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Aluminum profile anode oxidizing electrolyte, preparation method thereof and aluminum profile anode oxidizing process

An anodizing and electrolyte technology, applied in electrolytic coatings, surface reaction electrolytic coatings, coatings, etc., can solve the problems of poor electrolyte stability, color change of oxide film, uneven thickness, etc., to enhance corrosion resistance. The effect of improving corrosion resistance and film performance

Active Publication Date: 2019-10-08
ANHUI LANT ALUMINUM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The anodized film obtained by this process is more uniform, more compact and less porous, but the oxalic acid in the electrolyte not only has certain toxicity, but also is reduced to glycolic acid on the cathode and oxidized to carbon dioxide on the anode, resulting in The stability of the electrolyte becomes poor, which will cause the color of the final oxide film to change with the change of the oxidation process, and the thickness is extremely uneven
In addition, the nickel salt used in the sealing process will also bring some pollution to the environment.

Method used

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  • Aluminum profile anode oxidizing electrolyte, preparation method thereof and aluminum profile anode oxidizing process

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Embodiment 1

[0035] In this embodiment, the electrolyte is prepared through the following three steps:

[0036] (1) preparing phytic acid solution: dissolving phytic acid in water to obtain a phytic acid solution with a concentration of 225g / L;

[0037] (2) preparation of fulvic acid solution: fulvic acid is dissolved in water to obtain a concentration of fulvic acid solution of 87.5g / L;

[0038] (3) Preparation of electrolyte: the phytic acid solution prepared in step (1) is mixed with the fulvic acid solution prepared in step (2) in equal volumes, and ultrasonically mixed to obtain a mixed solution, which is added to the mixed solution in stirring Add dropwise a sodium hydroxide solution with a concentration of 0.1mol / L until the pH of the mixed solution is 2.5, then add water to the mixed solution to obtain an electrolyte, the concentration of phytic acid in the electrolyte is 90g / L, fulvic acid The concentration in the electrolyte is 35g / L.

[0039] The anodizing process of aluminum ...

Embodiment 2

[0047] In this embodiment, the electrolyte is prepared through the following three steps:

[0048] (1) preparing phytic acid solution: dissolving phytic acid in water to obtain a phytic acid solution with a concentration of 200g / L;

[0049] (2) preparation of fulvic acid solution: fulvic acid is dissolved in water to make a concentration of 102g / L fulvic acid solution;

[0050] (3) Preparation of electrolyte: the phytic acid solution prepared in step (1) is mixed with the fulvic acid solution prepared in step (2) in equal volumes, and ultrasonically mixed to obtain a mixed solution, which is added to the mixed solution in stirring Add dropwise a sodium hydroxide solution with a concentration of 0.1mol / L until the pH value of the mixed solution is 2.8, then add water to the mixed solution to obtain an electrolyte, the concentration of phytic acid in the electrolyte is 80g / L, fulvic acid The concentration in the electrolyte is 40.8g / L.

[0051] The anodizing process of aluminu...

Embodiment 3

[0059] In this embodiment, the electrolyte is prepared through the following three steps:

[0060] (1) preparing phytic acid solution: dissolving phytic acid in water to obtain a phytic acid solution with a concentration of 175g / L;

[0061] (2) preparation of fulvic acid solution: fulvic acid is dissolved in water to make a concentration of 137.5g / L fulvic acid solution;

[0062] (3) Preparation of electrolyte: the phytic acid solution prepared in step (1) is mixed with the fulvic acid solution prepared in step (2) in equal volumes, and ultrasonic dispersion is used to uniformly obtain a mixed solution, which is added to the mixed solution in stirring Add dropwise a sodium hydroxide solution with a concentration of 0.05mol / L until the pH value of the mixed solution is 2.0, then add water to the mixed solution to obtain an electrolyte, the concentration of phytic acid in the electrolyte is 70g / L, fulvic acid The concentration in the electrolyte is 55g / L.

[0063] The anodizin...

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Abstract

The invention discloses aluminum profile anode oxidizing electrolyte, a preparation method thereof and an aluminum profile anode oxidizing process and belongs to the technical field of electrolysis orelectrophoretic processes. The electrolyte is composed of phytic acid, fulvic acid, a PH conditioning agent and water, the concentration of the phytic acid in the electrolyte is 70-90 g / L, the concentration of the fulvic acid in the electrolyte is 35-55 g / L, and the PH value of the electrolyte is 2.0-2.8. On the one hand, the phytic acid of the electrolyte is mainly sourced from root trunks, stems and seeds of plants, the fulvic acid can be used for a medical purpose, and therefore, the electrolyte mainly composed of the phytic acid and the fulvic acid is completely poisonous and harmless andis environmentally friendly; and on the other hand, aluminum ions dispersed into a solution and a complex formed by the phytic acid and the aluminum ions can be adsorbed to a position nearby an aluminum profile, a complex of phytic acid and Al<3+> is also formed on the surface of aluminum oxide while hole sealing is assisted, a layer of compact hydrophobic protective film is produced, a chemicaldissolution effect of the electrolyte on the oxidation film is retarded, the performance of the film is improved, and the corrosion resistance of the oxidation film is enhanced.

Description

technical field [0001] The invention belongs to the technical field of electrolysis or electrophoresis technology, and in particular relates to an anodic oxidation electrolyte for aluminum profiles, a preparation method thereof, and an anodic oxidation process for aluminum profiles. Background technique [0002] Due to the advantages of low density, high specific strength, good formability, good thermal and electrical conductivity, and low price, aluminum alloys are widely used in the fields of construction and decoration, transportation, aerospace, and weapon manufacturing. In order to improve the anti-corrosion performance of aluminum alloy, the surface treatment method of one-time anodic oxidation is usually used to form an oxide film with corrosion resistance. However, because the oxide film has a disordered porous structure, its corrosion resistance is still poor and cannot meet some requirements. Fields with high requirements for anti-corrosion. [0003] Therefore, on...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25D11/10C25D11/12C25D11/16
CPCC25D11/10C25D11/12C25D11/16
Inventor 潘祖堂熊茂清袁学兵
Owner ANHUI LANT ALUMINUM
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