A kind of technological method of increasing the strength failure period of containerboard paper
A process method and exhaustion period technology, applied in the field of containerboard paper preparation, can solve the problems of reducing paper strength, easy moisture absorption of paper, low degree of polymerization, etc., and achieve the effect of improving dry strength and wet strength
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Embodiment 1
[0018] The specific preparation method of the wet strength agent is as follows: ①Put 12.2g of salicylaldehyde and 55mL of pyridine solution into the reaction vessel at the same time, and add 12.48g of malonic acid into it, stir and react for 18-20h at room temperature, and then evaporate to remove pyridine , while alkaline decompression distillation removes unreacted malonic acid wherein, obtains 2-(2-hydroxybenzylidene) malonic acid;
[0019] ② Weigh 11.2g of N-isopropylacrylamide and 18g of chloropropane into 50mL of acetone at the same time, add 1.3g of sodium hydroxide to it at the same time, then raise the temperature to 130-140°C, and reflux under the pressure of 1-2MPa for 24 -25h, then carry out underpressure distillation to obtain propenyl quaternary ammonium salt;
[0020] ③Add 20.9g of 2-(2-hydroxybenzylidene)malonic acid and 60mL of pyridine prepared in step ① into a three-necked flask, then add 15.2g of benzoyl peroxide and 23.5g of propenyl quaternary ammonium sa...
Embodiment 2
[0022] The specific preparation method of the wet strength agent is as follows: ①Put 10.6g of benzaldehyde and 55mL of pyridine solution into the reaction vessel at the same time, and add 12.48g of malonic acid thereinto, stir and react for 18-20h under normal temperature conditions, then evaporate to remove pyridine, Simultaneously basic underpressure distillation removes unreacted malonic acid wherein, obtains 2-(2-hydroxybenzylidene) malonic acid;
[0023] ② Weigh 11.2g of N-isopropylacrylamide and 18g of chloropropane into 50mL of acetone at the same time, add 1.3g of sodium hydroxide to it at the same time, then raise the temperature to 130-140°C, and reflux under the pressure of 1-2MPa for 24 -25h, then carry out underpressure distillation to obtain propenyl quaternary ammonium salt;
[0024] ③Add 19.2g of 2-(2-hydroxybenzylidene)malonic acid and 60mL of pyridine prepared in step ① into a three-necked flask, then add 15.2g of benzoyl peroxide and 23.5g of propenyl quater...
Embodiment 3
[0026]The specific preparation method of the wet strength agent is as follows: ①Put 12.2g of salicylaldehyde and 55mL of pyridine solution into the reaction vessel at the same time, and add 12.48g of malonic acid into it, stir and react for 18-20h at room temperature, and then evaporate to remove pyridine , while alkaline decompression distillation removes unreacted malonic acid wherein, obtains 2-(2-hydroxybenzylidene) malonic acid;
[0027] ②Add 20.9g of 2-(2-hydroxybenzylidene)malonic acid and 60mL of pyridine prepared in step ① into a three-necked flask, and then add 11.2g of N-isopropylacrylamide and 23.5g of propenyl quaternary ammonium salt, heated up to 120-125° C. for reflux reaction for 8-10 hours, and subjected to vacuum distillation to obtain a powdered wet strength agent.
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