Flexible strip-shaped pH sensor capable of detecting body fluid in real time, and preparation method thereof
A real-time detection and ph sensor technology, applied in the field of flexible sensors, can solve the problems of lack of flexibility and high price, and achieve the effect of simple materials, small volume and easy availability of materials
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[0038] The present invention also provides a method for preparing the above-mentioned flexible strip-shaped pH sensor capable of real-time detection of body fluids, comprising the following steps:
[0039] Step 1, preparing the reference electrode 22 and the working electrode 21 on the surface of the flexible substrate 1 .
[0040] Further, the flexible substrate 1 is selected from one or more composites of polyvinyl chloride, polycarbonate, polyethylene terephthalate, polyester, paper, cardboard, ceramics and regenerated silk fibroin thing.
[0041] More preferably, in a preferred embodiment of the present invention, the strip-shaped polyethylene terephthalate (PET) material is selected as the base material, which has excellent physical and mechanical properties in a wide temperature range. Performance, the long-term use temperature can reach 120 ℃, has excellent flexibility, electrical insulation, fatigue resistance, friction resistance and dimensional stability, and the ma...
Embodiment 1
[0073] This embodiment provides a flexible strip-shaped pH sensor that can detect body fluids in real time, which is made according to the following steps:
[0074] (1) Get the wool keratin solution of 5ml 5wt%, add HAuCl under vigorous stirring condition 4 solution, and then add 1M sodium hydroxide solution under constant stirring conditions, adjust the pH value to 12, and then place it at 38°C for 12h. Among them, wool keratin and HAuCl in the reaction solution 4 The mass ratio is 100:1.
[0075] (2) The reaction solution was placed at -80° C. for 48 hours of freeze-drying to obtain gold nanoparticles@wool keratin.
[0076] (3) Carbonization: under an argon atmosphere, the gold nanoparticle@wool keratin was heated to 150° C. at a heating rate of 2° C. / min and maintained for 3 hours. Then the temperature was raised to 350°C at a rate of 5°C / min and kept for 3h, and then the temperature was raised to 700°C at a rate of 5°C / min and kept for 2h. Finally, take it out after co...
Embodiment 2
[0081] This embodiment provides a flexible strip-shaped pH sensor that can detect body fluids in real time. The difference from Embodiment 1 is that:
[0082] In step (1), take 5ml of 5wt% silk fibroin solution as the protein base in the protein base nitrogen-doped carbon / gold nanoparticle composite material.
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