Positive electrode active material of battery core, high-voltage high-magnification battery core and manufacturing method thereof

A positive active material and high-rate technology, applied in the direction of active material electrodes, positive electrodes, battery electrodes, etc., can solve the problems of non-targeted improvement of negative electrode materials, affecting the use range of ternary batteries, and affecting customer satisfaction. , to achieve the effect of improving the discharge rate and cycle performance, increasing the electron diffusion rate, and improving the conductivity

Pending Publication Date: 2020-07-10
HUBEI RONGBAI LITHIUM BATTERY MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In today's environment of pursuing energy density, the currently widely used ternary cathode materials have the characteristics of high energy density, but the general discharge current is small, which greatly affects the use range of ternary batteries.
For example, if the discharge current is small, the acceleration capability of the electric vehicle will be reduced, affecting customer satisfaction
There are also a small number of high-rate batteries on the market, but the rate performance is generally not good enough and the cycle performance is poor.
The reason for the above problems is that most of the ternary materials used in batteries are polycrystalline structures, the modification of positive electrode materials is unreasonable, and the negative electrode materials have not been targetedly improved, etc.

Method used

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  • Positive electrode active material of battery core, high-voltage high-magnification battery core and manufacturing method thereof
  • Positive electrode active material of battery core, high-voltage high-magnification battery core and manufacturing method thereof
  • Positive electrode active material of battery core, high-voltage high-magnification battery core and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] A high-voltage high-rate cell, including: a positive electrode, a negative electrode, tabs, a diaphragm, an electrolyte, and an aluminum-plastic film, wherein:

[0047] The positive electrode is composed of a positive electrode active material, a positive electrode binder, a positive electrode conductive agent and a positive electrode current collector. 90 parts of nickel-cobalt lithium manganate are used as the positive electrode active material; 5 parts of polyvinylidene fluoride are used as the positive electrode binder; 5 parts of graphene are used as the positive electrode conductive agent; N-methylpyrrolidone is used as the solvent; 16 μm aluminum foil is used as the positive electrode current collector. Among them, lithium nickel cobalt manganese oxide is doped and coated lithium cobalt manganese oxide, the molar ratio of nickel cobalt manganese is 34:33:33, doped with Al and F elements, and the doping amount is 2000ppm; the coating has high conductivity Molecula...

Embodiment 2

[0061] A high-voltage high-rate cell, including: a positive electrode, a negative electrode, tabs, a diaphragm, an electrolyte, and an aluminum-plastic film, wherein:

[0062] The positive electrode is composed of a positive electrode active material, a positive electrode binder, a positive electrode conductive agent and a positive electrode current collector. 88 parts of nickel-cobalt lithium manganate are used as the positive electrode active material; 6 parts of polyvinylidene fluoride are used as the positive electrode binder; 6 parts of carbon nanotubes are used as the positive electrode conductive agent; N-methylpyrrolidone is used as the solvent; 20 μm aluminum foil is used as the positive electrode current collector. Among them, lithium nickel cobalt manganese oxide is doped and coated lithium cobalt manganese oxide, the molar ratio of nickel cobalt manganese is: 50:20:30, doped with Zr and B elements, the doping amount is 2000ppm and 1000ppm respectively; coating Al2O...

Embodiment 3

[0076] A high-voltage high-rate cell, including: a positive electrode, a negative electrode, tabs, a diaphragm, an electrolyte, and an aluminum-plastic film, wherein:

[0077] The positive electrode is composed of a positive electrode active material, a positive electrode binder, a positive electrode conductive agent and a positive electrode current collector. 85 parts of nickel-cobalt lithium manganate are used as the positive electrode active material; 7 parts of polyvinylidene fluoride are used as the positive electrode binder; 8 parts of carbon fiber are used as the positive electrode conductive agent; N-methylpyrrolidone is used as the solvent; and 18 μm aluminum foil is used as the positive electrode current collector. Among them, lithium nickel cobalt manganese oxide is doped lithium cobalt manganese oxide, the molar ratio of nickel cobalt manganese is: 60:20:20, doped with Rh and N elements, the doping amount is 8000ppm and 2000ppm respectively; single crystal structure...

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Abstract

The invention relates to a positive electrode active material of a battery core, a high-voltage high-magnification battery core and a manufacturing method thereof. The positive electrode active material is modified nickel cobalt lithium manganate, wherein the modified nickel cobalt lithium manganate is of a single-crystal structure, and the modified nickel cobalt lithium manganate is one or more of doped nickel cobalt lithium manganate and coated nickel cobalt lithium manganate. The battery core comprises a positive electrode, a negative electrode and a diaphragm, and the battery core adopts afull-tab winding type structure in which the diaphragm, the positive electrode, the diaphragm and the negative electrode are connected; the positive electrode comprises a positive electrode binder, apositive electrode conductive agent, a positive electrode current collector and the positive electrode active material; and the negative electrode comprises a negative electrode active material, a negative electrode conductive agent, a negative electrode binder and a negative electrode current collector. According to the invention, the rate capability of the battery core can be improved, and theheating of the battery core at a high rate is reduced, so that the overall performance of the battery core is improved.

Description

technical field [0001] The invention relates to the field of lithium-ion batteries, and more specifically, to a positive electrode active material of a battery, a high-voltage, high-rate battery and a manufacturing method thereof. Background technique [0002] Due to its high voltage, high energy density, and long cycle life, lithium-ion batteries are currently widely used in the field of power and energy storage, but they also have a series of problems. The cut-off voltage of the currently used ternary cells is basically 4.2V, which has certain restrictions on the power density and energy density of the cells. In today's environment of pursuing energy density, the currently widely used ternary cathode materials have the characteristics of high energy density, but the general discharge current is small, which greatly affects the use range of ternary batteries. For example, if the discharge current is small, the acceleration ability of the electric vehicle will be reduced, w...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/62H01M2/26H01M4/36H01M4/505H01M4/525H01M10/0525H01M10/0587
CPCH01M4/362H01M4/505H01M4/525H01M4/628H01M4/626H01M4/625H01M10/0525H01M10/0587H01M2004/028H01M2004/021H01M50/531Y02E60/10Y02P70/50
Inventor 佘潇徐乐乐周彦方徐哲徐成廖凡
Owner HUBEI RONGBAI LITHIUM BATTERY MATERIAL CO LTD
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