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Local in-situ electrochemical polymerization 3D printing method of conductive polymer

A conductive polymer, 3D printing technology, applied in the field of 3D printing, can solve the problems of volume and shape changes of printed components, damage to the molecular structure of conductive polymers, and unfavorable micro-electrode precision molding. Effects of Structural and Electrical Stability

Active Publication Date: 2019-07-26
RES & DEV INST OF NORTHWESTERN POLYTECHNICAL UNIV IN SHENZHEN +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, the subsequent heat treatment after ink direct writing has always been one of the main defects of ink direct writing technology, especially for conductive polymers, which are widely used in microelectronic devices and energy storage devices, the sintering process will not only make The volume and shape of the printed components change to a certain extent, which is not conducive to the precise molding of microelectrodes; at the same time, the high temperature of sintering will destroy the molecular structure of conductive polymers, causing them to lose or even lose their original electrical properties

Method used

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  • Local in-situ electrochemical polymerization 3D printing method of conductive polymer
  • Local in-situ electrochemical polymerization 3D printing method of conductive polymer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] (1) Configure 0.2mol / L aniline monomer and 1.0mol / L phosphoric acid to mix in the aqueous solution, and stir it evenly;

[0031] (2) Select glass as the substrate, and deposit gold on it as the current collector;

[0032] (3) Send the configured mixed solution into the printer;

[0033] (4) Load 0.8V voltage between the print head of the printer and the conductive substrate, and let the printer move according to the printing file to realize the printing and polymerization of the aniline monomer, and its conductivity is 1.4-1.5S / cm.

Embodiment 2

[0035] (1) Prepare 0.5 mol / L aniline monomer and 1.2 mol / L sulfuric acid, mix them in N-methylpyrrolidone solution, and stir evenly;

[0036] (2) Select graphene film as current collector;

[0037] (3) Send the configured mixed solution into the printer;

[0038] (4) Load 3V voltage between the print head of the printer and the conductive substrate, and let the printer move according to the print file to realize the printing and polymerization of aniline monomer, and its conductivity is 2.0-2.1S / cm.

Embodiment 3

[0040] (1) Prepare 0.1 mol / L pyrrole monomer and 0.3 mol / L lithium perchlorate, mix them in the N-methylpyrrolidone solution, and stir evenly;

[0041] (2) Choose stainless steel sheet as the base;

[0042] (3) Send the configured mixed solution into the printer;

[0043] (4) Load a voltage of 4.5V between the printer print head and the conductive substrate, and let the printer move according to the print file to realize the printing and polymerization of the pyrrole monomer, and its conductivity is 4.5-4.8S / cm.

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Abstract

The invention discloses a local in-situ electrochemical polymerization 3D printing method of a conductive polymer. The method comprises the steps of S100, uniformly mixing a conductive polymer monomer, an additive and a supporting electrolyte in a solvent for a 3D printer to prepare conductive polymer monomer dispersing liquid; S200, loading the conductive polymer monomer dispersing liquid into the 3D printer and applying voltage between a printing head and a conductive substrate; and S300, performing printing, allowing the conductive polymer monomer dispersing liquid to be printed by the printer layer by layer, and allowing the conductive polymer monomer to perform polymerization in a printing process to obtain a required conductive polymer product. The method is simple in technology, fewin procedure and high in production efficiency, is suitable for single or small-lot production, is also suitable for simultaneous large-lot 3D printing production of massive printers, and has a certain application prospect.

Description

Technical field [0001] The present invention belongs to the field of 3D printing (additive manufacturing), and specifically relates to a method of local in-situ electropolymerization 3D printing conductive polymer. Background technique [0002] 3D printing, also known as additive manufacturing, is a technology that manufactures three-dimensional products through layer-by-layer printing based on digital models. Because of its unique manufacturing method and huge manufacturing potential, it has received extensive attention and research from many research institutions and companies at home and abroad, and has been applied in medical, automotive, aerospace and other fields. In view of the difference between the printing targets of 3D printing and the printing materials, 3D printing is also subdivided into many types. Among them, the ink direct writing technology has obvious advantages in the printing of micro-electronic devices and micro-energy storage devices due to its wide range ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01B13/00
CPCH01B13/0026
Inventor 谢科予胡竟志徐照华沈超魏秉庆
Owner RES & DEV INST OF NORTHWESTERN POLYTECHNICAL UNIV IN SHENZHEN
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