Novel CuS preservative having strong leaching resistance as well as preparation method and application of preservative
An anti-loss and preservative technology, applied in manufacturing tools, reed/straw treatment, wood treatment, etc., can solve problems such as pollution, high solubility of copper ions, loss of heavy metal ions, etc., to achieve enhanced antibacterial performance, high protection efficiency, and extended The effect of service life
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example 1
[0036] Weigh 3.03g of raw material II copper chloride and dissolve it in 150ml of water to prepare solution A. Weigh 1.75g of raw material I sodium sulfide, 2g of surfactant Tween 80, and two drops of antifoaming agent, dissolve them in 150ml of water, and stir quickly to make solution B. Add all of the solution A dropwise to the solution B that is being stirred rapidly to prepare a stable wood preservative copper sulfide.
[0037] In the specific implementation, the morphology and particle size of CuS in the examples were observed with a transmission electron microscope (TEM), specifically as figure 1 shown. From this experimental verification, it can be seen that the prepared copper sulfide anticorrosion agent is a nano-scale anticorrosion agent.
example 2
[0039] Weigh 3.59g of raw material II copper sulfate and dissolve it in 150mL of water to prepare Solution A. Weigh 1.75g of raw material I sodium sulfide, 2g of surfactant Span 80 and dissolve it in 150ml of water, add two drops of defoamer to make solution B. Add all of Solution A dropwise to Solution B with rapid constant stirring. Prepared as a copper sulfide wood preservative.
[0040] In specific implementation, the wood preservative copper sulfide prepared in this embodiment is treated with vacuum pressure impregnation method to treat pine wood, and a part of the copper sulfide preservative is taken after the test piece is impregnated for loss treatment. The specific loss treatment method is as follows: The final test piece was placed in a Soxhlet extractor, extracted in 70°C water for 72 hours, and the water was changed every 24 hours. Then, according to the national standard "Wood Durability Part One: Natural Corrosion Resistance Test Method-GB / T 13942.1-2009", te...
example 3
[0047] Weigh 4.26g of raw material II copper nitrate and dissolve it in 150mL of water to prepare solution A. Weigh 2.47g of raw material I potassium sulfide, 2g of surfactant stearic acid and dissolve it in 150ml of water, add two drops of defoamer to make solution B. Add all of Solution A dropwise to Solution B with rapid constant stirring. Prepared as a copper sulfide wood preservative.
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