Preparation method for anode foil of medium-high voltage aluminum electrolytic capacitor and capacitor
A technology for aluminum electrolytic capacitors and anode foils, applied in electrolytic capacitors, capacitors, circuits, etc., can solve problems such as large differences in resistance of sintered films, uneven current distribution, and difficulty in formation
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[0023] A preparation method for medium and high voltage aluminum electrolytic capacitor anode foil, comprising the following steps:
[0024] 1) Deoxidize the powder, anneal the aluminum powder or aluminum alloy powder in vacuum or under the protection of an inert gas for 1-3 hours; the annealing temperature is 350-400 degrees Celsius. For the specific annealing method in this step, please refer to "Principles of Powder Metallurgy" by Huang Peiyun.
[0025] 2) The slurry is mixed, and the binder and the aluminum powder or aluminum alloy powder obtained in step 1) are evenly mixed; the solid-liquid volume ratio of the aluminum powder, aluminum alloy powder and the binder is 5:1-2:1.
[0026] The binder may be a resin binder, and solvents, sintering aids, surfactants, etc. may be added to the binder. These reagents can use known products on the market. In the present invention, the resin binder is preferably one or more of polyvinyl alcohol resin, polyester resin, epoxy resin, a...
Embodiment 1
[0039] Mix 60 parts by volume of aluminum powder with an average particle diameter of 20 microns and 20 parts by volume of polyester resin to obtain a mixed slurry with a solid-to-liquid volume ratio of 3:1; disperse the mixed slurry in ethanol. Use an applicator to coat one side of the aluminum foil substrate, and after drying, mold the formed film with a pressure of 50 Mpa. Then the aluminum foil is sintered in a nitrogen atmosphere. The temperature of the first stage of sintering is 350 degrees Celsius and the time is 5 hours, and the degumming treatment is carried out; the temperature of the second stage is 650 degrees Celsius and the time is 6 hours, so as to obtain the anode foil , the thickness of the anode foil sintered film is about 150 microns.
[0040]Etch the sintered anode foil in citric acid with a pH of 6 for 5 minutes, soak the etched anode foil in hot water at 100 degrees Celsius for 3-9 hours, and use Ultrasonic vibration is used to wash out some resin parti...
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