Scratch-resistant BOPP (biaxially-oriented polypropylene) film and preparation method thereof

A scratch-resistant and thin-film technology, applied in polyurea/polyurethane coatings, coatings, etc., can solve the problems of low surface energy of the film, difficulty in uniform dispersion of nano-silica particles, and poor binding force

Active Publication Date: 2019-06-18
SHANGHAI PUDONG HUANGGONG PRINTING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the commonly used BOPP film has poor surface wear resistance, and it is often scratched by contact with hard objects during post-processing, transportation and use, which affects the appearance of printed products.
[0003] At present, the surface of BOPP film is usually coated with a layer of anti-scratch coating to improve the scratch resistance of BOPP film. CN102604523A discloses a water-based matt scratch coating for BOPP film and its preparation method. The method is to endow the BOPP film with a certain ability to resist scratches by adding silicone resin and nano-silica into the coating. However, the inventors found in actual research that it is difficult to uniformly disperse nano-silica particles in the resin system. After the scratch coating is coated on the BOPP film substrate, the nanoparticles will agglomerate on the surface of the coating film, so that a complete lubricating film cannot be formed on the surface of the coating film, which will seriously affect the stability and stability of the scratch-resistant coating. Scratch resistance
In addition, due to the low surface energy of the BOPP film and no polar groups on the film surface, the bonding force between the BOPP film and the anti-scratch coating is poor, which will greatly reduce the service life of the coating film

Method used

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  • Scratch-resistant BOPP (biaxially-oriented polypropylene) film and preparation method thereof
  • Scratch-resistant BOPP (biaxially-oriented polypropylene) film and preparation method thereof

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Embodiment 1~4

[0029] A preparation method for scratch-resistant BOPP film, the steps are:

[0030] (1) Corona treatment is performed on the BOPP film substrate to generate oxygen-containing polar groups on its surface;

[0031] (2) Add nano silicon dioxide to toluene, and obtain a uniform suspension after ultrasonic dispersion at room temperature, add silane coupling agent KH-550 with a mass fraction of silicon dioxide of 4%, reflux at 110°C for 2 hours, and suction filter, After washing and drying with absolute ethanol, KH-550 modified nano silicon dioxide is obtained;

[0032] (3) Weigh aliphatic urethane acrylate hexaacrylate (HY330), dipropylene glycol diacrylate (Changxing EM222), KH-550 modified nano silica, defoamer (BYK1770) and Wetting agent (BYK-P104S), after ultrasonic dispersion at room temperature for 40 minutes, add the formulated amount of photoinitiator 1173, stir evenly, and obtain scratch-resistant coating;

[0033] (4) Coating the anti-scratch coating on the surface of ...

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Abstract

The invention discloses a scratch-resistant BOPP (biaxially-oriented polypropylene) film and a preparation method thereof, and belongs to the technical field of packaging. The scratch-resistant BOPP film comprises a BOPP film substrate and a scratch-resistant coating, the surface of the BOPP film substrate subjected to corona treatment is coated with scratch-resistant paint to form the scratch-resistant coating by ultraviolet curing, and the scratch-resistant paint comprises, by weight, 40-70 parts of aliphatic polyurethane acrylate hexaacrylate, 10-25 parts of dipropylene glycol diacrylate, 2-10 parts of photoinitiators 1173, 5-15 parts of KH-550 modified nano-silica, 0.1-0.5 part of defoaming agents and 0.1-0.5 part of wetting agents. The preparation method is simple, and the prepared scratch-resistant BOPP film has excellent scratch resistance and long service life.

Description

technical field [0001] The invention relates to a scratch-resistant BOPP film and a preparation method thereof, belonging to the technical field of packaging. Background technique [0002] With the continuous development of the packaging industry and the continuous improvement of human living standards, people also pay special attention to the packaging of various products. Laminating is the most commonly used process in the printing finishing process. The surface is covered with a layer of 0.012-0.020mm thick transparent plastic film to form a product processing technology that combines paper and plastic. BOPP film is a commonly used film material in the film coating process. It has the characteristics of colorless, non-toxic, high tensile strength, toughness and good transparency. Coating it on the surface of printed matter can not only protect the printed matter It can also improve the visual effect of the product, and at the same time, it can play a very good protective...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08J7/04C09D175/14C09D7/62
Inventor 胡显国钱永胜王友果李生王刚
Owner SHANGHAI PUDONG HUANGGONG PRINTING
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