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Patterned photochromic transparent film and preparation method thereof

A technology for photochromic and photochromic materials, applied in the field of patterned photochromic transparent films and their preparation, can solve the problems of reduced transparency, insufficient bonding, and inability to form patterns, and achieves improved service life and good mechanical properties. , the effect of improving transparency

Active Publication Date: 2020-02-21
WUHAN TEXTILE UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The patent whose publication number is CN102219987A provides a photochromic polyethylene terephthalate mixed film and its preparation method. After blending polyethylene terephthalate and photochromic materials, the solution is used to The film is made into a film by the film-forming method, which avoids the contact of the photochromic material with water and oxygen, thereby preventing its degradation and improving its service life; however, the photochromic material in the film prepared by this method is evenly distributed, and can only change color as a whole under light , cannot form patterns, and the aesthetics is insufficient; at the same time, the mechanical properties of the film prepared by this method still need to be improved
[0004] The patent with the publication number CN206431385U provides a photosensitive plastic color-changing film. By setting a protective layer outside the color-changing layer containing the photochromic material, the photochromic material in the color-changing layer is avoided from escaping, and by setting a gap in the color-changing layer, Form a pattern; but because the bottom protective layer and the top protective layer of the color-changing film are set separately, the combination is not tight enough, and gaps are easily generated after long-term use, and the protection of the photochromic material is insufficient; at the same time, due to the multi-layer material of the color-changing film There is no interaction between them, only simple superposition, and its transparency decreases with the increase of the number of layers, making the definition not high and affecting the overall effect of the pattern

Method used

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  • Patterned photochromic transparent film and preparation method thereof
  • Patterned photochromic transparent film and preparation method thereof
  • Patterned photochromic transparent film and preparation method thereof

Examples

Experimental program
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preparation example Construction

[0029] The invention provides a method for preparing a patterned photochromic transparent film, comprising the following steps:

[0030] S1, using electrospinning method or melt blending spinning method to prepare nanofiber membrane;

[0031] S2. Disperse the photochromic material in a solvent to form a mixed solution; then apply the mixed solution to the surface of the nanofiber membrane obtained in step S1 according to a preset pattern by coating, spraying or stencil printing;

[0032] S3. Immerse the nanofibrous film containing the patterned photochromic material on the surface obtained in step S2 into the epoxy resin solution containing the curing agent, fully infiltrate it, take it out and cure it, and obtain the patterned photochromic transparent film.

[0033] In step S1, the material of the nanofiber membrane is a mixture of one or more of polyester, polyolefin, polyamide, and graft copolymer, and the diameter of the nanofiber is 50-500nm; the nanofiber The difference...

Embodiment 1

[0039] This embodiment provides a method for preparing a patterned photochromic transparent film, comprising the following steps:

[0040] S1. Preparation of nanofibrous membrane

[0041] Prepare vinyl alcohol-ethylene graft copolymer (PVA-co-PE) nanofiber membrane by melt blending spinning method, the specific method is as follows:

[0042] Blend PVA-co-PE and cellulose ester (CAB) according to the weight ratio of 20:80, and then use twin-screw melt blending for spinning to prepare PVA-co-PE / CAB blended fibers; then use acetone PVA-co-PE nanofibers are obtained after removing the CAB in the blended fibers; the diameter range of the obtained PVA-co-PE nanofibers is 50-500nm; the nanofibers are dispersed in isopropanol and water with a mass ratio of 1:1 High-speed shear dispersion is carried out in the mixed solvent, and a PVA-co-PE nanofiber film is obtained by a film coating method, and its mass is weighed as 0.041g.

[0043] S2. Preparation of patterned photochromic material...

Embodiment 2~5

[0055] Embodiments 2 to 5 respectively provide a method for preparing a patterned photochromic transparent film. Compared with Example 1, the difference is that the mass of the nanofiber film accounts for the mass of the nanofiber film and the epoxy resin coating layer. percentage of the total mass.

[0056] The transparency and tensile strength of the products obtained in Examples 1-5 and Comparative Examples 1-2 were tested, and the results are shown in Table 1.

[0057] Transparency and tensile strength of nanofiber content and gained product in Table 1 embodiment 1~5 and comparative example 1~2

[0058]

[0059]

[0060] It can be seen from Table 1 that the transparency and tensile strength of the prepared photochromic transparent film can be adjusted by changing the percentage of the nanofiber film to the total mass of the nanofiber film and the epoxy resin coating layer. Among them, with the decrease of the percentage of the nanofiber film, the transparency of the...

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Abstract

The invention discloses a patterned photochromic transparent film and a preparation method thereof. The method comprises the following steps: forming a photochromic material on the surface of a prepared nanofiber film according to a desired pattern, performing covering by using epoxy resin, and performing curing to obtain the patterned photochromic transparent film. Through the above manner, the opaque nanofiber film shows a transparent state under the action of the epoxy resin, so that the effective protection of the photochromic material is realized and the service life is prolonged withoutaffecting light transmission; the synergy between the nanofiber film and the epoxy resin is used, so that the non-patterned area of the prepared photochromic transparent film has higher transparency,and the photochromic transparent film has better mechanical properties; and the preparation process is simple, the content and pattern shape of the photochromic material can be freely selected according to needs, the controllability is strong, large-area production can be realized, and the practical application range is wide.

Description

technical field [0001] The invention relates to the technical field of photochromism, in particular to a patterned photochromic transparent film and a preparation method thereof. Background technique [0002] Photochromic film is a film containing photochromic material, which can change color after being excited by light source, has excellent optical sensitivity and reversible color change, so it is widely used in decoration, protective packaging, anti-counterfeiting and information storage and other fields. Existing photochromic films are usually prepared directly by mixing photochromic materials with solvents. The photochromic materials of this type of photochromic film are directly exposed to the air and are exposed to direct ultraviolet radiation for a long time, so they are easily oxidized and decomposed. Aging, poor fatigue resistance, thereby reducing the use effect and life of the photochromic film. Therefore, it is necessary to provide a new photochromic film to i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L63/00C08L29/04C08L77/02C08L67/02C08K5/3415C08K9/10C08K3/22C08J5/18
CPCC08J5/18C08J2363/00C08J2429/04C08J2477/02C08J2467/02C08K9/10C08K5/3415C08K2003/2258
Inventor 王栋李沐芳赵旭王文陆莹向晨雪梅涛李颖颖
Owner WUHAN TEXTILE UNIV
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