System and method for acidizing and roasting rare earth concentrate through multi-section external heating rotary furnace

A rare earth concentrate, acidification and roasting technology, which is applied in the system field of acidification and roasting of rare earth concentrate in a multi-stage external heat rotary furnace, can solve the problems of frequent maintenance, increased follow-up treatment of exhaust gas, and large processing gas volume, so as to reduce the difficulty of treatment and operating costs , reduce bridging and clogging, reduce the effect of sulfuric acid concentration

A rare earth concentrate, acidification and roasting technology, which is applied in the system field of acidification and roasting of rare earth concentrate in a multi-stage external heat rotary furnace, can solve the problems of frequent maintenance, increased follow-up treatment of exhaust gas, and large processing gas volume, so as to reduce the difficulty of treatment and operating costs , reduce bridging and clogging, reduce the effect of sulfuric acid concentration

CN111363914AInactive Publication Date: 2020-07-03西安三瑞实业有限公司

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  • System and method for acidizing and roasting rare earth concentrate through multi-section external heating rotary furnace

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] The rare earth concentrate with a water content of 5% to 8% is transported to the rare earth silo 1, and after being measured by the metering device I2, it enters the rotary drying furnace 3. The rotary drying furnace 3 adopts flue gas jacket drying to keep the temperature of the dry material at 110 ~ Between 130°C and drying time of 0.5 hours, the dried tail gas is discharged from the gas phase outlet. The tail gas temperature is ≥120°C to prevent water vapor from condensing. After that, it is sent to the metering device II5. The dried rare earth concentrate has a water content of 0.8%, is discharged from the solid phase outlet of the rotary drying furnace 3, and then enters the metering device II5.

[0042] The dry rare earth concentrate is metered by the metering device Ⅱ5 and mixed with 100% sulfuric acid from the sulfuric acid tank 6 in a ratio of 1:1.1 in the mixing device 7, and then quickly sent to the rotary acidification furnace 8, and the heating source of th...

Embodiment 2

[0046] The rare earth concentrate with a water content of 13-15% is transported to the rare earth silo 1, and after being measured by the metering device I2, it enters the rotary drying furnace 3. The rotary drying furnace 3 uses steam tubes to dry, and the temperature of the dried material is kept at 200°C. The drying time is After 2.5 hours, the dried tail gas is discharged from the gas phase outlet. The temperature of the tail gas is ≥120°C to prevent water vapor from condensing. After the tail gas is discharged, it enters the bag filter 4. After dust removal, the tail gas reaches the standard and is discharged. After the dust is collected, it is transported to the metering device Ⅱ5 . The water content of the dried rare earth concentrate is 1%, and the dried rare earth concentrate is discharged from the rotary drying furnace 3 and enters the metering device II5.

[0047] The dry rare earth concentrate is measured by the metering device Ⅱ5 and sent to the rotary acidificati...

Embodiment 3

[0051] The rare earth concentrate with a water content of 5-10% is transported to the rare earth silo 1, and after being measured by the metering device I2, it enters the rotary drying furnace 3. The rotary drying furnace 3 adopts flue gas jacket drying to keep the temperature of the dried material at 150-180 ℃, drying time is 1 hour, the dried exhaust gas is discharged from the gas phase outlet, the exhaust gas temperature is ≥ 120 ℃, to prevent water vapor from condensing, the exhaust gas enters the bag filter 4 after being discharged, and the exhaust gas reaches the standard discharge after dust collection Transport to metering device Ⅱ5. The water content of the dried rare earth concentrate is 0.1%. The dried rare earth concentrate is discharged from the solid phase outlet of the rotary drying furnace 3 and enters the metering device II5.

[0052] The dry rare earth concentrate is metered by the metering device Ⅱ5 and mixed with 98% sulfuric acid from the sulfuric acid tan...

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Abstract

The invention discloses a method and system for acidizing and roasting rare earth concentrate through a multi-section external heating rotary furnace. The method comprises the following steps of metering and putting the rare earth concentrate into an external heating rotary drying furnace, controlling heating temperature of materials and staying time in the furnace, exhausting tail gas, conveyingdust and sulfuric acid into a rotary acidifying furnace, and controlling the temperature of the materials and the staying time in the furnace; exhausting the tail gas entering an acidified tail gas recovery device after the tail end reaches the standard; enbaling acidified materials to enter a rotary roasting furnace to be roasted, controlling the temperature of the materials and the staying timein the furnace, and exhausting roasted tail gas entering a roasting tail gas recycling device after the roasted tail gas reaches the standard; and enabling high-temperature roasted materials to entera rotary cooling furnace to be cooled and be conveyed to a water leaching procedure so as to obtain the acidified roasted rare earth concentrate with the roasted material leaching rate being 93%-98%.According to the method, the tail gas treatment amount and operation cost are greatly reduced, the fluidity of the dried rare earth concentrate is good, the corrosion rate of equipment and pipelines is reduced, and equipment pipeline blockage is reduced.

Description

technical field [0001] The invention belongs to the technical field of hydrometallurgy, and relates to a system and method for acidifying and roasting rare earth concentrates in a multi-stage external heat rotary furnace. Background technique [0002] Rare earth ore is an important mineral resource in my country, among which the rare earth reserves in Baotou Baiyun Obo mining area account for more than 80% of the country's total reserves. Baotou rare earth ore is mainly a mixture of bastnaesite and monazite. Since the 1970s, my country has used the concentrated sulfuric acid method to roast and smelt mixed rare earth concentrates, which has made important contributions to the development of my country's rare earth ore industry. During this period, two optimizations and improvements have been carried out, namely, the first generation sulfuric acid method. What is widely used now is the third generation sulfuric acid method, that is, the high temperature intensified roasting ...

Claims

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Application Information

Patent Timeline
03 Jul 2020
Publication
CN111363914A
IPC
C22B1/06; C22B59/00
CPC
C22B1/06; C22B59/00
Inventors
张纪刚; 何建祥