Single tin salt electrolytic coloring method for vertical hanging type electrolytic cell
An electrolytic coloring and electrolytic cell technology, applied in electrolytic coating, surface reaction electrolytic coating, anodic oxidation, etc., can solve problems such as unstable product quality, uneven coloring, and poor corrosion resistance of aluminum products, so as to avoid coloring Effects of unevenness, improved coloring effect, and extended working time
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[0028] Step S2. Preparation of oxide film: place the aluminum product after the surface purification treatment in an oxidation tank, the concentration of sulfuric acid in the oxidation tank is 170-180g / L, the concentration of aluminum ions is 12-16g / L, the temperature of the oxidation tank is The temperature is 16-17°C, the power supply voltage is 12.0-18.0V, and the anodic oxidation is carried out for 30-60 minutes, and an aluminum product covered with an oxide film on the surface can be obtained.
[0029] The outer surface of the oxide film covering the surface of the aluminum product obtained in step S2 is a porous layer, and the bottom layer of the oxide film is in contact with the aluminum substrate as an active layer. The pore size and distribution of the porous layer are one of the key factors affecting the electrolytic coloring effect on the surface of aluminum products, and the diameter and uniformity of the porous layer are closely related to the temperature of the ox...
Embodiment 1
[0037] A kind of monotin salt electrolytic coloring method that is used for vertical electrolyzer, described method comprises processing steps:
[0038] Step S1. Surface purification treatment of aluminum products: first place the aluminum products in a 13% sulfuric acid bath for 5 minutes to degrease, rinse them with clean water, then place the aluminum products in a 4.0% sodium hydroxide bath for 10 minutes, Then rinse off with plenty of water.
[0039] Step S2. Preparation of oxide film: place the aluminum product after the surface purification treatment in an oxidation tank, the concentration of sulfuric acid in the oxidation tank is 170g / L, the concentration of aluminum ions is 16g / L, the oxidation temperature is 16°C, and the voltage is 18.0V , anodized for 30min;
[0040] Step S3. Electrolytic coloring: the oxidized aluminum product is placed in a vertical electrolytic cell, and the electrolyte is a mono-tin salt electrolyte, including: stannous sulfate 6g / L, free sulf...
Embodiment 2
[0043] A kind of monotin salt electrolytic coloring method that is used for vertical electrolyzer, described method comprises processing steps:
[0044] Step S1. Surface purification treatment of aluminum products: first place the aluminum products in a 15% sulfuric acid bath for 3 minutes to degrease, rinse them with clean water, then place the aluminum products in a 5% sodium hydroxide bath for 5 minutes, Then rinse off with plenty of water.
[0045] Step S2. Preparation of oxide film: place the aluminum product after the surface purification treatment in an oxidation tank, the sulfuric acid concentration in the oxidation tank is 180g / L, the aluminum ion concentration is 12g / L, the oxidation temperature is 17°C, and the voltage is 12.0V , anodized for 60min;
[0046] Step S3. Electrolytic coloring: the oxidized aluminum product is placed in a vertical electrolytic cell, and the electrolyte is a mono-tin salt electrolyte, including: stannous sulfate 10g / L, free sulfuric acid...
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