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Post-processing and purification system for tail gas of ship engine

A technology of exhaust gas post-treatment and purification system, applied in exhaust gas treatment, engine components, combustion engines, etc., can solve problems such as unsafe, difficult layout, large space, etc., achieve energy consumption without secondary pollution, and widen the oxidation temperature , high efficiency effect

Active Publication Date: 2020-02-21
SINOCAT ENVIRONMENTAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are also some disadvantages. The first is that the SCR reactor and scrubber are large in size and difficult to arrange. If it is aimed at the transformation of the ship in use, it will be very difficult. At the same time, it will have a great impact on the back pressure of the diesel engine, and generally need to be installed Fans are also very expensive
[0006] According to the current methods of PM capture and removal, on the one hand, diesel particulate filters are used for filtration, air blowing is used for physical purging, or burners are used for external heating to achieve direct combustion, all of which will bring There are many disadvantages. On the one hand, the purging is not thorough, and the soot will accumulate quickly, resulting in a rapid increase in back pressure. On the other hand, it is heated by the burner, and the energy consumption is high. When a large amount of soot is collected and burned directly, the filter The temperature of the core may increase sharply, resulting in unsafe conditions. Another way is to combine soot with NO under certain temperature conditions through catalytic oxidation. 2 Oxidation-reduction reactions occur, usually requiring a temperature of 280°C to 500°C, and sufficient NO 2 When the temperature is below 280°C, the catalytic ability is not enough, and the oxidation removal efficiency of soot is low. When the ship engine is operated under a low load for a long time, it will cause soot emission sharply, and the back pressure will increase sharply
At the same time, ships usually require the back pressure to be lower than 10kPa, which requires a large volume of diesel soot particulate filter, correspondingly, it takes up a lot of space on the ship, and some ships cannot be installed in a reasonable layout, so they cannot be widely used

Method used

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Embodiment 1

[0053] A catalytic and cooperative low-temperature plasma removal PM and NOx ship exhaust post-treatment purification system, comprising the following steps:

[0054] According to the requirements of this patent, Si-Al-Ti / CeO2 material is used as a catalyst for DOC, and precious metals are impregnated into the material, wherein the molar ratio of precious metals is Pt:Pd=3:1, forming a DOC catalyst and coating it on a 35-mesh honeycomb ceramic carrier. , 100HZ is used for NTP, and Ce-Ti composite material is used for POC filter, in which the mass content of titanium dioxide is 5%, and the noble metal is single Pt; The contents are 3%, 10% and 87%, respectively. Finally, the PM filtration efficiency is 92%, the PM removal efficiency is 95%, and the NOx conversion efficiency is 96%.

Embodiment 2

[0056] A catalytic and cooperative low-temperature plasma removal PM and NOx ship exhaust post-treatment purification system, comprising the following steps:

[0057] According to the requirements of this patent, use Si-Al-Ti / Al-Ce material as catalyst for DOC, impregnate precious metals into the material to form DOC catalyst and coat it on 35 mesh honeycomb ceramic carrier, use 150HZ for NTP, and use 150HZ for POC filter A Ce-Ti composite material is used, wherein the mass content of titanium dioxide is 5%, and for the SCR catalyst, vanadium pentoxide, tungsten oxide and titanium dioxide are composited, and the mass content is 5%, 5% and 90% respectively. Finally, the PM filtration efficiency is 94%, the PM removal efficiency is 95%, and the NOx conversion efficiency is 97%.

Embodiment 3

[0059] A catalytic and cooperative low-temperature plasma removal of PM and NOx ship exhaust post-treatment purification system, comprising the following steps:

[0060] According to the requirements of this patent, use Si-Al-Ti / Ce-Zr material as catalyst for DOC, impregnate precious metals into the material to form DOC catalyst and coat it on 35 mesh honeycomb ceramic carrier, use 300HZ for NTP, and use 300HZ for POC filter A Ce-Ti composite material is used, wherein the mass content of titanium dioxide is 5%, and for the SCR catalyst, vanadium pentoxide, tungsten oxide and titanium dioxide are composited, and the mass content is 5%, 10% and 85% respectively. Finally, the PM filtration efficiency is 96%, the PM removal efficiency is 97%, and the NOx conversion efficiency is 97%.

[0061] Attached Table 1 shows the PM filtration efficiency, removal efficiency and NOx conversion efficiency obtained in each specific implementation case.

[0062] Table 1: Performance statistics ...

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Abstract

The invention discloses a post-processing and purification system for removing PM and NOx ship tail gas through catalyzing and cooperating low-temperature plasma, specifically suitable for the tail gas purification treatment of a ship adopting diesel oil as fuel power and a diesel-powered generator set with a fixed source, etc. The system removes soot particles (PM) and NOx by a catalyst in cooperation with the low-temperature plasma, the system is composed of an oxidation type catalytic unit, a plasma generator, an oxidation type particle semi-permeable filter and a selective reduction catalytic unit, and is integrated in sequence; the number of pores of the catalytic unit containing the catalyst is between 20 meshes and 100 meshes, and the wall porosity of the oxidation type particle semi-permeable filter is more than or equal to 50%. The whole system has a low back pressure and can purify PM and NOx rapidly, the PM capture rate is more than 90%, the removal efficiency is more than 95%, and the NOx conversion efficiency is more than or equal to 95%.

Description

technical field [0001] The invention belongs to the technical field of tail gas purification, in particular to the technical field of catalytic purification of engine tail gas, and in particular to a post-treatment purification system for ship engine tail gas. Background technique [0002] Diesel engines have the advantages of high fuel economy, high reliability, high power, and long life, and are widely used in large-scale equipment such as automobiles, ships, fixed source generator sets, and offshore oil platform diesel generators. However, diesel exhaust pollution also poses a great threat to the human living environment. Diesel engine exhaust mainly includes water vapor, O 2 , N 2 , CO and CO 2 , hydrocarbons (HC), nitrogen oxides (NO X ), sulfide and particulate pollutants (PM), particulate pollutants mainly include soot particles, highly soluble hydrocarbons, lead compounds, etc., of which nitrogen oxides (NO X ) and particulate pollutants (PM) are the main compon...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): F01N13/00F01N3/035F01N3/08F01N3/20F01N3/28F01N9/00
CPCF01N3/035F01N3/0892F01N3/20F01N3/2066F01N3/208F01N3/2828F01N9/00F01N2250/02F01N2570/14F01N2590/02F01N2610/02F01N13/009Y02T10/12Y02T10/40
Inventor 魏宽周超冯锡陈海昆蒋中锋王安霖李云陈启章
Owner SINOCAT ENVIRONMENTAL TECH