Preparation method of ultralow-temperature electronic cigarette lithium ion battery

A technology of lithium-ion batteries and electronic cigarettes, which is applied to battery electrodes, secondary batteries, circuits, etc., can solve the problems of reduced battery discharge capacity, increased battery internal resistance, and unusable batteries, so as to inhibit decomposition and optimize the ratio Composition, effect of stabilizing material structure

Inactive Publication Date: 2020-03-17
淮北市锂动芯新能源科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, lithium-ion batteries also have their own defects. The discharge capacity of the battery under low temperature conditions is significantly lower than that at room temperature, especially in ultra-low temperature (-40°C) environments. It tends to condense, the conductivity decreases, and the internal resistance of the battery increases. It is difficult for lithium ions to be embedded in the negative electrode during charging, and metal lithium deposits are formed on the surface, making the battery unusable. In severe cases, it will also form a safety hazard, causing safety problems such as combustion and explosion

Method used

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  • Preparation method of ultralow-temperature electronic cigarette lithium ion battery
  • Preparation method of ultralow-temperature electronic cigarette lithium ion battery

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 2

[0043] A method for preparing an ultra-low temperature soft-packaged electronic cigarette lithium-ion battery. The specific preparation process is the same as that of Example 1, but the artificial graphite used in the negative electrode is optimized and screened negative electrode particles, and the proportion of negative electrode particles with a particle size of 10-12 microns is 80%. %, and mixed with 10% negative electrode particles with a particle size of 3-5 microns, and 10% negative electrode particles with a particle size of 25-28 microns;

[0044] At the same time, the composition of the electrolyte is different, and the electrolyte includes solvent, lithium salt and additives;

[0045] The electrolyte solvent is composed of 30% ethylene carbonate by weight, 15% dimethyl carbonate by weight, 25% ethyl methyl carbonate by weight, and 35% dibutyl carbonate by weight;

[0046] The additive is composed of 5% by weight of vinylene carbonate and 3% by weight of 1-ethyl-3-me...

Embodiment 3

[0049] A method for preparing an ultra-low temperature soft-packaged electronic cigarette lithium-ion battery, the specific preparation process is the same as that of Example 1, but the artificial graphite used for the negative electrode is optimized and screened negative electrode particles, and the negative electrode particles with a particle size of 10-12 microns account for 70% , and mixed with 10% negative electrode particles with a particle size of 3-5 microns, and 20% negative electrode particles with a particle size of 25-28 microns;

[0050] The electrolyte used is composed of solvent, lithium salt and additives;

[0051] The electrolyte solvent is composed of 25% ethylene carbonate by weight, 10% dimethyl carbonate by weight, 20% ethyl methyl carbonate by weight, and 30% dibutyl carbonate by weight;

[0052] The additive is composed of 3% by weight of vinylene carbonate and 5% by weight of 1-ethyl-3-methylimidazolium tetrafluoroborate;

[0053] The lithium salt is a...

Embodiment 4

[0055] A preparation method of ultra-low temperature flexible packaging electronic cigarette lithium-ion battery, the specific preparation process is the same as that of Example 1, but the artificial graphite used for the negative electrode is optimized and screened negative electrode particles, and the negative electrode particles with a particle size of 10-12 microns account for 75% , and mixed with 15% negative electrode particles with a particle size of 3-5 microns, and 10% negative electrode particles with a particle size of 25-28 microns;

[0056] The electrolyte used is composed of solvent, lithium salt and additives;

[0057] The electrolyte solvent is composed of 20% ethylene carbonate by weight, 10% dimethyl carbonate by weight, 20% ethyl methyl carbonate by weight, and 30% dibutyl carbonate by weight;

[0058] The additive is composed of 3% by weight of vinylene carbonate and 3% by weight of 1-ethyl-3-methylimidazolium tetrafluoroborate;

[0059] The lithium salt i...

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Abstract

The invention discloses a preparation method of an ultra-low temperature flexible package electronic cigarette lithium ion battery, which comprises the following steps: winding a prepared positive pole part, a negative pole part and an isolating membrane together by a winding machine to form a roll core, the used PE membrane with the diaphragm thickness of 20 mu m having the porosity of 48%; and putting the obtained roll core into an aluminum-plastic film, injecting an electrolyte into the battery cell after baking, and then performing formation, secondary sealing and capacity grading on the prepared battery cell to obtain the lithium ion battery. According to the invention, the positive electrode adopts the graphene modified lithium cobalt oxide material; the graphene can be uniformly dispersed among lithium cobalt oxide positive electrode material particles, and the graphene on the surface of the lithium cobalt oxide positive electrode plays a role in fixing O atoms on the surface ofthe material, so that the structure of the material is stabilized, the decomposition of an electrolyte on the surface of the lithium cobalt oxide positive electrode is inhibited, and the cycle performance, especially the low-temperature cycle performance, of the material is improved.

Description

technical field [0001] The invention belongs to the field of lithium ion battery preparation and relates to a preparation method of an ultra-low temperature electronic cigarette lithium ion battery. Background technique [0002] Since the advent of lithium-ion batteries in the 1990s, because of their advantages such as high energy density, good cycle life, and no memory effect, they have been continuously promoted and applied in 3C digital products, energy storage power stations, new energy vehicles, aerospace and other fields. , becoming the most widely used battery. However, lithium-ion batteries also have their own defects. The discharge capacity of the battery under low temperature conditions is significantly lower than that at room temperature, especially in ultra-low temperature (-40°C) environments. It tends to condense, the conductivity decreases, and the internal resistance of the battery increases. It is difficult for lithium ions to be embedded in the negative el...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/0587H01M10/0525H01M4/36H01M4/525H01M4/583H01M4/62H01M4/1391H01M4/1393H01M10/0568
CPCH01M4/1391H01M4/1393H01M4/362H01M4/525H01M4/583H01M4/62H01M4/628H01M10/0525H01M10/0568H01M10/0587H01M2300/0025Y02E60/10Y02P70/50
Inventor 尹晓磊王明舟
Owner 淮北市锂动芯新能源科技有限公司
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