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Anti-corrosion coating for aluminum-magnesium-silicon sagger

An anti-corrosion coating, aluminum-magnesium-silicon technology, applied in the field of anti-corrosion coatings for aluminum-magnesium-silicon saggers, can solve the problems of limited service life of the box body, complicated preparation process, and non-compact structure, and achieve excellent resistance to lithium erosion Chemical composition and organizational structure, simple preparation process, and the effect of inhibiting penetration

Inactive Publication Date: 2020-09-11
SINOSTEEL LUOYANG INST OF REFRACTORIES RES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

By compounding a layer of anti-erosion layer material on the inner wall of the box wall, since the material structure of this layer is basically the same as that of the box and is not dense, it can still react with the matrix to cause the peeling of the composite layer when the erosive medium is in the liquid or gas phase. The improvement of the service life of the body is limited, and the preparation process is complicated and the cost is high

Method used

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  • Anti-corrosion coating for aluminum-magnesium-silicon sagger

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Sagger anti-corrosion coating solid component and mass percentage: CaCO 3 , 60.4%, TiO 2 , 20%; SiO 2 , 2%; Al 2 o 3 , 10%; Borax, 2.5%; FS10, 0.1%; Calcium aluminate cement, 5%. First premix the above solid powder in a vibrating ball mill tank, then add the mixed mixture into a planetary ball mill tank, and then add 40% water of the total weight of the above raw materials for wet mixing. The mixing time is 120 minutes, and the obtained slurry It is the coating of the present invention, and the construction method can be applied to the inner wall of the aluminum-magnesium-silicon green body sagger by brushing, spraying, dipping, etc., and the firing temperature ranges from 1200 to 1300.

Embodiment 2

[0019] Sagger anti-corrosion coating solid components and mass percentages are: MgCl 2 , 38.7%, TiO 2 , 40%; SiO 2 , 10%; Al 2 o 3 , 5%; Borax, 1%; FS20, 0.3%; Aluminum sol solution, 9%. First premix the above solid powder in a vibrating ball mill tank, then add the mixed mixture into a planetary ball mill tank, and then add 10% water of the total weight of the above raw materials for wet mixing. The mixing time is 240min, and the obtained slurry It is the coating of the present invention, and the construction method can be applied to the inner wall of the aluminum-magnesium-silicon green body sagger by brushing, spraying, dipping, etc., and the firing temperature range is 1250-1350.

Embodiment 3

[0021] Sagger anti-corrosion coating solid component and mass percentage are: BaSO 4 , 70%, TiO 2 , 20.2%; SiO 2 , 2.2%; Al 2 o 3 , 5.3%; Borax, 1.3%; T85, 0.2%; Carboxymethylcellulose, 0.3%. First premix the above solid powder in a vibrating ball mill tank, then add the mixed mixture into a planetary ball mill tank, and then add 30% water of the total weight of the above raw materials for wet mixing. The mixing time is 60 minutes, and the obtained slurry It is the coating of the present invention. The construction method can be applied to the inner wall of the aluminum-magnesium-silicon cooked sagger by brushing, spraying, dipping, etc., and the firing temperature ranges from 1300 to 1400.

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Abstract

The invention belongs to the technical field of saggers for synthesizing lithium battery cathode materials, and provides an anti-corrosion coating for an aluminum-magnesium-silicon sagger. The anti-corrosion coating for the aluminum-magnesium-silicon sagger is used for directly modifying the surface layer of the aluminum-magnesium-silicon sagger, so that the aluminum-magnesium-silicon sagger has an excellent anti-erosion tissue structure and chemical composition; the anti-corrosion coating comprises the following solid raw materials: 30-70% of alkaline earth metal salt; 20%-40% of TiO2; 2%-10%of SiO2; 5%-10% of Al2O3; 1%-5% of borax; 0.1%-0.3% of a dispersing agent; and 0.3%-10% of a binding agent. The anti-corrosion coating further comprises water, and the addition amount of the water is10-40% of the total weight of the solid raw materials. According to the coating, the surface of the aluminum-magnesium-silicon sagger is modified, so that the aluminum-magnesium-silicon sagger has excellent lithium corrosion resistant chemical composition and structure, meanwhile, the preparation process is simple, low-cost preparation can be realized, and the practical value is achieved.

Description

technical field [0001] The invention belongs to the technical field of saggers for synthesizing positive electrode materials of lithium batteries, and in particular relates to an anti-corrosion coating for aluminum-magnesium-silicon saggers. Background technique [0002] The sagger is widely used as a synthetic vessel for powder calcination or reaction. Its application scenarios are usually pusher kilns or roller kilns, and it has been used many times until it cracks or is severely eroded. Aluminum-magnesium-silicon saggers usually have good thermal shock resistance and can be used repeatedly without cracking. They are widely used in the field of lithium battery cathode material synthesis, but their disadvantage is poor corrosion resistance. Thereby the service life of sagger has reached the bottleneck. A prominent problem brought about is that the pollution of the synthesized positive electrode material is becoming more and more serious, which greatly restricts the rapid d...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B41/87
CPCC04B41/5027C04B41/5041C04B41/87C04B41/009C04B35/18C04B35/20C04B41/4535C04B41/5035C04B41/5031C04B41/5006C04B41/5007C04B41/0072C04B41/5012
Inventor 钱凡刘国齐王龙光李红霞杨文刚于建宾马渭奎
Owner SINOSTEEL LUOYANG INST OF REFRACTORIES RES
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