Environment-friendly nickel stripper and preparation method and using method thereof

An environment-friendly, nickel stripping agent technology, applied in the field of environment-friendly nickel stripping agent and its preparation, can solve the problems of uneven distribution of power lines, low stripping rate, easy-to-corrosion abutment, etc., to improve the use stability and Effect of shelf life, inhibition of self-decomposition, and guaranteed pH value

Active Publication Date: 2019-12-31
KUNSHAN CITY BANMING ELECTRONICS SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the electroplating nickel stripping method has a fast stripping speed, it requires a special power supply, and its one-time investment cost is relatively large. Moreover, due to the different shapes of the workpiece and the uneven distribution of the power lines, the stripping speed of the plating layer on each part of the workpiece varies greatly. , leading to local corrosion of the matrix
Chemical deplating is relatively simple, and the cost is relatively low. Using chemical deplating method, regardless of whether the working surface is flat or not, the stripping effect is very good, so it is widely used, but the stripping rate of this method is low
Currently commonly used chemical deplating methods: there are cyanide method and concentrated nitric acid method. The former cyanide is a highly toxic substance, which is very dangerous to the experimenter itself, and has basically been banned from use; while the concentrated nitric acid method is too acidic. It is easy to corrode the abutment, and also produces a large amount of smoke, which is very harmful to the human body. At the same time, it is dangerous to operate and is not easy to control, and its liquid medicine will contain a large amount of N elements, making the total nitrogen content in the waste liquid too high , does not meet the manufacturer's wastewater discharge standards, causing certain environmental pollution

Method used

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  • Environment-friendly nickel stripper and preparation method and using method thereof
  • Environment-friendly nickel stripper and preparation method and using method thereof
  • Environment-friendly nickel stripper and preparation method and using method thereof

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Embodiment

[0027] Embodiment: take each component in table 1 and prepare nickel stripper according to the following method, the preparation method of embodiment 1-6 is as follows:

[0028] S1: Measure half of the total volume of the nickel stripping agent in water, weigh the sulfuric acid solution of the formulated amount, slowly add it into the water, and keep stirring, and cool down to obtain the diluted sulfuric acid solution;

[0029] S2: Weigh the hydrogen peroxide solution and nitric acid solution in the formula amount, add them into the diluted sulfuric acid solution, and stir evenly to obtain a mixed solution;

[0030] S3: add the solubilizer, stabilizer and complexing agent in the prescribed amount in sequence, and after stirring evenly, add the remaining pure water, stir evenly to obtain the nickel stripper, and set aside;

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Abstract

The invention relates to an environment-friendly nickel stripper and a preparation method and using method thereof. The nickel stripper includes 30-150 g of a sulfuric acid solution, 20-50 g of a hydrogen peroxide solution, 4-10 g of a nitric acid solution, 1-10 g of a dissolution promoter, 1-5 g of a complexing agent and 1-5 g of a stabilizer per liter, where solvents are pure water. According tothe nickel stripper, a small amount of nitric acid is added into a sulfuric acid-hydrogen peroxide system, the nickel stripping speed is high, the stripping speed of a nickel plating layer reaches 2-4 micrometers / min, no corrosion is caused to a stainless steel base, a small amount of nitric acid is consumed, and the requirement for environmental protection can be met.

Description

technical field [0001] The invention relates to a nickel stripper, in particular to an environment-friendly nickel stripper, a preparation method and a use method thereof. Background technique [0002] With the development of modern science and technology and industrial construction, electroplating nickel and its alloys have been widely used as a process technology, but in the process of production, there will always be some unqualified products and electroless nickel plating cylinders in the hanger. Bulk nickel coating, they may not be coated with nickel layer locally, or may have poor anti-corrosion ability. For workpieces with strict tolerance dimensions, the thickness of the coating cannot meet the standard, and defects such as pinholes and spots will appear on the surface. If you throw it away directly , It will cause cost increase, and it is also a waste of resources, so nickel stripping is usually performed on poor nickel plating layer or nickel plating layer of racks...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23F1/28
CPCC23F1/28
Inventor 李晨庆黄志齐陈修宁黄京华王立中刘亮亮王淑萍
Owner KUNSHAN CITY BANMING ELECTRONICS SCI & TECH
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