A kind of technological method of increasing the strength failure period of containerboard paper

A process method and exhaustion period technology, applied in the field of containerboard paper preparation, can solve the problems of reducing paper strength, easy moisture absorption of paper, low degree of polymerization, etc., and achieve the effect of improving dry strength and wet strength

Active Publication Date: 2021-07-27
SHANYING INT HLDG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Normally, after the paper is completely wetted by water, its tensile and burst strength are only 10%-20% of its original dry strength, so the paper whose wet strength can maintain more than 30% of the dry strength is wet strength paper. Due to the high hygroscopicity of paper fiber, paper is easy to get wet in a humid environment, and the paper fiber in the paper is easy to disperse after getting wet, thereby reducing the strength of the paper. Therefore, in the prior art, it is usually added to the paper Wet strength agent, through the wet strength agent to achieve cross-linking polymerization between paper fibers, which can effectively prevent the dispersion of paper fibers in the environment with high humidity, and realize the improvement of paper strength, but due to the existing wet strength agent and paper fiber The force between them is weaker, so that the degree of polymerization is lower, which in turn makes the wet strength increase of the paper lower
At the same time, paper is easy to absorb moisture. After absorbing moisture, the entire paper including the paper core is completely wet, and it is difficult to dry naturally, which will cause the paper to stay in a wet state for a long time, reducing its strength.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] The specific preparation method of the wet strength agent is as follows: ①Put 12.2g of salicylaldehyde and 55mL of pyridine solution into the reaction vessel at the same time, and add 12.48g of malonic acid into it, stir and react for 18-20h at room temperature, and then evaporate to remove pyridine , while alkaline decompression distillation removes unreacted malonic acid wherein, obtains 2-(2-hydroxybenzylidene) malonic acid;

[0019] ② Weigh 11.2g of N-isopropylacrylamide and 18g of chloropropane into 50mL of acetone at the same time, add 1.3g of sodium hydroxide to it at the same time, then raise the temperature to 130-140°C, and reflux under the pressure of 1-2MPa for 24 -25h, then carry out underpressure distillation to obtain propenyl quaternary ammonium salt;

[0020] ③Add 20.9g of 2-(2-hydroxybenzylidene)malonic acid and 60mL of pyridine prepared in step ① into a three-necked flask, then add 15.2g of benzoyl peroxide and 23.5g of propenyl quaternary ammonium sa...

Embodiment 2

[0022] The specific preparation method of the wet strength agent is as follows: ①Put 10.6g of benzaldehyde and 55mL of pyridine solution into the reaction vessel at the same time, and add 12.48g of malonic acid thereinto, stir and react for 18-20h under normal temperature conditions, then evaporate to remove pyridine, Simultaneously basic underpressure distillation removes unreacted malonic acid wherein, obtains 2-(2-hydroxybenzylidene) malonic acid;

[0023] ② Weigh 11.2g of N-isopropylacrylamide and 18g of chloropropane into 50mL of acetone at the same time, add 1.3g of sodium hydroxide to it at the same time, then raise the temperature to 130-140°C, and reflux under the pressure of 1-2MPa for 24 -25h, then carry out underpressure distillation to obtain propenyl quaternary ammonium salt;

[0024] ③Add 19.2g of 2-(2-hydroxybenzylidene)malonic acid and 60mL of pyridine prepared in step ① into a three-necked flask, then add 15.2g of benzoyl peroxide and 23.5g of propenyl quater...

Embodiment 3

[0026]The specific preparation method of the wet strength agent is as follows: ①Put 12.2g of salicylaldehyde and 55mL of pyridine solution into the reaction vessel at the same time, and add 12.48g of malonic acid into it, stir and react for 18-20h at room temperature, and then evaporate to remove pyridine , while alkaline decompression distillation removes unreacted malonic acid wherein, obtains 2-(2-hydroxybenzylidene) malonic acid;

[0027] ②Add 20.9g of 2-(2-hydroxybenzylidene)malonic acid and 60mL of pyridine prepared in step ① into a three-necked flask, and then add 11.2g of N-isopropylacrylamide and 23.5g of propenyl quaternary ammonium salt, heated up to 120-125° C. for reflux reaction for 8-10 hours, and subjected to vacuum distillation to obtain a powdered wet strength agent.

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PUM

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Abstract

The invention discloses a process method for improving the strength failure period of container board paper. The specific process is as follows: the pulp in the pulp tower is transported to the mixed pulp tank through the pulp pump to be fully mixed, and then sent to the paper machine by the mixed pulp pump Pulp tank, add wet strength agent in the pulp tank of the paper machine and mix evenly; transport the mixed slurry in the pulp tank of the paper machine to the mixer through the pulp pump of the paper machine, and add neutral sizing agent into the mixer at the same time After mixing evenly, the pulp is flushed by the pulp pump, and then goes through the pressure screen to remove impurities and the pulse tank to reduce the pulse, and then enters the surface layer headbox; the pulp is made into paper, and then sizing on the surface of the paper. In the present invention, a wet strength agent is added in the pulp preparation process, and the paper fibers are cross-linked into a network structure through the wet strength agent, thereby improving the dry strength and wet strength of the paper, and adding a neutral sizing agent in the paper, The core of the prepared paper is made waterproof, and the relative wet strength of the paper is further improved.

Description

technical field [0001] The invention belongs to the field of boxboard paper preparation and relates to a process method for improving the strength failure period of the boxboard paper. Background technique [0002] Normally, after the paper is completely wetted by water, its tensile and burst strength are only 10%-20% of its original dry strength, so the paper whose wet strength can maintain more than 30% of the dry strength is wet strength paper. Due to the high hygroscopicity of paper fiber, paper is easy to get wet in a humid environment, and the paper fiber in the paper is easy to disperse after getting wet, thereby reducing the strength of the paper. Therefore, in the prior art, it is usually added to the paper Wet strength agent, through the wet strength agent to achieve cross-linking polymerization between paper fibers, which can effectively prevent the dispersion of paper fibers in the environment with high humidity, and realize the improvement of paper strength, but...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D21H27/10D21H21/20D21H17/06D21H17/07D21H17/14D21H17/11D21H17/64D21H21/18D21H21/16D21H19/14
CPCD21H17/06D21H17/07D21H17/11D21H17/14D21H17/64D21H17/72D21H17/74D21H19/14D21H21/16D21H21/18D21H21/20D21H27/10
Inventor 陈学萍宋杰高宽刘召强
Owner SHANYING INT HLDG CO LTD
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