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A kind of lead-acid battery positive plate and its preparation method and battery

A technology for lead-acid batteries and positive plates, applied in the direction of lead-acid battery electrodes, lead-acid batteries, battery electrodes, etc., can solve the problems of shedding cost, easy softening of positive electrode paste, etc., increase manufacturing costs, reduce charge and discharge time, Slows down softening and swelling effects

Active Publication Date: 2022-03-29
CHAOWEI POWER CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In view of the above analysis, the present invention aims to provide a lead-acid battery positive plate and its preparation method and storage battery, which are used to solve the problems in the prior art that the positive electrode paste is easy to soften, fall off or increase the cost.

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  • A kind of lead-acid battery positive plate and its preparation method and battery
  • A kind of lead-acid battery positive plate and its preparation method and battery
  • A kind of lead-acid battery positive plate and its preparation method and battery

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preparation example Construction

[0046] The invention discloses a method for preparing a positive plate of a lead-acid storage battery, which comprises the following steps:

[0047] Step 11. mixing raw material graphite, polytetrafluoroethylene emulsion and lead oxide;

[0048] Step 12. Add an appropriate amount of dispersant to completely infiltrate the raw materials, stir to obtain a paste mixture and roll it into thin slices;

[0049] Step 13. Prepare the positive lead paste and apply it on the grid to obtain the initial plate;

[0050] Step 14. Attach the thin sheet as a protective layer to both sides of the original plate, perform acid leaching and pressure roller curing to obtain the positive plate of the lead-acid battery. During curing, the dispersant dries and evaporates to form micropores in the protective layer.

[0051] In step 11, the raw material components are 0.01%-10% of graphite, 0.01%-10% of polytetrafluoroethylene emulsion, and 80%-99.98% of lead oxide in terms of mass fraction. Prefera...

Embodiment 1

[0064] The present embodiment provides a kind of preparation method of lead-acid storage battery positive plate, comprises the following steps:

[0065] Step 11. Mix 1 g of graphite, 1 g of polytetrafluoroethylene emulsion, and 20 g of lead oxide; the graphite is flake graphite, and the polytetrafluoroethylene solid content (mass) in the polytetrafluoroethylene emulsion is 55%.

[0066] Step 12. Add 50ml of alcohol to completely infiltrate the raw materials, and then stir while heating; the heating temperature is 45°C, stir to form a paste, and roll the paste mixture into a 0.2mm thick sheet.

[0067] Step 13. Follow the normal production process and prepare the positive electrode lead paste and apply it on the grid to obtain the initial plate.

[0068] Step 14. Attach the thin sheet as a protective layer to both sides of the original plate, perform acid leaching and pressure roller curing according to the normal production process to obtain the positive plate of the lead-acid...

Embodiment 2

[0071] The present embodiment provides a kind of preparation method of lead-acid storage battery positive plate, comprises the following steps:

[0072] Step 11. Mix 0.5 g of graphite, 1 g of polytetrafluoroethylene emulsion, and 15 g of lead oxide; the graphite is flake graphite, and the polytetrafluoroethylene solid content (mass) in the polytetrafluoroethylene emulsion is 50%.

[0073] Step 12. Add 30ml of alcohol to completely infiltrate the raw materials, and then stir while heating; the heating temperature is 40°C, stir to form a paste, and roll the paste mixture into a 0.05mm thick sheet.

[0074] Step 13. Follow the normal production process and prepare the positive electrode lead paste and apply it on the grid to obtain the initial plate.

[0075] Step 14. Attach the thin sheet as a protective layer to both sides of the original plate, perform acid leaching and pressure roller curing according to the normal production process to obtain the positive plate of the lead-a...

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Abstract

The invention discloses a lead-acid accumulator positive plate, a preparation method thereof and an accumulator, belonging to the technical field of lead-acid accumulators, and solves the problems in the prior art that the anode lead paste is easy to soften, fall off or increase in cost. A positive plate of a lead-acid battery, comprising a grid and a positive lead paste coated on the grid; a protective layer is arranged outside the positive lead paste, and the protective layer is used to slow down the softening and expansion of the lead paste; the protective layer includes poly Vinyl fluoride. The invention can significantly improve the charging and discharging performance of the lead-acid battery and prolong the cycle life of the lead-acid battery.

Description

technical field [0001] The invention belongs to the technical field of lead-acid batteries, and in particular relates to a positive plate of a lead-acid battery, a preparation method thereof and a battery. Background technique [0002] Due to its high output power, safe and reliable use, and low cost of raw materials, lead-acid batteries are currently one of the most widely used secondary batteries in the market. When the battery is charged, the positive electrode turns into lead dioxide, and the concentration of sulfuric acid in the electrolyte increases to store energy; when the battery is discharged, the active material of the positive electrode is converted into lead sulfate, and the concentration of sulfuric acid in the electrolyte decreases. Realize the storage and release of capabilities. [0003] However, the volume of lead sulfate generated during discharge increases, which will lead to softening and falling off of the positive electrode paste after repeated cycles...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/62H01M4/14H01M4/20H01M10/06
CPCH01M4/628H01M4/14H01M4/20H01M4/623H01M10/06Y02E60/10
Inventor 周志学殷思思陈理黄伟国
Owner CHAOWEI POWER CO LTD