High-heat-conductivity anisotropic polymer-based composite material and preparation method thereof

A composite material and anisotropic technology, applied in the field of thermally conductive composite material preparation, can solve the problems of high thermal resistance between fillers, low efficiency in increasing thermal conductivity, etc., and achieve the effects of simple preparation process, economical cost, and broad thermal conductivity application prospects.

Inactive Publication Date: 2019-09-13
SHANGHAI JIAO TONG UNIV
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  • Abstract
  • Description
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Problems solved by technology

[0004] The purpose of the present invention is to overcome the problems of low thermal conductivity increase efficiency and high thermal resistance between fillers of existing filled thermal conductive composite materials with the increase of filler content, and provide a kind of super-high in-plane thermal conductivity, low thermal resistance contact between fillers, and isotropic Anisotropic polymer-based composite material with high thermal conductivity and its preparation method characterized by heterogeneous structure and easy preparation

Method used

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  • High-heat-conductivity anisotropic polymer-based composite material and preparation method thereof
  • High-heat-conductivity anisotropic polymer-based composite material and preparation method thereof
  • High-heat-conductivity anisotropic polymer-based composite material and preparation method thereof

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Embodiment 1

[0038] This embodiment relates to a composite fiber and a method for preparing a composite material. The composite fiber is composed of boron nitride nanosheets covered with PVA nanofibers. The composite material is made by laminating composite fibers and hot pressing. The preparation process of composite materials such as figure 1 shown, prepared by the following steps:

[0039]A. Liquid phase exfoliation of hexagonal boron nitride (h-BN): According to the method of liquid phase ultrasonic exfoliation and centrifugal classification reported in the literature (Chen, et al., Adv. Funct. Mater. 2017, 27, 1604754.) Preparation of boron nitride nanosheets (BNNS);

[0040] B. Electrospinning of PVA: A certain amount of PVA white particle powder was dissolved in deionized water at a concentration of 18 wt%, and stirred in a beaker for 1 hour at ambient temperature. Then the stirred solution was left to stand for 0.5 h, and then transferred to a vacuum oven at room temperature for ...

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Abstract

The invention provides a high-heat-conductivity anisotropic polymer-based composite material and a preparation method thereof. The composite material is of an overlapped structure consisting of multiple composite fiber layers after overlapping and hot-pressing, wherein the composite fiber layers are formed by covering surfaces of polymer nanofibers by heat conduction fillers. In preparation, a heat conduction packing dispersion solution is sucked into an injector for high-pressure electrostatic spraying, and is adhered to the polymer nanofibers under the actions of electrostatic force and hydrogen bonds, then a network structure with fillers which contact with one another and are arranged in an orientation direction is formed, and after overlapping, the composite material is prepared through cold-pressing compression and hot-pressing molding. Due to the special structure of the composite material, efficient conduction paths are formed by the fillers in the composite material filled with the fillers, the purpose that the heat conductivity of the polymer-based composite material is remarkably improved by a small amount of the high heat conduction fillers can be achieved, and heat conduction requirements in preparing electronic and electric equipment can be met.

Description

technical field [0001] The invention belongs to the technical field of heat-conducting composite material preparation, and relates to a high-heat-conducting anisotropic polymer-based composite material and a preparation method thereof. Background technique [0002] With the miniaturization, high integration and multi-functionalization of modern electronic and electrical equipment, a large amount of heat has accumulated in the equipment, which may cause thermal failure or even explosion of these electronic and electrical equipment. Therefore, effective thermal management of these electrical and electronic devices is crucial for their performance, reliability and lifetime. In addition, in many cutting-edge technology fields, especially next-generation flexible electronic devices or cutting-edge aerospace technologies, there are additional stricter performance requirements for thermal management materials, such as electrical insulation, ultra-high in-plane lateral thermal condu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/02B32B27/12B32B37/06B32B37/10D04H1/728D01D5/00D06M11/80D06M101/24
CPCB32B5/02B32B5/26B32B37/06B32B37/10B32B2262/02B32B2307/302D01D5/0015D04H1/728D06M11/80D06M2101/24
Inventor 黄兴溢陈金江平开
Owner SHANGHAI JIAO TONG UNIV
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