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A kind of method and system for heavy oil production of light olefins and light aromatics

A low-carbon olefin and heavy oil technology, which is applied in the direction of hydrocarbon cracking, hydrocarbon oil treatment, petroleum industry, etc., can solve the problems of high energy consumption of steam cracking, low yield of naphtha fraction, and low-carbon olefin production, etc., to achieve Improve economic and social benefits, promote transformation and development, and increase productivity

Active Publication Date: 2021-11-16
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, naphtha steam cracking and other processes are mainly used in my country for production. Steam cracking consumes a lot of energy, and because the raw materials in our country are generally heavy, the yield of naphtha fractions with a boiling point below 200°C is low, and only less than 50% of steam cracking can be provided. Feedstock for the production of light olefins
[0011] From the technologies disclosed in the above patent applications, it can be seen that the development of existing technologies for the catalytic conversion of hydrocarbons to produce light olefins is mainly focused on heavy oil catalytic cracking technology, and has not maximized the production of light olefins. In order to increase the demand for low-carbon olefins, it is necessary to develop a catalytic conversion method that uses conventional heavy oil as a raw material and converts it into chemical raw materials such as light olefins and light aromatics to the maximum extent through product hydroprocessing and back refining, so as to improve process selectivity , Efficient use of oil resources

Method used

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  • A kind of method and system for heavy oil production of light olefins and light aromatics

Examples

Experimental program
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Effect test

Embodiment approach

[0070] According to the first embodiment of the present invention, the conditions of the first riser reactor include: the reaction temperature (outlet temperature) is 550-720°C, preferably 580-700°C, and the reaction time is 1-10 seconds, preferably 1.5-6 seconds, the reaction pressure (gauge pressure) is 0.13-1 MPa, preferably 0.25-0.4 MPa, and the agent-oil weight ratio is 1-100, preferably 10-50, more preferably 20-40; The conditions of the fluidized bed reactor may include: the reaction temperature is 530-730°C, preferably 560-680°C, more preferably 610-660°C, and the reaction time is 1-20 seconds, preferably 3-15 seconds, more preferably Preferably 3-10 seconds; the reaction conditions of the second riser reactor can include: the reaction temperature (outlet temperature) is 460-720°C, preferably 500-660°C, more preferably 560-650°C, the reaction time is 1-10 seconds, preferably 1-6 seconds, the reaction pressure (gauge pressure) is 0.1-1 MPa, preferably 0.2-0.4 MPa, and t...

preparation example

[0087] The preparation method of catalytic cracking catalyst A used in the embodiment is as follows:

[0088] 1) Filter the mother liquor from the crystallized β molecular sieve (produced by Changling Catalyst Factory), wash with water, filter and dry; roast the dried molecular sieve in the air for 6 hours at a temperature of 550°C to remove the templating agent Get above-mentioned molecular sieve 100 grams (dry basis) and add in the NaOH solution of 1000 grams 2.4% by weight, be warming up to 65 ℃, after reacting for 30 minutes, after rapidly cooling to room temperature, filter, wash to filtrate neutrality. Then, add 800 grams of water to the filter cake to make a slurry, add 40 grams of NH 4 Cl, heated to 75°C, exchanged for 1 hour, to Na 2 The O content is lower than 0.2% by weight, filtered and washed to obtain a molecular sieve filter cake; take 50 grams (dry basis) of the above-mentioned molecular sieve and add water to prepare a molecular sieve slurry with a solid cont...

Embodiment 1

[0091] This embodiment is used to illustrate the method for producing light olefins described in the present invention.

[0092] according to figure 1 The process shown in the test is carried out on a medium-sized device. The heavy oil raw material is atmospheric residue Z, and its properties are shown in Table 1. The catalyst is catalyst A. The preheated feed oil (350 ° C) enters the first riser reactor. The first catalytic cracking reaction is carried out at the bottom, and the obtained oil agent enters the fluidized bed reactor from the outlet of the first riser reactor to continue the second catalytic cracking reaction. Separation, the reaction product was further separated to obtain products such as ethylene, propylene, and middle distillate AM with a distillation range of 160-220 ° C. The properties of the middle distillate AM are listed in Table 2.

[0093] The middle distillate oil AM is subjected to a hydrotreating reaction with a hydrotreating catalyst, and the cond...

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Abstract

The invention relates to a method and system for producing more light olefins and light aromatics from heavy oil, the method comprising: introducing heavy oil feedstock into a first riser reactor to contact with a first catalytic cracking catalyst and performing a first catalytic cracking reaction; The oil agent obtained in the first riser reactor is introduced into the fluidized bed reactor for the second catalytic cracking reaction to obtain the first reaction product and the first spent catalyst; the first reaction product and the first spent catalyst are subjected to the first Separation of oil agent, the obtained reaction product is separated into middle distillate oil; the obtained middle distillate oil is contacted with a hydrotreating catalyst and subjected to hydrotreating to obtain a hydrogenated distillate oil; the obtained hydrogenated distillate oil is introduced into the second riser reactor Contact with the second catalytic cracking catalyst and perform the third catalytic cracking reaction to obtain the second reaction product and the second spent catalyst. The method and system of the present invention can produce more light olefins and light aromatics.

Description

technical field [0001] The invention relates to a method and system for producing more light olefins and light aromatics from heavy oil. Background technique [0002] Low-carbon olefins such as ethylene and propylene are important organic chemical raw materials, especially the production capacity of ethylene is often regarded as a symbol of the petrochemical development level of a country or region. According to analysis, my country's ethylene production in 2015 was 17.145 million tons, and apparent consumption was 18.6607 million tons, an average increase of about 0.6% year-on-year; my country's propylene production and consumption continued to grow. In 2016, propylene production reached 22.61 million tons, a year-on-year increase of 13.63% %; consumption was 25.87 million tons, a year-on-year increase of 19.3%, and the growth rate of consumption was about 6 percentage points higher than the growth rate of production. The relatively tight supply and demand pattern determine...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G69/04C07C4/06C07C11/04C07C11/06
CPCC07C4/06C10G69/04C10G2300/10C10G2300/1037C10G2300/1048C10G2300/107C10G2300/1077C10G2300/70C07C11/04C07C11/06Y02P20/52
Inventor 张金行王迪首时
Owner CHINA PETROLEUM & CHEM CORP
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