanol present in the dissociation product (IV), d) fractional distillation of the bottom stream obtained in step c) under conditions under which the methanol is obtained as bottom product (VII) and more than 99% of the MTBE is obtained in the overhead product (VIII), and e) recirculation of the overhead product (VIII) to step a).

Described is a reaction of a fluorinated alkoxide with an alkyl fluorovinylalkyl ether, the alkyl fluorovinylalkyl ether having alpha-beta carbon-carbon unsaturation relative to the ether oxygen, to produce a hydrofluoroether.

The present invention relates to a method for preparing diol mono-tert-butyl ether. According to the method, isobutene gas and liquid-phase diol are introduced into the catalyst bed layer in the middle portion of a reactor, the generated diol mono-tert-butyl ether is instantly distilled from the bed layer under the gas stripping effect of the isobutene gas so as to avoid the generation of ethylene glycol di-tert-butyl ether due to the continuous reaction between the diol mono-tert-butyl ether and the isobutene, the diol mono-tert-butyl ether is separated on the upper portion of the reactor, the separated diol mono-tert-butyl ether is condensed on the tower top, the condensed diol mono-tert-butyl ether is extracted from the tower top or the side line, and the unreacted isobutylene and the unreacted diol are respectively extracted from the tower top and the tower bottom and then are recycled to the inlet. With the process of the present invention, the generation of the diol di-tert-butyl ether can be inhibited, such that the problems that the azeotropy of the diol di-tert-butyl ether and the diol mono-tert-butyl ether causes high separation energy consumption, high investment, and the like can be avoided.

A selectivated molecular sieve, e.g., ZSM-22 or ZSM-23, is used as olefin oligomerization catalyst to provide product, e.g., octenes and dodecenes from butene, having a low degree of branching and hindered double bonds.

The invention discloses a mixed C4 utilization method which comprises the following steps of: performing an etherification reaction between mixed C4 and methanol in the presence of cation exchange resin to generate MTBE and isobutene-free mixed C4, allowing the isobutene-free mixed C4 to enter into an extraction tower for extraction to obtain mixed butanes and mixed butylene, and allowing the mixed butane to perform a catalytic reaction in the presence of a modified shape-selective zeolite catalyst to generate propane and aromatic hydrocarbon. The mixed butylene is used as the raw material for the production of propylene. The mixed C4 is fully utilized, thus raising the yield of ethene and propylene.

The invention relates to a method for preparing glycerin ether from glycerol. The glycerol reacts with ether, alcohol or olefinic hydrocarbon in the existence of a catalyst to obtain di-tert-butyl glycerin ether, tri-tert-butyl glycerin ether and other glycerin ethers which can be used as diesel fuel additives, antibacterial agents, flavoring agents, humectants, emulsifying agents and surfactants at a high yield.

The invention relates to a preparation method of hydrofluoroether. The preparation method comprises the following steps: (1), dissolving an alkali compound in fluorine-containing alkanol, adding a solvent, adding fluorinated olefin, and heating and stirring for reaction to obtain a mixed solution; (2), washing the mixed solution obtained in the step (1) by using water, standing for demixing, collecting an organic phase solution of a lower layer, and rectifying to obtain a hydrofluoroether product. According to the preparation method, the generation of double-bond impurities can be inhibited, and a reaction product from which a target product is easily purified can be obtained; the reaction temperature and the reaction pressure are relatively mild, the safety coefficient is high, and more satisfactory reaction speed can be obtained; the solvent is easily recycled, the cost is lowered, and a plurality of wastes are prevented from polluting the environment.