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Natural rubber wastewater treatment process

A technology for natural rubber and waste water, which is applied in the fields of materials, chemical industry and environmental protection. It can solve the problems of negative impact on the environment, difficulty in achieving governance effects, difficult biodegradation of polyolefins, etc., to reduce pollutants, reduce ammonia nitrogen and total phosphorus content, and alleviate burden effect

Pending Publication Date: 2020-06-30
苏州仕净科技股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

If this waste water is discharged into the environmental water body without effective treatment, it will have a great negative impact on the environment.
[0004] At present, the treatment of natural rubber wastewater mainly adopts biological treatment processes, such as: anaerobic method, aerobic method, anaerobic-anoxic-aerobic method combined process treatment, because natural rubber wastewater contains a large amount of granular, Suspended and emulsified impurities also contain a large amount of polyolefin, and polyolefin is difficult to biodegrade. In addition, it contains high content of ammonia nitrogen and total phosphorus, which makes it difficult to achieve stable and up-to-standard discharge treatment effects based on biological methods

Method used

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Effect test

Embodiment 1

[0045] Contains CODcr=8000mg / l, BOD5=5300mg / L, SS=550mg / L, TP=130mg / L, NH in one cubic meter 3-Add 300-600ppm polyaluminum chloride (PAC) to the natural rubber wastewater with N=160mg / l, and then pass through the sedimentation tank, enter the slag separation tank, and add polyoxyethylene polyoxypropylene stearyl ether 100- After 300ppm, add 100-300ppm polyaluminum chloride (PAC), remove the floating substances through the grid, and then carry out dissolved air flotation, and further gather small particles and small specific gravity substances in the waste water, remove them through the fine grid, after After the above treatment, 50-60 grams of sodium hydroxide and 50-60 grams of magnesium oxide are added successively therein. After precipitation and separation, the treated wastewater is subjected to a biological treatment process, and 500-1000 ppm of ferrous sulfate heptahydrate is added therein. Hydrogen peroxide 500-1000ppm degrades polyolefins into small molecules. After th...

Embodiment 2

[0047] Contains CODcr=7000mg / l, BOD5=5000mg / L, SS=600mg / L, TP=150 mg / L, NH in one cubic meter 3- Add 400-700ppm polyferric sulfate (PFS) to the natural rubber wastewater with N=180mg / l, then pass through the sedimentation tank, enter the slag separation tank, add nonylphenol polyether 150-350ppm, add 100-300ppm Polymerized ferric sulfate (PFS), removes the floating substances through the grid, and then carries out dissolved air flotation, and further gathers small particles and small specific gravity substances in the wastewater to float up, and then removes them through the fine grid. After the above treatment, add them in turn 40-65 grams of sodium hydroxide, 40-65 grams of magnesium oxide, after precipitation and separation, the treated wastewater is subjected to a biological treatment process, and then 400-900 ppm of ferrous sulfate heptahydrate and 400-900 ppm of hydrogen peroxide are added to it, and the polyolefin Degraded into small molecules, after the above treatment...

Embodiment 3

[0049] Contains CODcr=9000mg / l, BOD5=6000mg / L, SS=800mg / L, TP=180 mg / L, NH in one cubic meter 3- Add 300-500ppm polyaluminum chloride (PAC) and 200-400ppm polyferric sulfate (PFS) to the natural rubber wastewater with N=200mg / l, then pass through the sedimentation tank, enter the slag separation tank, and add polyoxyethylene to it After 200-400ppm of polyoxypropylene stearyl ether, add 100-300ppm of polyferric sulfate (PFS), remove the floating substances through the grid, and then carry out dissolved air flotation, and further gather small particles and small specific gravity substances in the wastewater to float , removed through a fine grid, after the above treatment, 60-90 grams of sodium hydroxide and 60-90 grams of magnesium oxide were added in sequence, after precipitation and separation, the treated wastewater was subjected to a biological treatment process, and then seven Hydrated ferrous sulfate 500-1000ppm and hydrogen peroxide 500-1000ppm degrade polyolefins into s...

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Abstract

The invention relates to a natural rubber wastewater treatment process. The process comprises the following steps: adding a flocculating agent into natural rubber wastewater and carrying out precipitation separation; carrying out dissolved air flotation on the wastewater obtained in the step S1, removing floating substances, adding Mg < 2 + > into the wastewater obtained in the step S2, carrying out precipitation separation, carrying out a biological treatment process on the wastewater obtained in the step S3, adding Fe < 2 + > and H2O2 into the wastewater obtained in the step S4, carrying outchemical degradation, and carrying out coagulation separation on the wastewater obtained in the step S5. The invention aims natural rubber wastewater, the flocculating agent, Mg < 2 + >, Fe < 2 + > and H2O2 are added, and a biological treatment process is combined, so that a large number of granular, suspended and emulsified impurities can be effectively removed, polyolefin substances can be biodegraded, the content of ammonia nitrogen and total phosphorus can be reduced, and the purpose of final up-to-standard emission can be achieved.

Description

technical field [0001] The invention relates to the fields of environmental protection, chemical industry and materials, in particular to a process for treating natural rubber wastewater. Background technique [0002] Natural rubber refers to natural fresh latex collected from rubber trees. Natural rubber can be made into smoked sheet, air-dried film, crepe sheet, technically graded dry rubber and concentrated latex according to different rubber-making methods. In 2019, the latest data from the International Rubber Research Organization shows that the total rubber planting area in the world's raw rubber producing countries is 13.3114 million hectares, of which 125,100 hectares are in Asia, accounting for about 90% of the global rubber tree planting area. Thailand has the largest raw rubber production, but Indonesia has the largest planting area, with a total area of ​​3.639 million hectares. China's rubber tree planting area ranks third in the world, with a total area of ​​1...

Claims

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Application Information

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IPC IPC(8): C02F9/14C02F103/38C02F101/16C02F101/10
CPCC02F1/24C02F1/40C02F1/5236C02F1/5245C02F1/722C02F1/725C02F3/02C02F3/28C02F3/30C02F9/00C02F2101/105C02F2101/16C02F2103/38C02F2209/08C02F2209/14C02F2209/18
Inventor 董仕宏吴倩倩何文
Owner 苏州仕净科技股份有限公司