High-efficiency environment-friendly acidic soap washing agent, and preparation method thereof

An environment-friendly, soaping agent technology, applied in the directions of surface active detergent composition, thioether preparation, detergent composition, etc., can solve problems such as environmental eutrophication, achieve strong deposition ability, good soaping effect, reduce The effect of discharge pressure

Active Publication Date: 2019-11-26
SHANDONG EFIRM BIOCHEMISTRY & ENVIRONMENTAL PROTECTION CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to solve the above-mentioned technical problems, the present invention provides a high-efficiency and environment-friendly acidic soaping agent, which has a better effect of removing floating colors, ensures the color fastness and brightness of fabrics, and does not contain nitrog

Method used

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  • High-efficiency environment-friendly acidic soap washing agent, and preparation method thereof
  • High-efficiency environment-friendly acidic soap washing agent, and preparation method thereof
  • High-efficiency environment-friendly acidic soap washing agent, and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Carboxyethylthiosuccinic acid: take by weighing 107.8g (1.10mol) maleic anhydride and dissolve in 300g water, heat to 90°C, add 108.16g of 3-mercaptopropionic acid with a mass fraction of 98% dropwise with a constant pressure funnel, The dropping time is controlled at 1h, after stirring evenly, add maleic anhydride and 3-mercaptopropionic acid with 10% triethylamine, react at a constant temperature of 90°C for 3h, then cool and crystallize, filter to obtain a white solid, and dry it in an oven to obtain carboxyl Ethylthiosuccinic acid, the yield is 97%;

[0031] Complexing agent: Weigh 261g (1.0mol) of 2,3-dithio(2-mercapto)-1-propanethiol into a three-necked flask equipped with a stirring paddle, heat to 55°C in a water bath, and add 62g in 3 times (2.0mol) sulfur solid, reacted for 1h under stirring conditions, after the reaction was completed, cooled to room temperature to obtain a transparent liquid, filtered to obtain a liquid product, weighed, and the yield was 85...

Embodiment 2

[0034] Carboxyethylthiosuccinic acid: Weigh 102.96g (1.05mol) of maleic anhydride and dissolve it in 300g of water, heat to 90°C, add 108.16g of 98% 3-mercaptopropionic acid dropwise with a constant pressure funnel, and the dropping time Controlled at 1h, after stirring evenly, add maleic anhydride and 3-mercaptopropionic acid resin catalyst SepliteLSZ-106 with 10% of the total mass, react at a constant temperature of 90°C for 3h, then cool and crystallize, filter to obtain a white solid, and dry it in an oven to obtain Carboxyethylthiosuccinic acid, yield 96%;

[0035] Complexing agent: Weigh 261g (1.0mol) of 2,3-dithio(2-mercapto)-1-propanethiol into a three-necked flask equipped with a stirring paddle, heat to 60°C in a water bath, and add 48g in 5 times (1.5mol) sulfur solid, reacted under stirring conditions for 2h, after the reaction was completed, lowered to room temperature to obtain a transparent liquid, filtered to obtain a liquid product, weighed, and the yield was ...

Embodiment 3

[0038] Carboxyethylthiosuccinic acid: Weigh 102.96g (1.05mol) of maleic anhydride and dissolve it in 300g of water, heat to 90°C, add 108.16g of 98% 3-mercaptopropionic acid dropwise with a constant pressure funnel, and the dropping time Control it for 1 hour, after stirring evenly, add SepliteLSZ-106S with 10% of the total mass of maleic anhydride and 3-mercaptopropionic acid, react at a constant temperature of 90°C for 3 hours, then cool and crystallize, filter to obtain a white solid, and dry it in an oven to obtain carboxyethyl Thiosuccinic acid, yield 96%;

[0039] Complexing agent: Weigh 261g (1.0mol) of 2,3-dithio(2-mercapto)-1-propanethiol into a three-necked flask equipped with a stirring paddle, heat to 60°C in a water bath, and add 48g in 4 times (1.5mol) sulfur solid, reacted under stirring conditions for 3h, after the reaction was completed, lowered to room temperature to obtain a transparent liquid, filtered to obtain a liquid product, weighed, and the yield was ...

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Abstract

The invention belongs to the field of fine chemistry, and more specifically relates to a high-efficiency environment-friendly acidic soap washing agent, and a preparation method thereof. The high-efficiency environment-friendly acidic soap washing agent comprises, by mass, 10 to 30 parts of carboxyalkylthiosuccinic acid, 30 to 50 parts of acrylic acid-2-acrylamido-2-methyl propyl sulfonic acid (AA/AMPS) copolymer 20 to 50 parts of sodium gluconate, 5 to 10 parts of hydrolytic polymaleic anhydride, 0.1 to 2 parts of a surfactant, 0.5 to 10 parts of a complexing agent, and 30 to 50 parts of water. When the high-efficiency environment-friendly acidic soap washing agent is used in cotton and cotton blended fabric reactive dye dying, surface dyeing removing effect is better, and fabric color fastness and brightness are ensured; the high-efficiency environment-friendly acidic soap washing agent contains no nitrogen and phosphorus, and is relatively high in acidity, so that the acid neutralizing process before common soaping can be avoided, waste discharge amount is reduced, human labor is saved, electricity cost is reduced, and better market advantages are achieved.

Description

technical field [0001] The invention belongs to the field of fine chemicals, and in particular relates to an efficient and environment-friendly acid soaping agent and a preparation method thereof. Background technique [0002] A common problem in the textile dyeing and finishing industry is the problem of incomplete dyeing and low color fastness of subsequent fabrics during the dyeing and color fixing process. Therefore, after dyeing, the fabric needs to be washed with a large amount of water and soaped to remove floating colors. , Improve the color fastness of the fabric to meet the needs of customers. [0003] Traditional soaping agents mostly use phosphorus and nitrogen-containing substances, which cause serious eutrophication to the environment; conventional soaping processes mainly use neutral soaping agents, and a large amount of water washing and pickling must be selected before soaping to reduce the concentration of the working fluid in the soaping process. PH, to r...

Claims

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Application Information

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IPC IPC(8): C11D1/62C11D3/60C11D3/37C11D3/20C11D3/34C11D1/68C07C319/14C07C321/14D06P5/04D06P5/08D06P5/10D06P3/66
CPCC07C319/14C11D1/62C11D1/66C11D3/2082C11D3/2086C11D3/3427C11D3/3765C11D3/3773D06P3/66D06P5/04D06P5/08D06P5/10C07C321/14
Inventor 邢莹莹曹飞羽孔凡波刘洋张建林马韵升
Owner SHANDONG EFIRM BIOCHEMISTRY & ENVIRONMENTAL PROTECTION CO LTD
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