Local in-situ electrochemical polymerization 3D printing method of conductive polymer
A conductive polymer, 3D printing technology, applied in the field of 3D printing, can solve the problems of volume and shape changes of printed components, damage to the molecular structure of conductive polymers, and unfavorable micro-electrode precision molding. Effects of Structural and Electrical Stability
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Embodiment 1
[0030] (1) Configure 0.2mol / L aniline monomer and 1.0mol / L phosphoric acid to mix in the aqueous solution, and stir it evenly;
[0031] (2) Select glass as the substrate, and deposit gold on it as the current collector;
[0032] (3) Send the configured mixed solution into the printer;
[0033] (4) Load 0.8V voltage between the print head of the printer and the conductive substrate, and let the printer move according to the printing file to realize the printing and polymerization of the aniline monomer, and its conductivity is 1.4-1.5S / cm.
Embodiment 2
[0035] (1) Prepare 0.5 mol / L aniline monomer and 1.2 mol / L sulfuric acid, mix them in N-methylpyrrolidone solution, and stir evenly;
[0036] (2) Select graphene film as current collector;
[0037] (3) Send the configured mixed solution into the printer;
[0038] (4) Load 3V voltage between the print head of the printer and the conductive substrate, and let the printer move according to the print file to realize the printing and polymerization of aniline monomer, and its conductivity is 2.0-2.1S / cm.
Embodiment 3
[0040] (1) Prepare 0.1 mol / L pyrrole monomer and 0.3 mol / L lithium perchlorate, mix them in the N-methylpyrrolidone solution, and stir evenly;
[0041] (2) Choose stainless steel sheet as the base;
[0042] (3) Send the configured mixed solution into the printer;
[0043] (4) Load a voltage of 4.5V between the printer print head and the conductive substrate, and let the printer move according to the print file to realize the printing and polymerization of the pyrrole monomer, and its conductivity is 4.5-4.8S / cm.
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