Long-acting and weather-proof resin tile co-extrusion material with light screening function and preparation method thereof

A technology for light shielding and resin tiles, which is applied in the field of long-term weather-resistant resin tile co-extrusion and its preparation, can solve the problems of reducing the mechanical properties of materials, failing to effectively improve the anti-ultraviolet aging performance of ASA, and poor anti-ultraviolet aging properties, etc. Long life, excellent anti-ultraviolet aging performance, and the effect of large specific surface area

Inactive Publication Date: 2019-08-02
安徽国邦永盛智能科技有限公司
View PDF2 Cites 5 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, ASA resin has poor anti-ultraviolet aging performance in outdoor conditions. Therefore, in order to improve the anti-ultraviolet aging performance of ASA resin, light stabilizers are often added. However, adding a small amount cannot effectively improve the anti-ultraviolet aging performance of ASA, while a large Adding a light stabilizer will significantly reduce the mechanical properties of the material

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Long-acting and weather-proof resin tile co-extrusion material with light screening function and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] A long-acting weather-resistant resin tile co-extrusion material with light shielding function, characterized in that its raw materials include by weight: 65 parts of ASA resin, 20 parts of AS resin, 5 parts of modified montmorillonite, carbon black, nano-titanium dioxide 5 parts, UV-944 0.5 parts, salicylate 0.3 parts, antioxidant 1010 0.2 parts, EBS 0.5 parts, toner 3.5 parts.

[0027] Wherein, the modified montmorillonite is prepared by the following steps: dissolving sodium hexametaphosphate in water to form a homogeneous solution with a mass concentration of 1.2%, and then adding montmorillonite to obtain a suspension with a montmorillonite content of 0.3 g / ml; After the suspension is ultrasonically dispersed and stratified, the supernatant is vacuum spray-dried at 100°C to obtain a prefabricated material; the prefabricated material is dissolved in toluene, heated to boiling, and the treatment agent KH-570 is added dropwise, and stirred React for 4 hours, filter, w...

Embodiment 2

[0029] A long-acting weather-resistant resin tile co-extrusion material with light shielding function is characterized in that its raw materials include by weight: 65 parts of ASA resin, 20 parts of AS resin, 5 parts of modified montmorillonite, 5 parts of nano-titanium dioxide, 0.6 parts of UV-622, 0.4 parts of benzotriazoles, 0.5 parts of antioxidant 168, 0.5 parts of EBS, 3 parts of toner.

[0030] Wherein, the modified montmorillonite is prepared by the following steps: dissolving sodium hexametaphosphate in water to form a homogeneous solution with a mass concentration of 1.6%, and then adding montmorillonite to obtain a suspension with a montmorillonite content of 0.6 g / ml; Ultrasonic dispersion treatment of the suspension, standing and layering, taking the supernatant and vacuum spray drying at 110°C to obtain a preform; dissolving the preform in toluene, raising the temperature and adding the treatment agent KH-570 dropwise, and stirring for 9 hours , and filtered, was...

Embodiment 3

[0032] A long-acting weather-resistant resin tile co-extrusion material with light shielding function is characterized in that its raw materials include by weight: 75 parts of ASA resin, 15 parts of AS resin, 3.5 parts of modified montmorillonite, 3 parts of carbon black, UV-770, 0.5 parts, 0.3 parts of substituted acrylonitrile, 0.2 parts of antioxidant 1076, 0.1 parts of EBS, 2 parts of toner.

[0033] Wherein, the modified montmorillonite is prepared by the following steps: dissolving sodium hexametaphosphate in water to form a homogeneous solution with a mass concentration of 1.4%, and then adding montmorillonite to obtain a suspension with a montmorillonite content of 0.45 g / ml; Ultrasonic dispersion treatment of the suspension, standing and layering, taking the supernatant and vacuum spray drying at 105°C to obtain a prefabricated material; dissolving the prefabricated material in toluene, raising the temperature and adding treatment agent KH-570 dropwise, and stirring fo...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
melt flow indexaaaaaaaaaa
tensile strengthaaaaaaaaaa
melt flow indexaaaaaaaaaa
Login to view more

Abstract

The invention discloses a long-acting and weather-proof resin tile co-extrusion material with a light screening function. The co-extrusion material comprises the following raw materials: ASA resin, ASresin, modified montmorillonite, a light screener, a hindered amine light stabilizer, an ultraviolet light absorber, an antioxidant, EBS and toner. The modified montmorillonite is prepared in the following steps: dissolving sodium hexametaphosphate into water to form homogeneous solution and adding montmorillonite, so as to obtain suspension liquid; performing ultrasonic dispersion on the suspension liquid, allowing standing still for layering and performing vacuum spray drying on an upper-layer matter, so as to obtain a prefabricated material; dissolving the prefabricated material into methylbenzene, rising the temperature, dropping in a treating agent and stirring the mixture for reaction, so as to obtain primary modified montmorillonite; dissolving the primary modified montmorilloniteinto methylbenzene, performing ultrasonic dispersion, adding an initiator under a protective atmosphere, slowing dropping in a monomer MMA (methyl methacrylate), rising the temperature and stirring the mixture for reaction, so as to obtain the modified montmorillonite. The prepared resin tile co-extrusion material is excellent in ultraviolet aging resistance, long in service life and good in mechanical property.

Description

technical field [0001] The invention relates to the technical field of new materials, in particular to a long-acting weather-resistant resin tile co-extrusion material with light shielding function and a preparation method thereof. Background technique [0002] As a building material for waterproof, heat preservation and heat insulation, clay tile is one of the building materials that we use more and has a long history. However, this kind of tile needs to consume a lot of clay. In order to protect cultivated land, protect the environment, save energy, my country has gradually restricted or even banned the use of clay tiles. At present, more and more synthetic resin tiles have been applied to buildings. Synthetic resin tile is a new type of building material developed by using high-tech chemical and chemical technology. Pollution, green environmental protection, fire prevention, insulation, easy installation, etc., and the shape is beautiful and three-dimensional, and the co...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L51/04C08L25/12C08K13/06C08K9/02C08K9/06C08K9/04C08K3/34C08K3/22C08K3/04C08K5/00
CPCC08K2003/2241C08K2201/003C08K2201/011C08L51/04C08L2201/08C08L25/12C08K13/06C08K9/02C08K9/06C08K9/04C08K3/346C08K3/22C08K3/04C08K5/005
Inventor 郭洪武李宏武高振兴
Owner 安徽国邦永盛智能科技有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products