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Environmentally-friendly antirust oil for iron-based powder metallurgy parts and preparation method of antirust oil

An iron-based powder metallurgy, anti-rust oil technology, applied in the petroleum industry, lubricating composition and other directions, can solve the problems of environmental and human hazards, poor rust-proof oil-water replacement ability, difficult to enter the gap, etc., and achieves good salt spray resistance. Effect

Active Publication Date: 2019-11-12
GUANGZHOU LANDNOK CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, for iron-based powder metallurgy parts, they are all made by sintering metal powder. There must be many pores inside the product, and the water in the pores is difficult to discharge, and rust is more likely to occur. However, the existing anti-rust oil and water replacement The ability is poor, it is not easy to immerse into the gap of the metal substrate, and it cannot prevent the corrosion of the metal substrate by the pore water, and almost 90% of the existing antirust oils are based on oil-soluble barium sulfonate. Oil-soluble barium salt itself is non-toxic, but if it is scattered in the natural environment, it will decompose into toxic soluble barium salt, which is a serious hazard to the environment and human body
Therefore, the comprehensive antirust performance of the existing antirust oil is poor, and it is difficult to guarantee the working performance and service life of the equipment

Method used

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  • Environmentally-friendly antirust oil for iron-based powder metallurgy parts and preparation method of antirust oil
  • Environmentally-friendly antirust oil for iron-based powder metallurgy parts and preparation method of antirust oil

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preparation example Construction

[0069] The second aspect of the present invention provides a method for preparing an environmentally friendly antirust oil for iron-based powder metallurgy parts, the steps comprising:

[0070] (1) Add the base oil into the blending kettle, stir at 40-50°C for 20-40min, and prepare the base oil mixture A;

[0071] (2) Add barium-free sulfonate into the blending kettle, heat up to 110-120°C and stir at constant temperature for 40-60min to prepare barium-free sulfonate mixture B;

[0072] (3) Add the antirust agent into the blending kettle, heat up to 70-80°C and stir at a constant temperature for 20-40min to prepare antirust agent mixture C;

[0073] (4) Add mixtures A, B, C, auxiliary agents and antioxidants into a blending kettle, stir at 40-50°C for 20-40 minutes, filter and pack in a tank to obtain the environmentally friendly anti-rust oil.

Embodiment 1

[0077] Example 1 provides an environmentally friendly antirust oil for iron-based powder metallurgy parts, which includes the following components in parts by weight: 60 parts of base oil, 3 parts of barium-free sulfonate, 2 parts of antirust agent, and 1 part of auxiliary agent part, 0.1 part of antioxidant.

[0078] The base oil is composed of D80 solvent oil and No. 10 transformer oil according to the ratio of 1:9;

[0079] The barium-free sulfonate is composed of sodium petroleum sulfonate, calcium dinonylnaphthalene sulfonate, and synthetic calcium sulfonate with high alkali value in a weight ratio of 6:1:1;

[0080] The antirust agent is composed of dodecenylsuccinate half ester, sorbitan oleate, and oxidized paraffin butyl ester in a weight ratio of 1:2:4;

[0081] The auxiliary agent is composed of ethylene glycol butyl ether and fatty alcohol polyoxyethylene ether in a weight ratio of 1:1;

[0082] The antioxidant is 2,6-di-tert-butyl-p-cresol.

[0083] A method fo...

Embodiment 2

[0089] Embodiment 2 provides an environmentally friendly antirust oil for iron-based powder metallurgy parts, which includes the following components in parts by weight: 90 parts of base oil, 20 parts of barium-free sulfonate, 20 parts of antirust agent, and 10 parts of auxiliary agent 1 part, antioxidant 1 part.

[0090] The base oil is composed of D80 solvent oil and No. 10 transformer oil according to the ratio of 1:7;

[0091] The barium-free sulfonate is composed of sodium petroleum sulfonate, calcium dinonylnaphthalene sulfonate, and synthetic calcium sulfonate with high alkali value in a weight ratio of 6:1:1;

[0092] The antirust agent is composed of dodecenylsuccinate half ester, sorbitan oleate, and oxidized paraffin butyl ester in a weight ratio of 1:2:4;

[0093] The auxiliary agent is composed of ethylene glycol butyl ether and fatty alcohol polyoxyethylene ether in a weight ratio of 1:1;

[0094] The antioxidant is 2,6-di-tert-butyl-p-cresol.

[0095] A metho...

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Abstract

The invention belongs to the technical field of metal processing, and more particularly relates to environmentally-friendly antirust oil for iron-based powder metallurgy parts and a preparation methodof the antirust oil. The environmentally-friendly antirust oil for the iron-based powder metallurgy parts comprises the following components, in parts by weight: 60-90 parts of base oil, 3-20 parts of a barium-free sulfonate, 0.1-20 parts of a rust inhibitor, 0.5-10 parts of an auxiliary agent and 0.1-1 part of an antioxidant. According to the environmentally-friendly antirust oil for the iron-based powder metallurgy parts provided by the invention, the base oil, the barium-free sulfonate, the rust inhibitor, the auxiliary agent and the antioxidant are adopted for compounding to provide highantirust performance, different from a traditional antirust method of powder metallurgy which needs high-temperature cooking, the product provided by the invention is immersed at room temperature andcan be quickly penetrated into metal gaps to discharge moisture in pores and the metal surface out, after draining is performed, an oil film is thin and non-sticky, has good salt spray resistance andmeets the antirust requirements for sea export of products, and the product does not contain heavy metals such as barium and is safe and environmentally friendly.

Description

technical field [0001] The invention belongs to the technical field of metal processing. More specifically, the invention relates to an environment-friendly antirust oil for iron-based powder metallurgy parts and a preparation method thereof. Background technique [0002] Metal corrosion has been a problem that has plagued people for a long time. The loss caused by metal corrosion is extremely heavy. According to the statistics of the American Institute of Metals, the annual economic loss caused by metal corrosion in the world accounts for 4% of the total production value, and the scrap metal due to corrosion accounts for 4% of the total output. 30% of my country's annual economic losses due to metal corrosion amounted to more than 300 billion yuan. In order to avoid corrosion and reduce losses, people have adopted various protection methods, among which, using various anti-rust oils to protect metal workpieces is one of the most common protection methods at present. [0003...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10M169/04C10N30/12
CPCC10M169/044C10M2207/026C10M2207/046C10M2207/141C10M2207/281C10M2207/282C10M2209/104C10M2209/109C10M2219/044
Inventor 毛志铭陈郁明郭璐瑶黄天辉
Owner GUANGZHOU LANDNOK CHEM TECH
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