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Method for soiling red mud by using pyrite cinder

A pyrite slag and soil conversion technology, applied in chemical instruments and methods, recycling technology, sludge treatment, etc., can solve the problems of small amount of recycling, secondary pollution, and difficult separation of waste, and achieve improvement The speed of dealkalization, the effect of increasing the fertility of red mud and accelerating the rate of sulfuric acid

Active Publication Date: 2019-08-06
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] At present, most of the soil-based resource utilization methods of red mud are to treat red mud in the form of additives. Compared with the huge annual output of red mud in my country, the amount of recovery is very small; the processing method of some bulk red mud is generally "Treating waste with waste", mixing one kind of waste into red mud to achieve the effect of red mud restoration, but there is a problem of secondary pollution, and it is difficult to separate the two wastes after treatment; therefore, now we need a A method that can process red mud in large quantities and is not prone to secondary pollution

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Embodiment 1: The method of utilizing pyrite slag to soil red mud is as follows:

[0031] Mix red mud and water spinach according to the mass ratio of 7:3 to obtain a red mud mixture, and lay it on the experimental site with a thickness of 30cm, and then lay sawdust on the red mud mixture as a water-retaining material with a thickness of 10cm , put a geotextile on the top of the water-retaining material layer, and then lay a mixture of pyrite slag and pyrolusite powder (mass ratio: 5:0.8) on the upper layer of the water-retaining material, with a thickness of 7cm; use decomposed rice every three days Water (decomposed rice washing water is made by adding apple peel to the collected rice washing water, exposing it to the sun for 10 days, then filtering to remove the filter residue, diluting the filtrate 10 times with water, and adding 50g of apple peel to each liter of rice washing water) Spray the neutralizing material layer to keep the red mud mixture layer in a super-...

Embodiment 2

[0032] Embodiment 2: The method of utilizing pyrite slag to soil red mud is as follows:

[0033] Mix red mud and water hyacinth in a mass ratio of 7:3, lay it on the experimental site, the laying thickness is 35cm, and then lay sawdust on the top of the red mud mixture as a water-retaining material, the laying thickness is 8cm, and pad on the top of the water-retaining material layer Geotextile, lay neutralizing material above the water-retaining material, and set up 3 layers of neutralizing material, the bottom layer is a mixture of 200 mesh pyrite slag and pyrolusite powder, the middle layer is 30 mesh pyrite slag and soft manganese ore powder A mixture of manganese ore powder, the top layer is a compound of untreated pyrite slag and pyrolusite powder, the mass ratio of pyrite slag to pyrolusite powder is 5:0.9; use decomposed rice every three days Water (decomposed rice washing water is made by adding apple peel to the collected rice washing water, exposing it to the sun fo...

Embodiment 3

[0034] Embodiment 3: the method of utilizing pyrite slag to soil red mud is as follows:

[0035]Mix red mud and water hyacinth in a mass ratio of 6:4 to obtain a red mud mixture, and lay it on the experimental site with a thickness of 50 cm, and then lay coconut shells on top of the red mud mixture as a water-retaining material with a thickness of 5 cm , a geotextile is placed on the top of the water-retaining material layer, and a neutralizing material is laid on the top of the water-retaining material. There are 3 layers of neutralizing material layers, the bottom layer is a mixture of 300 mesh pyrite cinder and pyrolusite powder, and the middle layer is 20 mesh sulfur The mixture of iron ore slag and pyrolusite powder, the top layer is the compound of untreated pyrite slag and pyrolusite powder, the mass ratio of pyrite slag and pyrolusite powder is 5:1.0; Use decomposed rice washing water for 2 days (decomposed rice washing water is made by adding apple peels to the collec...

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Abstract

The invention discloses a method for soiling red mud by using pyrite cinder. The method includes the following steps: evenly mixing to-be-treated red mud and biomass to obtain a red mud mixture and laying the red mud mixture on a bottom layer; laying a water-retaining material over the red mud mixture; laying a neutralizing material over the water-retaining material, wherein the neutralizing material is a mixture of pyrite cinder and an oxidant and geotextile is laid between the water-retaining material and the neutralizing material; regularly spraying the neutralizing material; and when the pH of the red mud mixture of the bottom layer is 6-9, removing the neutralizing material layer and evenly mixing the treated red mud mixture and the water-retaining material to obtain soiled red mud. The pyrite cinder is used to be oxidized in air to generate sulfur dioxide and then is reacted with water to generate sulfuric acid to dealkali the red mud, and organic matters can improve the nutrients of the red mud to finally achieve the purpose of soiling of the red mud. The method is simple and cheap in raw material sampling, accords with national conditions of China, and can carry out large-scale soiling utilization of the red mud.

Description

technical field [0001] The invention belongs to the technical field of mining waste utilization and red mud soilization, and in particular relates to a method for using pyrite slag to soil red mud. Background technique [0002] Red mud is a kind of bulk solid waste produced in the alumina industry. Because it contains iron oxide, its color is generally red, so it is called red mud. On average, for every ton of iron oxide produced, 1 to 2 tons of red mud will be produced. As of 2015, the annual output of red mud in my country has reached nearly 35 million tons. At present, red mud is mainly processed by stockpiling. Due to the Mud contains a large amount of combined alkali, and its pH is generally above 11, which leads to high alkalinity that will pollute the soil environment and groundwater around the red mud stockpile. At the same time, there is a risk of dam failure in the red mud stockpile. The safety of people's life and property has caused great hidden dangers, which urg...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B09B3/00B09B5/00C02F11/00C02F11/02
CPCB09B3/00B09B5/00C02F11/00C02F11/02C02F2303/06Y02W30/78
Inventor 黄建洪张利祥
Owner KUNMING UNIV OF SCI & TECH
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