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A kind of preparation method and application of cement-based material additive

A technology for cement-based materials and additives, applied in chemical instruments and methods, calcium/strontium/barium compounds, inorganic chemistry, etc., can solve the problems of high cost, difficult hardening of liquid binders, and inability to put into practical engineering applications, etc. The effect of reducing dosage, improving engineering durability and service life, and improving mineralization efficiency

Active Publication Date: 2021-11-26
JIANGSU UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are many problems in the above methods. The liquid binder is difficult to harden in the water environment, the mineral additives must be encapsulated to avoid premature failure, and the ion complexing agent is harsh on the repair environment. Moreover, these methods are expensive and often cannot be put into practical engineering applications.

Method used

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  • A kind of preparation method and application of cement-based material additive
  • A kind of preparation method and application of cement-based material additive
  • A kind of preparation method and application of cement-based material additive

Examples

Experimental program
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Effect test

Embodiment 1

[0034] (1) Calcium chloride solution and sodium bicarbonate solution are prepared in equal quantities, and organic template sodium dodecylsulfonate is added to the calcium chloride solution and sodium bicarbonate solution respectively in an amount of 1 g / L, and magnetic particles are added. Ferriferric oxide, the addition amount is 1g / L, the calcium chloride solution is slowly added dropwise to the sodium bicarbonate solution, the reaction temperature is 30°C, after standing for 2 hours, use centrifugal separation, wash the sediment with ethanol solution, and dry it Promptly obtain porous calcium carbonate microspheres;

[0035] (2) Inoculate Bacillus lysinus into the culture medium, the mass ratio of inoculum to culture medium is 1:100, the culture medium is deionized water 1000mL, peptone 8g, beef extract 2g, NaCl 1g, FeCl 2 0.4g, shake culture at constant temperature for 48 hours, add manganese chloride, a high-efficiency spore transformation agent, to the culture medium, ...

Embodiment 2

[0039] (1) Calcium chloride solution and sodium bicarbonate solution are prepared in equal quantities, and organic template sodium dodecylsulfonate is added to the calcium chloride solution and sodium bicarbonate solution respectively, in an amount of 10g / L, and magnetic particles are added. Ferriferric oxide, the addition amount is 5g / L, the calcium chloride solution is slowly added dropwise to the sodium bicarbonate solution, the reaction temperature is 30°C, after standing for 2 hours, centrifugal separation is used, and the ethanol solution is used to wash the sediment, and after drying Promptly obtain porous calcium carbonate microspheres;

[0040](2) Inoculate Bacillus lysinus into the culture medium, the mass ratio of inoculum to culture medium is 2:100, the culture medium is deionized water 1000mL, peptone 12g, beef extract 3g, NaCl 5g, FeCl 2 0.6g, shake culture at constant temperature for 48 hours, add manganese chloride, a high-efficiency spore transformation agent...

Embodiment 3

[0044] (1) Calcium chloride solution and sodium bicarbonate solution in the amount of substances such as preparation, add organic template sodium dodecylsulfonate to calcium chloride solution and sodium bicarbonate solution respectively, the addition amount is 5g / L, add magnetic particles Ferriferric oxide, the addition amount is 2g / L, the calcium chloride solution is slowly added dropwise to the sodium bicarbonate solution, the reaction temperature is 30°C, after standing for 2 hours, the sediment is washed by centrifugation and ethanol solution, and dried Promptly obtain porous calcium carbonate microspheres;

[0045] (2) Inoculate Bacillus lysinus into the medium, the mass ratio of inoculum to medium is 1:100, the medium is deionized water 1000mL, peptone 10g, beef extract 2.5g, NaCl 2g, FeCl 2 0.5g, shake culture at constant temperature for 48 hours, add manganese chloride, a high-efficiency spore transformation agent, to the culture medium, and the addition amount is 2g / ...

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Abstract

The invention discloses a method for preparing a cement-based material additive and its application. Calcium chloride solution and sodium bicarbonate solution are prepared to produce porous calcium carbonate microspheres; Bacillus lysine is inoculated into the culture medium, Adding a high-efficiency spore transformation agent to the culture solution; putting the calcium carbonate microspheres into the spore culture solution of Bacillus lysinus, and fully standing until the concentration of the spore culture solution tends to be stable, so as to obtain calcium carbonate microspheres loaded with microbial spores; The calcium carbonate microspheres loaded with microbial spores are dissolved in a mixed solution of sodium alginate and barium silver, stirred evenly, and the surface coating of the calcium carbonate microspheres is realized by spray drying. The results show that the cement-based material additive prepared by this method is suitable for marine environment, can effectively fill and seal the cracks of cement-based materials, and improve engineering durability and service life.

Description

technical field [0001] The invention belongs to the field of cement material modification, and relates to a preparation method and application of a cement-based material additive. Background technique [0002] Marine development requires the construction of a large number of marine or coastal projects. However, the relatively low tensile strength makes cement-based materials inevitably crack under the action of internal and external factors, and seawater contains Cl - , SO 4 2- and Mg 2+ After plasma intrusion reacts with cement hydration products, it will cause different degrees of erosion and damage to engineering structures, resulting in continuous degradation of cement-based materials, seriously affecting the durability and service life of buildings. Therefore, how to repair the cracks of cement-based materials in a timely and effective manner is one of the problems that need to be solved urgently to ensure the long-term safe operation of marine construction projects...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B20/12C04B14/28C01F11/18
CPCC01F11/18C01F11/185C04B14/28C04B20/12C04B20/1018C04B20/1048C04B20/107
Inventor 詹其伟张爽爽冯蕾李涛刘仁杰尤俊齐
Owner JIANGSU UNIV OF SCI & TECH
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