Acrylic polymer with large particle size and wide particle size distribution and preparation method thereof
An acrylic polymer, large particle size technology, applied in coatings and other directions, can solve the problems of high cost performance, hot stickiness and cold brittleness, and poor water resistance.
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
preparation example Construction
[0042] A preparation method of an acrylic acid polymer with large particle size and wide particle size distribution, comprising the following steps:
[0043] (1) Weighing: Weigh butyl acrylate, methyl methacrylate, methacrylic acid, styrene, butyl methacrylate, cross-linking monomers, compound emulsifiers, initiators, and neutralizing agents in parts by weight ,Deionized water;
[0044] (2) Monomer mixing: Put butyl acrylate, methyl methacrylate, methacrylic acid, styrene, butyl methacrylate, and cross-linking monomer into the mixing tank, and stir for more than 30 minutes;
[0045] (3) Configuration: add the initiator to a certain amount of deionized water and stir evenly;
[0046] (4) Polymerization: Add the composite emulsifier into a certain amount of deionized water, start stirring, raise the temperature to 50-55 degrees, add part of the configured initiator and part of the monomer mixture in sequence, and after the reaction starts, add the remaining steps dropwise at th...
Embodiment 1
[0052] The raw materials are as follows: 193 parts of deionized water, 66.26 parts of butyl acrylate, 4.35 parts of methacrylic acid, 17.30 parts of methyl methacrylate, 15.13 parts of styrene, 5.39 parts of hydroxypropyl methacrylate, 32.09 parts of butyl methacrylate , 3.04 parts of methylol acrylamide, 2.17 parts of ethylene glycol dimethacrylate, 8.96 parts of sodium dodecylbenzenesulfonate, 2.40 parts of Softanol 400 ((C12-14 secondary alcohol) polyalkyl ether), over 0.57 parts of sodium sulfate, 0.09 parts of vitamin C and 0.16 parts of sodium metabisulfite, 1.39 parts of ammonia water and 1.01 parts of monoethanolamine.
[0053] monomer mix
[0054] 66.26 parts of butyl acrylate, 4.35 parts of methacrylic acid, 17.30 parts of methyl methacrylate, 15.13 parts of styrene, 5.39 parts of hydroxypropyl methacrylate, 32.09 parts of butyl methacrylate, 3.04 parts of methylol acrylamide 1. Add 2.17 parts of ethylene glycol dimethacrylate into the stirring tank, start stirring,...
Embodiment 2
[0062]The raw materials are as follows: 193 parts of deionized water, 66.26 parts of butyl acrylate, 5.45 parts of methacrylic acid, 17.30 parts of methyl methacrylate, 15.13 parts of styrene, 5.39 parts of hydroxypropyl methacrylate, 32.09 parts of butyl methacrylate , 1.04 parts of methylol acrylamide, 1.57 parts of ethylene glycol dimethacrylate, 8.96 parts of sodium dodecylbenzenesulfonate, 2.40 parts of Softanol 400 ((C12-14 secondary alcohol) polyalkyl ether), over 0.57 parts of sodium sulfate, 0.09 parts of vitamin C and 0.16 parts of sodium metabisulfite, 1.39 parts of ammonia water and 1.01 parts of monoethanolamine.
[0063] monomer mix
[0064] 66.26 parts of butyl acrylate, 5.45 parts of methacrylic acid, 17.30 parts of methyl methacrylate, 15.13 parts of styrene, 5.39 parts of hydroxypropyl methacrylate, 32.09 parts of butyl methacrylate, and 1.04 parts of methylol acrylamide 1.57 parts of ethylene glycol dimethacrylate were added to the mixing tank, and the stir...
PUM
Login to View More Abstract
Description
Claims
Application Information
Login to View More