Radiation refrigeration coating and its preparation method and application

A radiative cooling and coating technology, applied in reflective/signal coatings, coatings, silicates, etc., can solve the problem of unmentioned solar light reflection ability of cordierite powder, weak infrared radiation heat dissipation ability in the window, and lack of choice. Infrared radiation characteristics and other problems, to achieve the effect of widening the construction temperature range, good cooling effect and strong reflection effect

Active Publication Date: 2021-08-27
NAT UNIV OF DEFENSE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the biggest problems of composite thermal insulation coatings are: 1. Although reflective fillers can strongly reflect sunlight, they are not strong enough for near-infrared reflection, weak in the heat dissipation capacity of infrared radiation in the window, and lack of selective infrared radiation characteristics; 2. Although the radiation filler has strong infrared radiation ability, it lacks selective infrared radiation characteristics, especially the weak reflection ability to sunlight. If it is partially replaced by reflective filler, it will weaken the reflection performance of the composite coating on sunlight
At present, there are many patents and documents on the preparation method of cordierite powder, but they focus on the particle size, purity and sintering activity of the powder, and none of them mention the sunlight (0.3-2.5μm) reflection ability of the cordierite powder. , and there is no related technology and enlightenment to improve its reflective ability and use it as a filler in thermal insulation coatings
In addition, there is no report on how to adjust the process to improve the infrared reflection ability of cordierite powder outside the atmospheric window (8-13 μm)
In fact, the cordierite produced in the prior art has a single pore size of only 240nm. According to the Mie theory and the research results of the light-absorbing layer of solar cells, this pore size will enhance the absorption of sunlight, so it is impossible Has excellent thermal insulation properties

Method used

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  • Radiation refrigeration coating and its preparation method and application
  • Radiation refrigeration coating and its preparation method and application
  • Radiation refrigeration coating and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0052] A kind of radiant cooling paint, comprises the following raw material components according to mass percentage:

[0053]

[0054]

[0055] In the present embodiment, silane coupling agent is Z6040, Dow Corning; Film-forming aid is Loxanol @ CA 5308, BASF; leveling agent is BYK-3700, Germany BYK; dispersant is Efka @ FA 4654AN, BASF; defoamer is TEGO @ Foamex810, Evonik; thickener is Rheovis @ PE 1331, BASF; anti-flash rust agent is Efka @ MI 6613, BASF.

[0056] A preparation method of the radiant refrigeration coating in the above-mentioned embodiment 1 of the present invention, comprising the following steps:

[0057] (1) Pour porous cordierite, titanium dioxide, dipropylene glycol methyl ether acetate, silane coupling agent, film-forming aid, leveling agent, dispersant, defoamer, thickener, anti-flash rust agent into a beaker , sonicated for 30 minutes, and stirred by a high-speed shearer for 30 minutes to mix them uniformly to obtain a filler / dipropylene g...

Embodiment 2

[0085] A radiation cooling coating, which is basically the same as the radiation cooling coating in Example 1, the only difference is that the preparation method of porous cordierite is different.

[0086] In Example 2, the preparation method of the porous cordierite used is basically the same as the preparation method of the porous cordierite in Example 1, the only difference being: in step S2 of the preparation method of Example 2, pH=3; in step S3, The temperature of the second step of calcination is 1200°C.

[0087] Figure 11 It is the XRD spectrum of the porous cordierite powder prepared in Example 2 of the present invention. Such as Figure 11 As shown, it shows that the gel obtained at pH = 3 can also obtain pure α-cordierite phase after calcination at 1200°C for 2 hours.

[0088] Figure 12 It is the SEM image of the porous cordierite powder prepared in Example 2 of the present invention. Such as Figure 12 As shown, it can be seen that the product still has a p...

Embodiment 3

[0092] A radiation cooling coating, which is basically the same as the radiation cooling coating in Example 1, the only difference is that the preparation method of porous cordierite is different.

[0093] In Example 3, the preparation method of the porous cordierite used is basically the same as the preparation method of the porous cordierite in Example 2, the only difference being that in the step S2 of the preparation method of Example 3, the sol was placed at 50° C. 60h to get a gel.

[0094] The heat insulation test results show that the coated panel obtained in Example 3 can achieve an absolute cooling effect (daytime) of 6.2°C.

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Abstract

The invention discloses a radiation refrigeration paint and its preparation method and application. The radiation refrigeration paint comprises the following raw material components in terms of mass percentage: 4%-8% of porous cordierite, 10%-18% of titanium dioxide, acrylic resin 22%~35%, 0.5%~1.5% of silane coupling agent, 0.1%~1% of film-forming agent, 0.1%~1% of leveling agent, 0.1%~1% of dispersant, 0.2%~1% of defoamer %, thickener 0.1%-2%, anti-flash rust agent 0.1%-2%, and the balance is dipropylene glycol methyl ether acetate, which is prepared by mixing the above raw materials. The radiation cooling coating of the present invention has both high reflectivity of sunlight and selective high radiation rate in the atmospheric window, and its preparation method has the advantages of simplicity, low cost, etc., and at the same time, the radiation cooling coating prepared by the coating can realize all-weather refrigeration , good refrigeration effect, high use value and application prospect.

Description

technical field [0001] The invention relates to a radiant cooling coating, a preparation method and application thereof. Background technique [0002] Passive radiative cooling technology achieves cooling or even cooling without energy input. However, because most of the heat radiated out will be absorbed and intercepted by various components in the atmosphere, only a small part of infrared radiation can freely pass through the "atmospheric window" and be thrown into outer space. Therefore, to achieve efficient cooling, it is necessary It is required that the infrared radiation of the material be concentrated in the window band as much as possible, that is, 8-13 μm. To achieve daytime radiative cooling, in addition to satisfying selective radiation, it is also necessary to prevent the entry of solar heat. Therefore, the surface of the material should also have extremely high solar reflection capabilities. Although metamaterials have the potential to perfectly realize the a...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D133/04C09D5/33C01B33/26
CPCC01B33/26C01P2002/72C01P2004/03C01P2004/30C01P2004/61C01P2004/62C01P2006/17C08K2003/2241C09D5/004C09D133/04C08K7/26C08K3/22
Inventor 王璟杨玲妮穆思彤楚增勇郭涛涛周浒林
Owner NAT UNIV OF DEFENSE TECH
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