High-performance high-flame-retardant halogen-free TPU material and preparation method thereof

A high-flame-retardant, high-performance technology, applied in the field of high-performance high-flame-retardant halogen-free TPU materials and its preparation, can solve problems affecting the life safety of the parties involved, limit the scope of application, pollute the environment, etc., and achieve enhanced hydrolysis resistance stability, High wear resistance, effect of lowering surface temperature

Pending Publication Date: 2020-04-17
上海皆利新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the oxygen index of ordinary TPU is only 17.0% to 18.0%, which is a flammable material, and the char formation rate is low when burning, and it has a strong droplet phenomenon, which limits its application range; in order to enhance the flame retardancy of TPU, the current general The method is to add a halogen-containing flame retardant to it, but the chlorine-containing flame retardant mainly achieves the flame-retardant effect through the gas-phase flame-retardant mechanism, and will release a large amount of toxic and harmful gases when burning, which not only pollutes the environment, but also seriously affects the life safety of the parties; In this context, chlorine-containing flame retardants have been banned by many countries

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A high-performance high-flame-retardant halogen-free TPU material, its composition includes: polycarbonate type material, polyether type material, polyester type material, flame retardant, antibacterial agent, antifungal agent, polyamide, wear-resistant enhancer , plasticizer, organic bismuth, antistatic agent, antioxidant, chain-extending crosslinking agent, compound lubricant, the specific formula is made of the following raw materials by weight: polycarbonate type material 80-95 parts, polyether type material 55-65 parts of material, 45-55 parts of polyester material, 15-25 parts of flame retardant, 3-6 parts of antibacterial agent, 2-5 parts of antifungal agent, 5-9 parts of polyamide, 0.8 parts of wear-resistant enhancer -2.4 parts, 30-40 parts of plasticizer, 6-12 parts of organic bismuth, 2-4 parts of antistatic agent, 0.2-0.4 parts of antioxidant, 5-9 parts of chain extension cross-linking agent, 0.3-0.9 parts of composite lubricant share.

[0023] Preferably, ...

Embodiment 2

[0036]A high-performance high-flame-retardant halogen-free TPU material, its composition includes: polycarbonate type material, polyether type material, polyester type material, flame retardant, antibacterial agent, antifungal agent, polyamide, wear-resistant enhancer . 45 parts of polyester material, 15 parts of flame retardant, 3 parts of antibacterial agent, 2 parts 2 parts of static agent, 0.2 part of antioxidant, 5 parts of chain-extending crosslinking agent, and 0.3 part of compound lubricant.

[0037] Preferably, the polycarbonate-type material is one of polytetrahydrofuran and its copolyether polyol, polyether polyol, polyoxypropylene polyol, excellent mechanical properties, hydrolysis resistance, heat resistance, oxidation resistance Resistance, abrasion resistance in vivo oxidation and microbial degradation.

[0038] Preferably, the polyether-type material is polyether polyol, and the polyether polyol has the characteristics of low toxicity, hydrolysis resistance a...

Embodiment 3

[0050] A high-performance high-flame-retardant halogen-free TPU material, its composition includes: polycarbonate type material, polyether type material, polyester type material, flame retardant, antibacterial agent, antifungal agent, polyamide, wear-resistant enhancer . 55 parts of polyester material, 25 parts of flame retardant, 6 parts of antibacterial agent, 5 parts of antifungal agent, 9 parts of polyamide, 2.4 parts of wear-resistant enhancer, 40 parts of plasticizer, 12 parts of organic bismuth, antibacterial 4 parts of static agent, 0.4 part of antioxidant, 9 parts of chain-extending cross-linking agent, and 0.9 part of compound lubricant.

[0051] Preferably, the polycarbonate-type material is one of polytetrahydrofuran and its copolyether polyol, polyether polyol, polyoxypropylene polyol, excellent mechanical properties, hydrolysis resistance, heat resistance, oxidation resistance Resistance, abrasion resistance in vivo oxidation and microbial degradation.

[0052]...

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PUM

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Abstract

The invention provides a high-performance high-flame-retardant halogen-free TPU material which comprises the following components a polycarbonate material, a polyether material, a polyester material,a flame retardant, an antibacterial agent, a mildew preventive, polyamide, a wear-resistant enhancer, a plasticizer, organic bismuth, an antistatic agent, an antioxidant, a chain extension cross-linking agent and the like, and specifically is prepared from the following raw materials in parts by weight: 80-95 parts of the polycarbonate material, 55-65 parts of the polyether material, 45-55 parts of the polyester material, 15-25 parts of the flame retardant, 3-6 parts of the antibacterial agent, 2-5 parts of the mildew preventive, 5-9 parts of polyamide, 0.8-2.4 parts of the wear-resistant enhancer, 30-40 parts of the plasticizer, 6-12 parts of organic bismuth, 2-4 parts of the antistatic agent, 0.2-0.4 part of the antioxidant, 5-9 parts of the chain extension cross-linking agent and the like. The high-performance high-flame-retardant halogen-free TPU material has the advantages of high wear resistance, favorable elastic toughness, oil resistance, high / low temperature resistance and thelike.

Description

technical field [0001] The invention relates to the field of TPU materials, in particular to a high-performance, highly flame-retardant, halogen-free TPU material and a preparation method thereof. Background technique [0002] As one of the top ten fields, new materials have attracted widespread attention. This field focuses on the development of special metal functional materials, high-performance structural materials, functional polymer materials, special inorganic non-metallic materials and advanced composite materials, and accelerates the research and development of advanced smelting, solidification molding, vapor deposition, profile processing, and high-efficiency synthesis. Key technologies and equipment for material preparation, strengthen basic research and system construction, and break through the bottleneck of industrial preparation. Actively develop special new materials for military and civilian use, accelerate the two-way transfer and transformation of technol...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/04C08L77/00C08K5/00C08K5/103C08K5/17C08K5/3492C08K5/315C08K5/31C08K5/56C08G18/42C08G18/44C08G18/48
CPCC08G18/4018C08G18/42C08G18/44C08G18/48C08L75/04C08L2201/02C08L2201/22C08L2205/03C08L77/00C08K5/00C08K5/103C08K5/17C08K5/34922C08K5/3155C08K5/31C08K5/56
Inventor 陈俊杰
Owner 上海皆利新材料科技有限公司
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