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A kind of flame-retardant hdpe tube and its preparation method

A technology of seed tube and flame retardant synergist, which is applied in the field of plastic product processing, can solve the problems of reduced service life, low HDPE oxygen index, and aggravated combustion, so as to reduce smoke generation, improve flame retardant effect, and improve flame retardant performance effect

Active Publication Date: 2022-06-17
深圳市深捷通管业发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] HDPE (High Density Polyethylene) is a white powder or granular resin, which has good wear resistance, electrical insulation, toughness, cold resistance and anti-aging properties, and can be used as cable insulation materials. Cables made of HDPE The tube is located on the outer layer of the cable, which has the function of protecting the cable and preventing the cable from being damaged; however, due to the low oxygen index of HDPE, it is flammable and will produce a large number of molten droplets with ignitable ability when it burns, which will further aggravate the combustion Therefore, it is necessary to carry out flame retardant treatment on HDPE materials
[0003] At present, the most effective way to flame-retardant HDPE is to add flame retardants, which are generally divided into halogen-based flame retardants and halogen-free flame retardants; compared with halogen-free flame retardants, the addition of halogen-based flame retardants is small , the flame retardant effect is good, it will not reduce the mechanical properties and electrical properties of polymer materials, but the disadvantage of halogen flame retardants is that they will volatilize and produce a large amount of toxic gases at high temperatures, which will affect the environment and cause harm to human health. ; Although halogen-free flame retardants do not produce toxic gases, their flame retardant effect is far inferior to that of halogen-based flame retardants. To achieve the same flame retardant effect, a large amount of halogen-free flame retardants must be added, and halogen-free flame retardants The compatibility with polymers is poor, and after a large amount of addition, the mechanical strength of HDPE sub-pipes will be greatly reduced, and its service life will be reduced

Method used

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  • A kind of flame-retardant hdpe tube and its preparation method
  • A kind of flame-retardant hdpe tube and its preparation method

Examples

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Effect test

preparation example 1

[0038] Preparation example 1: 1. get 50kg of aluminum hydroxide and 6kg of medical stone powder, and screen through a 100-mesh sieve after grinding; 2. add 1kg of glycerol monostearate and 100kg of isopropyl to the screened aluminum hydroxide and medical stone powder alcohol, and then ultrasonically dispersed for 5min under the condition of ultrasonic power of 300W to obtain a suspension; 3. Add 1kg of titanate coupling agent to the suspension, raise the temperature to 85°C, stir for 10min at a speed of 1000r / min, and pass After suction filtration and washing, it was dried at a temperature of 160° C. for 8 hours, and then ground and sieved through a 600-mesh sieve to obtain modified aluminum hydroxide.

preparation example 2

[0039] Preparation example 2: 1. get 55kg of aluminum hydroxide and 7kg of medical stone powder, and screen through a 150 mesh sieve after grinding; 2. to add 1.5kg of glycerol monostearate and 110kg of isoglycerol to the screened aluminum hydroxide and medical stone powder. Propanol, and then ultrasonically dispersed for 8min under the condition of ultrasonic power of 320W to obtain a suspension; 3. Add 1.5kg of titanate coupling agent to the suspension, heat up to 90°C, and stir for 13min at a speed of 1500r / min , after suction filtration, washing, drying at a temperature of 170 ° C for 9 hours, and then grinding and sieving through a 600-mesh sieve to obtain modified aluminum hydroxide.

preparation example 3

[0040]Preparation example 3: 1. get 60kg aluminum hydroxide and 8kg medical stone powder, pass through 200 mesh sieves after grinding; alcohol, and then ultrasonically dispersed for 10min under the condition of ultrasonic power of 350W to obtain a suspension; 3. Add 2kg of titanate coupling agent to the suspension, heat up to 95°C, stir at a speed of 2000r / min for 15min, and pass After suction filtration and washing, drying at 180° C. for 10 hours, and then grinding and sieving through a 600-mesh sieve, the modified aluminum hydroxide is obtained.

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Abstract

The invention discloses a flame-retardant HDPE sub-pipe and a preparation method thereof, belonging to the technical field of plastic product processing. A flame-retardant HDPE sub-pipe comprises the following components in parts by weight: 60-70 parts of HDPE resin, modified 20-25 parts of permanent aluminum hydroxide, 4-6 parts of flame retardant synergist, 3-5 parts of lubricant and 1-2 parts of antioxidant; the modified aluminum hydroxide is made from the following raw materials in parts by weight: 50-60 parts of aluminum hydroxide, 6-8 parts of medical stone powder, 1-2 parts of glycerol monostearate, 100-120 parts of isopropyl alcohol and 1-2 parts of titanate coupling agent. The modified aluminum hydroxide of the present invention can improve its compatibility with HDPE resin, so that while improving the flame retardancy of the HDPE sub-pipe, the mechanical properties of the sub-pipe will not be significantly reduced.

Description

technical field [0001] The invention relates to the technical field of plastic product processing, in particular to a flame-retardant HDPE sub-pipe and a preparation method thereof. Background technique [0002] HDPE (High Density Polyethylene) is a white powder or granular resin with good wear resistance, electrical insulation, toughness, cold resistance and anti-aging properties. It can be used as a cable insulation material. The tube is located on the outer layer of the cable, which has the function of protecting the cable and preventing the cable from being damaged; however, due to the low oxygen index of HDPE, it is flammable and will produce a large number of molten droplets with ignition ability when it burns, which will further aggravate the burning. Therefore, flame retardant treatment of HDPE materials is required. [0003] At present, the most effective way to flame retardant HDPE is to add flame retardants. Flame retardants are generally divided into halogen-bas...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/06C08K13/06C08K9/04C08K3/22C08K3/02C08K3/38C08K3/34
CPCC08K13/06C08K9/04C08K3/22C08K3/02C08K3/38C08K3/34C08K2003/2227C08K2003/387C08K2003/026C08L23/06
Inventor 吴伟聪
Owner 深圳市深捷通管业发展有限公司
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