Preparation method of carbon nanotube fiber/polydimethylsiloxane composite electro-conductive elastomer

A carbon nanotube fiber and dimethylsiloxane technology is applied in the field of preparation of carbon nanotube fiber/polydimethylsiloxane composite conductive elastomer, which can solve the problem of poor durability of conductive elastomer, easy agglomeration of CNTs, Easy to pull off and other problems, to achieve the effects of excellent cycleability and durability, mature preparation technology, and good electrical conductivity

Active Publication Date: 2019-06-25
ZHEJIANG SCI-TECH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Since Ecoflex is a highly elastic material, when the strain sensor is stretched, the highly oriented carbon nanotube fibers prepared by dry spinning are easy to break and have poor durability
[0005] So far, the carbon nanotube / polydimethylsiloxane composite conductive elastomer prepared by the hybrid method has the disadvantages of easy aggregation of CNTs in the polymer and unreliable conductivity of the conductive elastomer, which affects its flexibility. Applications of Stretchable Electronics
The carbon nanotube fibers prepared by the CNT array spinning method have low yield and are easy to break. The conductive elastomer prepared based on this carbon nanotube fiber has poor durability and is not suitable for use in flexible and stretchable electronic devices.

Method used

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  • Preparation method of carbon nanotube fiber/polydimethylsiloxane composite electro-conductive elastomer
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  • Preparation method of carbon nanotube fiber/polydimethylsiloxane composite electro-conductive elastomer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Step 1: take ethanol (97.4wt%), ferrocene (1.6wt%), thiophene (8wt%) and deionized water (0.2wt%) as raw materials, after mixing, ultrasonic 30min obtains reaction solution, adopts digital syringe pump to The rate of 40mL / h is injected into a horizontal tube furnace at 1180°C, and the hollow cylinder of carbon nanotubes is prepared by floating catalytic chemical vapor deposition, and then immersed in deionized water to bundle and collect, and the air is discharged to process Twist to obtain carbon nanotube fibers, put them in an oven and dry them at 60°C for 2 hours, and set them aside.

[0039] Step 2: Add polydimethylsiloxane and curing agent into the beaker according to the mass ratio of 10:1, stir with a glass rod until fully mixed to obtain a mixed solution, and put the beaker containing the mixed solution into a vacuum drying oven , evacuated at room temperature for 1 hour until all air bubbles were removed.

[0040] Step 3: Pour 2 / 3 of the mixture that has been ...

Embodiment 2

[0046] Step 1: Take ethanol (97.4wt%), ferrocene (1.6wt%), thiophene (8wt%) and deionized water (0.2wt%) as raw materials, mix and sonicate for 30 minutes to obtain a reaction solution, and use a digital syringe pump to The rate of 30mL / h is injected into a horizontal tube furnace at 1180°C, and the hollow cylinder of carbon nanotubes is prepared by floating catalytic chemical vapor deposition, which is then immersed in deionized water to bundle and collect, and the air is discharged to process. Twist to obtain carbon nanotube fibers, put them in an oven and dry them at 60°C for 2 hours, and set them aside.

[0047] Step 2: Add polydimethylsiloxane and curing agent into the beaker according to the mass ratio of 15:1, stir with a glass rod until fully mixed to obtain a mixed solution, and put the beaker containing the mixed solution into a vacuum drying oven , evacuated at room temperature for 1 hour until all air bubbles were removed.

[0048] Step 3: Pour the 2 / 3 mixture tha...

Embodiment 3

[0054] Step 1: Take ethanol (97.4wt%), ferrocene (1.6wt%), thiophene (8wt%) and deionized water (0.2wt%) as raw materials, mix and sonicate for 30 minutes to obtain a reaction solution, and use a digital syringe pump to The rate of 28mL / h was injected into a horizontal tube furnace at 1180°C, and the hollow cylinder of carbon nanotubes was prepared by floating catalytic chemical vapor deposition, and then immersed in deionized water to bundle and collect, and the air was discharged to process Twist to obtain carbon nanotube fibers, put them in an oven and dry them at 60°C for 2 hours, and set them aside.

[0055] Step 2: Add polydimethylsiloxane and curing agent into the beaker according to the mass ratio of 18:1, stir with a glass rod until fully mixed to obtain a mixed solution, and put the beaker containing the mixed solution into a vacuum drying oven , evacuated at room temperature for 1 hour until all air bubbles were removed.

[0056] Step 3: Pour the 2 / 3 mixed solution...

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Abstract

The invention discloses a preparation method of a carbon nanotube fiber/polydimethylsiloxane composite conductive elastomer. The method comprises the following steps: 1) ultrasonically mixing ethanol,ferrocene, thiophene and deionized water to obtain a reaction solution, preparing a hollow cylindrical object of the carbon nano tube by a floating catalytic chemical vapor deposition method, performing bundling, filament collecting and air exhaustion, performing twisting operation to obtain carbon nano tube fibers, and drying the carbon nano tube fibers for later use; 2) fully stirring and uniformly mixing polydimethylsiloxane and a curing agent to obtain a mixed solution, vacuumizing the solution, pouring the mixed solution into a culture dish, and drying and preheating the mixed solution;3) dipping the dried carbon nanotube fiber into the preheated mixed solution, adding the mixed solution before preheating, and curing and molding the carbon nanotube fibers in a drying oven to obtaina carbon nanotube fiber/polydimethylsiloxane compound; and 4) performing cutting operation to obtain the carbon nanotube fiber/polydimethylsiloxane composite conductive elastomer. The preparation method is controllable in process and easy to operate, and the prepared finished product has high elasticity and flexibility and also has good electrical conductivity.

Description

technical field [0001] This product relates to the field of flexible and stretchable electronics, in particular to a method for preparing a carbon nanotube fiber / polydimethylsiloxane composite conductive elastomer. Background technique [0002] With the development of electronic information technology, people have put forward higher requirements for wearable electronic products, and electronic products are developing at a rapid speed in the direction of intelligence, miniaturization, portability, flexibility and elasticity. The construction of flexible and stretchable electronic devices relies on elastic conductors that can maintain good electrical conductivity under deformation. Carbon nanotubes possess high mechanical properties and excellent electrical conductivity, and have attracted much attention in stretchable wires in recent years. [0003] In recent years, Zu et al. prepared some conductive elastomers by dispersing CNTs in polymers or directly impregnating CNT arra...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/04C08K7/06D06M15/643D01F9/12D06M101/40
Inventor 陈建军马瑞琦姜敏
Owner ZHEJIANG SCI-TECH UNIV
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