The invention belongs to the field of anticorrosive coating, and in particular, relates to a graphene/deimpurity polyaniline-containing anticorrosive coating. The anticorrosive coating is composed of the following raw materials in parts by weight: 20-80% of epoxy resin, 5-15% of a graphene/deimpurity polyanilin composite material, 5-10% of a zinc powder, 5-10% of a filler, 1-10% of a coloring pigment, 0.1-3% of a dispersion agent, 0.1-3% of a wetting agent, 0.1-3% of a thickening agent, 0.1-1% of a levelling agent, 0.1-1% of a defoaming agent, 0.1-1% of a bactericide, and 1-35% of water. In the preparation process of the anticorrosive coating, polyaniline is loaded on graphene by an in-situ polymerization method, so that the dispersion of polyaniline is improved, polyaniline agglomeration is avoided, and the graphene/deimpurity polyaniline-containing anticorrosive coating is prepared.