Special engineering plastic composite material and preparation method thereof
A technology for special engineering plastics and composite materials, applied in the field of special engineering plastics composite materials and their preparation, can solve the problems of low production process efficiency, slow processing and molding process, poor processability, etc., and achieve simple and rapid molding and high molecular weight. , Overcome the effect of poor toughness
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Embodiment 1
[0027] A special engineering plastic composite material, comprising the following materials in parts by weight: 20 parts of polyester resin, 18 parts of polyethylene sebacamide, 16 parts of polyvinyl chloride, 21 parts of modifier, and 10 parts of additive.
[0028] The modifier includes 8 parts of polyglyceryl sebacate, 5 parts of propylene glycol adipate, 6 parts of acrylate, and 3 parts of xylyl phosphate.
[0029] The additives include 5 parts of nano-titanium nitride and 6 parts of nano-calcium oxide. These nanoparticles can block the molecular gap, making it difficult for gas to diffuse and penetrate, thereby improving the barrier properties of plastic materials, increasing the crystallization rate, and improving production efficiency.
[0030] Polyglycerol sebacate is obtained by polycondensation of glycerin and sebacic acid under the condition of nitrogen flow and water separation, the flow rate of nitrogen gas is 0.1m3 / h, the reaction temperature is 160°C, the reaction...
Embodiment 2
[0034] A preparation method of a special engineering plastic composite material, comprising the following steps:
[0035] S1: Prepare 30 parts of polyester resin, 20 parts of polyethylene sebacamide, 20 parts of polyvinyl chloride, 20 parts of modifier, and 10 parts of additives according to parts by weight;
[0036] S2: mixing polyester resin, polyethylene sebacyl diamine, and polyvinyl chloride to form a mixed slurry;
[0037] S3: Add modifiers and additives to the mixed solution in S2. Modifiers include 10 parts of polyglyceryl sebacate, 4 parts of propylene glycol adipate polyester, 4 parts of acrylate, 2 parts of xylyl phosphate, additives Including 5 parts of nano-titanium nitride and 5 parts of nano-calcium oxide, stirring, while the pH of the mixed solution is detected in real time during the addition of modifiers and additives, the pH is controlled to be neutral, and the plastic slurry is obtained after fully mixing ;
[0038] S4: Put the plastic slurry obtained in ...
Embodiment 3
[0041] A preparation method of a special engineering plastic composite material, comprising the following steps:
[0042] S1: 16 parts of polyester resin, 15 parts of polyethylene sebacamide, 11 parts of polyvinyl chloride, 13 parts of modifier, and 7 parts of additives are prepared according to parts by weight;
[0043] S2: mixing polyester resin, polyethylene sebacyl diamine, and polyvinyl chloride to form a mixed slurry;
[0044]S3: Add modifiers and additives to the mixed solution in S2. The modifiers include 4 parts of polyglyceryl sebacate, 3 parts of propylene glycol adipate polyester, 4 parts of acrylate, 2 parts of xylyl phosphate, additives Including 3 parts of nano-titanium nitride and 4 parts of nano-calcium oxide, stirring, and at the same time, the pH of the mixed solution is detected in real time during the addition of modifiers and additives, and the pH is controlled to be neutral, and the plastic slurry is obtained after fully mixing ;
[0045] S4: Put the p...
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