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A method for extracting zeaxanthin from corn gluten enzymolysis jelly

A technology of corn gluten powder and zeaxanthin, which is applied in the fields of chemical industry, medicine, and food, can solve the problems of long time, difficult application, and limited improvement of extraction rate, and achieve the effects of promoting transformation, increasing yield, and improving purity

Active Publication Date: 2021-05-18
QILU UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Fat-soluble zeaxanthin is most easily combined with hydrophobicity) and other substances, and it is difficult to extract zeaxanthin from zein hydrolyzate by single methods such as microwave extraction, supercritical extraction, and multi-solvent extraction. The yield of zeaxanthin thus obtained is very low. For example, in Chinese patent CN103073914A "A method for extracting zeaxanthin from zein", it uses microwave extraction to extract zeaxanthin from zein. According to its background Technology and invention content, although it can overcome ordinary solvent extraction and high-tech auxiliary extraction, such as patent CN1306045A "Preparation method of corn yellow pigment" disclosed in the use of different solvent extraction from small to large polarity, the polarity is small The use of hexane and ethyl acetate, propanol, etc., is the most polar choice, and after extraction, it is treated with enzyme preparations, which takes a long time and complicated operations; Higher but expensive equipment, difficult to apply to industrial production, and the problem of low extraction rate; and can overcome such as patent application CN101280121A disclosed, using microwave-ultrasonic extraction of zeaxanthin, shorten the extraction time, but the thermal effect caused by high-power microwave It is difficult to control the temperature of the reaction system, which is unfavorable for industrial production, and the elution of n-hexane may cause difficult-to-handle solvent residues and difficult application problems in the food processing industry. However, the technical scheme disclosed in CN103073914A itself has limited improvement in the extraction rate. rate is still low

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Take corn gluten powder and grind it through a 60-mesh sieve, take 100 g of the sieved corn gluten powder, add 500 mL of tap water, and mix well; adjust the pH to 7 with 30% NaOH solution, and let it soak for 3 hours. When the water bath is heated under stirring until the temperature of the feed liquid is 42°C, according to the composition of the sieved corn gluten powder and compound protease (subtilisin, streptomycin and aminopeptidase, the compound ratio is 4:3:3 (W:W:W), the three enzymes were respectively purchased from Novozymes) = 100:3 (w / w) ratio, 3 g of complex protease was added, and the enzymatic hydrolysis was performed for 24 hours. Pour out the feed solution after enzymatic hydrolysis, and dry it in an oven at 65°C for 16 hours. Crush to a fine powder. Add 500mL 95% ethanol for extraction for 12 hours, filter to obtain the first filtrate and filter residue, and set aside the filtrate, add 500mL 95% ethanol to the filter residue, extract at 55°C for 1 hou...

Embodiment 2

[0038] Take corn gluten powder and crush it through an 80-mesh sieve, take 100 g of the sieved corn gluten powder, add 400 mL of tap water, and mix well; adjust the pH to 7.2 with 10% NaOH solution, let it stand for 2 hours to soak, and obtain a feed liquid. When heating in a water bath with stirring until the temperature of the feed liquid is 38°C, add 2.5 g of the compound protease at a ratio of 100:2.5 (w / w) of the sieved corn gluten powder and the compound protease, and perform enzymatic hydrolysis for 36 hours. Pour out the feed solution after enzymolysis, and dry it in an oven at 75°C for 14 hours. Crush to a fine powder. Add 400mL of absolute ethanol, stir and extract for 8h, filter to obtain the first filtrate and filter residue, and use the filtrate for later use; add 400mL of absolute ethanol to the filter residue, extract at 65°C for 2h, filter to obtain the second filtrate and filter residue, and use the filtrate for later use; repeat the second time The extractio...

Embodiment 3

[0040] Take corn gluten powder and crush it through a 40-mesh sieve, take 100 g of the sieved corn gluten powder, add 600 mL of tap water and mix well; adjust the pH to 6.8 with 20% NaOH solution, and let it soak for 4 hours. When heating in a water bath with stirring until the temperature of the feed liquid is 45°C, add 4.5 g of compound protease according to the ratio of the sieved corn gluten powder and compound protease = 100:4.5 (w / w), enzymolyze for 12 hours, and pour out the enzyme The decomposed feed liquid was dried in an oven at 55°C for 20 hours, and then crushed into fine powder. Add 600mL of 95% ethanol, stir and extract for 4h, filter to obtain the first filtrate and filter residue, and set aside the filtrate, add 600mL of 95% ethanol to the filter residue, extract at 50°C for 1.5h, filter to obtain the second filtrate and filter residue, and set aside the filtrate. Repeat the second extraction process once, that is, heat extraction for 2 times in total, and filt...

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PUM

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Abstract

The present invention provides a method for extracting zeaxanthin from corn gluten meal enzymatic hydrolysis colloid, wherein the corn gluten meal enzymatic hydrolysis colloid is a reddish-brown jelly obtained by processing corn gluten meal; the The method for treating the corn gluten meal includes: performing the first alkali treatment on the corn gluten meal, enzymatic hydrolysis, alcohol extraction, and then extracting the filtrate and evaporating to dryness. The method of the invention can better realize the effective separation of zeaxanthin and corn polypeptide substances, and improve the yield and purity of zeaxanthin.

Description

technical field [0001] The invention relates to the fields of chemical industry, medicine and food, in particular to a method for extracting zeaxanthin from enzymatically hydrolyzed jelly of corn gluten powder. Background technique [0002] The information disclosed in this background section is only intended to increase the understanding of the general background of the present invention, and is not necessarily taken as an acknowledgment or any form of suggestion that the information constitutes the prior art already known to those skilled in the art. [0003] There are 11 double bonds in the molecular structure of zeaxanthin, which constitute a large conjugated system, which can block free radical chain transmission, and play an anti-inflammatory role in organisms by reducing the reactivity of free radical singlet oxygen and photosensitizers. oxidation. The hydroxyl groups on the rings at both ends strengthen the antioxidant effect. Zeaxanthin can prevent ultraviolet ray...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C12P23/00C07C403/24
CPCC07C403/24C12P23/00
Inventor 王永敏
Owner QILU UNIV OF TECH