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A chemical pretreatment method for organic waste gas containing styrene components

A technology of organic waste gas and styrene, applied in chemical instruments and methods, separation methods, gas treatment, etc., can solve problems such as hidden dangers, pipeline and device blockage safety, etc.

Active Publication Date: 2022-06-28
CHINA PETROLEUM & CHEM CORP +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to solve the technical defects in the above-mentioned prior art, the present invention proposes a chemical pretreatment method for organic waste gas containing styrene components. Modification treatment, realizing low-temperature self-polymerization of styrene components at the inlet of the pipeline, so as to solve the problems of blockage and safety hazards caused by the polymerization of styrene to pipelines and devices

Method used

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  • A chemical pretreatment method for organic waste gas containing styrene components

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Embodiment 1

[0031] Specific steps include:

[0032] The first step, the 13X molecular sieve produced by the purchased commercialized Transung company is mixed with the phosphoric acid aqueous solution, extruded on the twin-screw extruder, and the concentration of the phosphoric acid aqueous solution used is 0.15mol / L;

[0033] The second step is to place the formed 13X molecular sieve to dry naturally at room temperature for 12 hours, and then place it in an oven and dry it at 120°C for 12 hours;

[0034] The third step, prepare a certain concentration of titanium chloride solution, the concentration is 0.35mol / L;

[0035] In the fourth step, the dried 13X molecular sieve is placed in the above titanium chloride solution, and electromagnetically stirred for 2 hours, taken out and calcined at 450° C. for 6 hours to obtain the modified 13X molecular sieve.

Embodiment 2

[0037] Specific steps include:

[0038] The first step, the 13X molecular sieve produced by the purchased commercial Transung company is mixed with the phosphoric acid aqueous solution, extruded on the twin-screw extruder, and the concentration of the phosphoric acid aqueous solution used is 0.30mol / L;

[0039] The second step is to place the formed 13X molecular sieve to dry naturally at room temperature for 12 hours, and then place it in an oven to dry at 150°C for 8 hours;

[0040] The third step, prepare a certain concentration of ferric chloride solution, the concentration is 0.40mol / L;

[0041] In the fourth step, the dried 13X molecular sieve is placed in the above titanium chloride solution, and electromagnetically stirred for 1 hour, taken out and calcined at 350° C. for 10 hours to obtain the modified 13X molecular sieve.

Embodiment 3

[0043] The first step, the 13X molecular sieve produced by the purchased commercial Transung company is mixed with the phosphoric acid aqueous solution, extruded on the twin-screw extruder, and the concentration of the phosphoric acid aqueous solution used is 0.7mol / L;

[0044] The second step is to place the formed 13X molecular sieve to dry naturally at room temperature for 12h, and then place it in an oven and dry it at 110°C for 6h;

[0045] The third step, prepare a certain concentration of zirconium chloride solution, the concentration is 0.45mol / L;

[0046] In the fourth step, the dried 13X molecular sieve is placed in the above-mentioned zirconium chloride solution, and electromagnetically stirred for 6 hours, taken out and calcined at 600° C. for 2 hours to obtain the modified 13X molecular sieve.

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Abstract

The invention discloses a chemical pretreatment method for organic waste gas containing styrene components, which belongs to the technical field of organic waste gas treatment, and solves the problem that waste gas of organic gas compounds containing styrene components easily occurs in pipelines and devices in the prior art The polymer generated by the polymerization reaction blocks the pipeline, and the temperature rise generated by the self-polymerization reaction has technical problems such as a relatively large safety hazard for the device. In the present invention, the 13X molecular sieve is modified by titanium chloride, zirconium chloride or ferric chloride, and then the modified 13X molecular sieve is loaded into a chemical pretreatment device to polymerize styrene in the organic waste gas. In the present invention, by selecting a modified 13X molecular sieve to treat styrene in organic waste gas, the self-polymerization reaction of styrene can be controlled in the polymerization reaction tank, so as to avoid the self-polymerization reaction of styrene in the pipeline or device and cause other Danger.

Description

technical field [0001] The invention relates to the technical field of treatment of organic waste gas, in particular to a chemical pretreatment method for organic waste gas containing styrene components. Background technique [0002] Styrene is an important intermediate product of the petroleum and petrochemical industry and an important part of the organic chemical industry. According to the output, the output of resin prepared from styrene as a raw material is second only to the output of ethylene series and vinyl chloride series, ranking second in synthetic resins. three. Styrene generates styrene after self-polymerization, which is used to prepare foamed plastic products, accounting for about two-thirds of its total demand. Macromolecular compounds such as saturated polyester. In 2010, the global demand reached 28 million tons, and it showed an increasing trend year by year. [0003] The main production process of styrene is ethylbenzene dehydrogenation. Due to the li...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01D53/86B01D53/72
CPCB01D53/8668B01D2255/20707B01D2255/20715B01D2255/20738B01D2257/7027
Inventor 刘欢宫中昊牟小冬单晓雯刘全桢
Owner CHINA PETROLEUM & CHEM CORP