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High-surface-precision copper alloy strip and preparation method thereof

A copper alloy strip, high surface technology, applied in the direction of metal rolling, metal material coating process, manufacturing tools, etc., can solve the problems of surface quality decline of copper alloy strip, affecting the economic benefits of enterprises, oxidation of copper alloy surface, etc. , to achieve the effect of improving antioxidant capacity, excellent high temperature stability, and improving surface accuracy

Active Publication Date: 2019-12-13
郁杨
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] However, in the process of rolling and processing copper alloy strips, there will be instability of high or low heating temperature, serious oxidation problems on the surface of copper alloy, and low surface hardness, resulting in copper alloy in the rolling process. The surface quality of the strip decreases, resulting in an increase in the rate of defective products, which seriously affects the economic benefits of the enterprise

Method used

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  • High-surface-precision copper alloy strip and preparation method thereof

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Effect test

Embodiment 1

[0025] The copper-hafnium alloy plate with hafnium mass fraction of 0.1% was evenly ground with sandpaper with a particle size of 300#, washed with water three times after grinding, and dried in cold air; 2 0.5% N by volume 2 +O 2 The mixture was heated in a belt furnace with mixed atmosphere, and the oxygen content in the system was monitored by an oxygen sensor. The heating temperature was 600 °C, and the reaction was performed for 0.5 h. The surface micro-oxidized copper-hafnium alloy plate is heated in a hydrogen reduction furnace, the reduction temperature is 400 ° C, and the reaction is performed for 2 hours, so that a high-hardness nano-hafnium oxide dispersion-strengthened copper thin layer is formed on the surface of the plate; the obtained nano-hafnium oxide dispersion-strengthened copper plate is obtained. It is fully heated and hot rolled. After the hot rolling is completed, the obtained sheet is put into an annealing furnace at 400 ° C for annealing treatment for...

Embodiment 2

[0027] The copper-hafnium alloy plate with a hafnium mass fraction of 0.5% was evenly ground with sandpaper with a particle size of 400#, washed with water four times after grinding, and dried in cold air; 2 5% N by volume 2 +O 2 Heating in a mixed atmosphere belt furnace, and monitoring the oxygen content in the system by an oxygen sensor, the heating temperature was 400 °C, and the reaction was performed for 1 h. The copper-hafnium alloy plate with its surface slightly oxidized is heated in a hydrogen reduction furnace, the reduction temperature is 700 ° C, and the reaction is 0.5 h, so that a high-hardness nano-hafnium oxide dispersion-strengthened copper thin layer is formed on the surface of the plate; the obtained nano-hafnium oxide dispersion-strengthened copper plate is The material is fully heated and hot rolled. After the hot rolling is completed, the obtained sheet is placed in an annealing furnace at 450°C for annealing treatment for 20 minutes, then quickly and u...

Embodiment 3

[0029] The copper-hafnium alloy plate with a hafnium mass fraction of 0.3% was evenly ground with sandpaper with a particle size of 450#, washed with water four times after grinding, and dried in cold air; 2 2% N by volume 2 +O 2 Heating in a mixed atmosphere belt furnace at a heating temperature of 500°C and reacting for 1.5h. The surface micro-oxidized copper-hafnium alloy plate is heated in a hydrogen reduction furnace, the reduction temperature is 600 ° C, and the reaction is 0.5 h, so that a high-hardness nano-hafnium oxide dispersion-strengthened copper thin layer is formed on the surface of the plate; the obtained nano-hafnium oxide dispersion-strengthened copper plate is obtained. The material is fully heated and hot rolled. After the hot rolling is completed, the obtained sheet is put into an annealing furnace at 450 ° C for annealing treatment for 30 minutes, then quickly and uniformly cooled to room temperature, and then subjected to room temperature cold rolling d...

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Abstract

The invention provides a high-surface-precision copper alloy strip and belongs to the technical field of copper alloy strip processing. A preparation method of the high-surface-precision copper alloystrip comprises the following steps of conducting grinding treatment on a copper-hafnium alloy plate and conducting micro-oxidation reaction in a mixed atmosphere belt furnace to obtain a surface micro-oxidized copper-hafnium alloy plate; conveying the urface micro-oxidized copper-hafnium alloy plate into a hydrogen reduction furnace to be subjected to heating reaction to form a high-hardness nanohafnium oxide dispersion strengthened copper thin layer on the surface of the plate; and conducting hot rolling and cold rolling on the obtained nano hafnium oxide dispersion strengthened copper plate to obtain the high-surface-precision copper alloy strip. The alloy preparation method provided by the invention is simple in operation and high in rate of finished products. The obtained copper alloy strip has the high oxidation resistance.

Description

technical field [0001] The invention belongs to the technical field of copper alloy strip processing, and particularly provides a method for preparing copper alloy strip with high surface precision by using copper-hafnium alloy as raw material. Background technique [0002] Copper alloy strip is an important variety of copper processing materials, widely used in electronics, electrical, communications, instrumentation, instrument control machinery, medicine, optics, aviation satellites, transportation and other fields. Especially with the development of modern communication, electronics and semiconductor industries, its demand is increasing rapidly, especially the high-precision, high-performance copper strip products have a broad market space. [0003] However, in the process of rolling and processing copper alloy strips, there will be instability of high or low heating temperature, serious oxidation problems on the surface of copper alloys, and low surface hardness, causin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C8/12C22F1/02C22F1/08C22C9/00C21D9/00B21B3/00
CPCB21B3/00B21B2003/005C21D9/0081C22C9/00C22F1/02C22F1/08C23C8/12
Inventor 郁杨
Owner 郁杨