Catalytic cracking method and system for producing propylene and light aromatic hydrocarbons

A technology of catalytic cracking and light aromatics, which is applied in the direction of catalytic cracking, only multi-stage series cracking process treatment, hydrocarbon cracking and hydrocarbon production, etc. It can solve the problems of low reaction conversion rate and reduced coke yield, so as to improve reaction conversion efficiency, increased yield, product distribution and the effect of improved product quality

Active Publication Date: 2020-01-24
CHINA PETROLEUM & CHEM CORP +1
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  • Abstract
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  • Claims
  • Application Information

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Problems solved by technology

The reduction of coke yield can be achieved when the down-flow reactor is used, but the reaction conversion rate is relatively low, and a special catalyst is required

Method used

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  • Catalytic cracking method and system for producing propylene and light aromatic hydrocarbons

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Effect test

Embodiment 1

[0095] according to figure 1 The test process is carried out, the low-quality raw material oil is hydrogenated residual oil, and the light raw material oil is catalytically cracked gasoline. The test was carried out on a medium-sized device, and the reactor was divided into the first reactor (fast fluidized bed) and the second reactor (dense phase fluidized bed in series with dilute phase conveying bed), and the preheated inferior raw material oil entered the fast fluidized bed The lower part is in contact with the regenerated catalyst and undergoes catalytic cracking reaction. By adjusting the gas linear velocity and setting an umbrella-shaped gas distributor at the feed position, the catalyst in the fast fluidized bed is controlled to be in a full dense phase distribution, and the axial solid fraction in the fast fluidized bed is The ε distribution is in the range of 0.1-0.2 from bottom to top. The light feedstock oil enters the lower part of the dilute-phase conveying bed ...

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Abstract

The invention relates to a catalytic cracking method and system for producing propylene and light aromatic hydrocarbons. The method comprises the following steps that light raw material oil is introduced into adilute phase conveying bed from the lower part of the dilute phase conveying bed to be contacted with a first catalytic cracking catalyst and to be subjected to first catalytic cracking reaction from bottom to top to obtain a first reaction product and a semi-spent catalyst; the obtained first reaction product and the semi-spent catalyst are fed into a dense-phase fluidized bed to continue to be subjected to a second catalytic cracking reaction to obtain a second reaction product and a first spent catalyst; and preheated inferior heavy oil is introduced into a fast fluidized bed fromthe lower part of the fast fluidized bed to be contacted with a second catalytic cracking catalyst and to be subjected to a third catalytic cracking reaction from bottom to top to obtain a third reaction product and a second spent catalyst. By virtue of the catalytic crackingmethod and system, the yield of propylene and light aromatic hydrocarbons is high, and the yield of coke and dry gas is low.

Description

technical field [0001] The invention relates to a catalytic cracking method and system for producing propylene and light aromatic hydrocarbons. Background technique [0002] Propylene is an important organic chemical raw material. In 2016, the equivalent consumption of propylene in my country was 33.8 million tons, and the equivalent self-sufficiency rate was 75.2%. It is estimated that by 2020, the equivalent consumption of propylene in my country will reach 39 million tons, and there is still a certain space for its production capacity gap. Benzene, toluene and xylene (BTX) are important basic chemical raw materials, among which p-xylene (PX) accounts for about 45% of the total consumption of BTX. With the development of my country's polyester and other industries, it is expected that the demand for BTX will continue to grow at a high speed. About 90% of ethylene, about 70% of propylene, 90% of butadiene, and 30% of aromatics come from steam cracking by-products. Althou...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G51/02C10G11/04C10G11/02C07C4/06C07C11/06
CPCC07C4/06C07C11/06C10G11/02C10G11/04C10G51/026Y02P20/52Y02P20/584
Inventor 魏晓丽龚剑洪张执刚
Owner CHINA PETROLEUM & CHEM CORP
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