This invention provides a
polymer electrolyte, its preparation method, and its application. The raw materials of the
polymer electrolyte, by
mass, include the following components: 8-12 parts of an olefin
polymer, 4-8 parts of a
sodium salt, 0.4-1.2 parts of hydrophobic
fumed silica (SiO2), 7-30 parts of a fluorinated small-molecule
plasticizer, and 35-85 parts of a
solvent. The polymer
electrolyte of this invention uses a fluorinated small-molecule
plasticizer with weak
solvation ability as the
plasticizer in the electrolyte, which improves the mechanical properties of the electrolyte membrane. Simultaneously, it forms a competitive coordination effect with the
residual solvent with strong
solvation ability, which is beneficial for inhibiting the
corrosion effect of
sodium salt on the
current collector. The hydrophobic
fumed silica filler reduces the
crystallinity of the polymer matrix and enhances the mobility of the polymer matrix segments, thereby improving the
ionic conductivity.