Camellia sinensis pest repellant from plant-source extract products
A technology of plant source extracts and insect repellents, applied in animal repellents, plant growth regulators, pest repellents, etc., can solve problems such as residual toxic substances and human body injury
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Embodiment 1
[0039] Embodiment 1: a kind of eutectic of carvacrol and fumaric acid, its preparation method is: prepare the ethanol solution of carvacrol and the ethanol solution of fumaric acid respectively, add the ethanol solution of fumaric acid under stirring condition into the ethanol solution of carvacrol, stirred and reacted at 50° C. for 4 hours, filtered to collect the solid, and dried.
[0040] The molar ratio of carvacrol and fumaric acid is 1:1.00; in the ethanol solution of carvacrol, the mass ratio of carvacrol and ethanol is 1:1.0; in the ethanol solution of fumaric acid, fumaric acid and ethanol The mass ratio is 1:2.0.
[0041] NMR test verifies that carvacrol and fumaric acid form a co-crystal.
[0042] The purity of the co-crystal of carvacrol and fumaric acid was 99.2% as tested by HPLC.
[0043] X-ray powder diffraction test such as figure 1 shown. The X-ray powder diffraction pattern expressed in 2θ of the cocrystal of carvacrol and fumaric acid has characteristi...
Embodiment 2
[0045] Embodiment 2: a kind of eutectic of carvacrol and fumaric acid, its preparation method is: prepare the ethanol solution of carvacrol and the ethanol solution of fumaric acid respectively, add the ethanol solution of fumaric acid under stirring condition into the ethanol solution of carvacrol, stirred and reacted at 48° C. for 5 hours, filtered to collect the solid, and dried.
[0046] The molar ratio of carvacrol and fumaric acid is 1:0.95; in the ethanol solution of carvacrol, the mass ratio of carvacrol and ethanol is 1:0.8; in the ethanol solution of fumaric acid, fumaric acid and ethanol The mass ratio is 1:1.8.
[0047] The purity of the co-crystal of carvacrol and fumaric acid was 97.8% as tested by HPLC.
[0048] The X-ray powder diffraction test is the same as in Example 1.
Embodiment 3
[0049] Embodiment 3: a kind of eutectic of carvacrol and fumaric acid, its preparation method is: prepare the ethanol solution of carvacrol and the ethanol solution of fumaric acid respectively, add the ethanol solution of fumaric acid under stirring condition into the ethanol solution of carvacrol, stirred and reacted at 52°C for 3 hours, filtered to collect the solid, and dried.
[0050] The molar ratio of carvacrol and fumaric acid is 1:1.05; in the ethanol solution of carvacrol, the mass ratio of carvacrol and ethanol is 1:1.2; in the ethanol solution of fumaric acid, fumaric acid and ethanol The mass ratio is 1:2.5.
[0051] The purity of the co-crystal of carvacrol and fumaric acid was 98.1% as tested by HPLC.
[0052] The X-ray powder diffraction test is the same as in Example 1.
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