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Core-shell anti-ice-freezing modifier, method for producing same, and anti-ice-freezing coating material comprising same

An anti-condensation ice, core-shell type technology, applied in the field of anti-condensation ice coatings and core-shell type anti-condensation ice modifiers, can solve the problems of difficulty in uniform coating on the surface of particles, many voids in the coating material, and huge production workload. Achieve the effects of excellent hydrophobicity, excellent sustained release, and short experimental period

Active Publication Date: 2019-06-25
江苏山海新型建材有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Thereby, there is following problem in prior art: because inorganic salt particle is little (big specific surface area), the consumption of used wax, asphalt or various resin (as patent document 3) can be very big, uneconomical; Adopt this simple The physical way of wrapping, the surface of the particles is difficult to wrap evenly, and the organic matter is sticky, and the wrapped particles will stick together. In order to disperse the bonded particles, the follow-up production workload will be very huge, and it is difficult to achieve real industrialization; further In actual use, it is found that in the case of using polymers to wrap small particles of inorganic salts, the surface of the wrapped inorganic salt particles has more gaps in the wrapping material, and the slow-release effect will be greatly reduced when it meets water.

Method used

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  • Core-shell anti-ice-freezing modifier, method for producing same, and anti-ice-freezing coating material comprising same
  • Core-shell anti-ice-freezing modifier, method for producing same, and anti-ice-freezing coating material comprising same
  • Core-shell anti-ice-freezing modifier, method for producing same, and anti-ice-freezing coating material comprising same

Examples

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preparation example Construction

[0059]

[0060] In the step of preparing the pre-dispersion liquid, the water-soluble metal salt is uniformly dispersed in the alcohol solvent, and then a basic catalyst is added thereto, and deionized water is optionally added to obtain the pre-dispersion liquid.

[0061] As the initial dispersion medium, specific examples of the alcohol solvent used in the predispersion liquid include methanol, ethanol, n-propanol, isopropanol, n-butanol, isobutanol, t-butanol, n-pentanol, neopentyl alcohol , n-hexanol, cyclopentanol, cyclohexanol, benzyl alcohol, phenylethyl alcohol, ethylene glycol. These can be used alone or in combination of two or more. From the viewpoint of further improving productivity, the alcohol solvent of the present invention is preferably one or more of methanol, ethanol, and isopropanol, more preferably ethanol.

[0062] The details of the water-soluble metal salt particles have been described above and will not be repeated here. From the standpoint of for...

Embodiment 1

[0146] 40 parts of emulsified asphalt with a solid content of 50% was added to 100 parts of a silicone emulsion with a solid content of 50% and stirred at a speed of 200 rpm for 10 minutes, and 16 parts of the core-shell anti-icing modifier prepared in Production Example 2 were added to Stir at a speed of 200 rpm for 15 minutes, add 3 parts of silane coupling agent, and simultaneously add 1.0 parts of dibutyltin dilaurate and stir for 20 minutes at a speed of 300 rpm, and finally add 10 parts of 40-mesh corundum. A hydrophobic slow-release anti-icing silicone coating is obtained.

Embodiment 2

[0148] A silicone coating was obtained in the same manner as in Example 1, except that the core-shell anti-icing modifier in Example 1 was replaced with the core-shell anti-icing modifier prepared in Production Example 1.

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Abstract

The present invention relates to a core-shell anti-ice-freezing modifier, a method for producing the same, and an anti-ice-freezing coating material comprising the same. The core-shell anti-ice-freezing modifier comprises a core and a shell layer, wherein the core is water-soluble metal salt particles; the shell layer is formed of oxide particles and coats the core. The thickness of the shell layer is 10 nm or more. The anti-ice-freezing modifier disclosed by the invention is easy to construct. When used for the anti-ice-freezing coating, an anti-ice-freezing coating layer formed by the anti-ice-freezing coating has excellent anti-ice-freezing property, hydrophobicity, slow release property and long service life.

Description

technical field [0001] The invention relates to a core-shell anti-icing modifier, a manufacturing method thereof and an anti-icing coating comprising the same. Background technique [0002] Snow and ice on roads in winter has always been a problem that plagues road traffic safety. Snow and ice on the road surface will greatly reduce the anti-skid ability of the road surface, which not only weakens the traffic capacity of the road, is prone to vicious traffic accidents, but also damages the road and its subsidiary structures. In severe cases, it will cause traffic interruption and make people's lives Production and production cannot be carried out normally, and even endanger the safety of people's lives and property. [0003] At present, the commonly used road surface deicing methods are generally divided into two categories: passive suppression type and active ice and snow melting type. Commonly used passive suppression ice and snow removal measures mainly include spreadin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B22/12C04B26/32
Inventor 惠嘉朱宝林江睿南石艳赵锡森严世祥周彬谷云辉张翠刚红润王曈付立边莉
Owner 江苏山海新型建材有限公司
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