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Imidazoline derivatives as well as synthesis method and application thereof

A technology of imidazoline derivatives and synthesis methods, applied in chemical instruments and methods, water/sludge/sewage treatment, organic chemistry, etc., can solve the problem of increased concentration of corrosion inhibitors and difficulty in compatibility with various environmental conditions , increase the cost of oilfield sewage treatment and other issues

Inactive Publication Date: 2020-09-29
SOUTHWEST PETROLEUM UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] At present, the main problems of commercial corrosion inhibitors for oilfield sewage treatment: 1) High corrosion rate
At present, most of the corrosion inhibitors actually used in existing oil fields are difficult to meet this requirement.
2) It is difficult to meet the requirements of different oil fields
3) The price of corrosion inhibitor is higher
In order to meet the requirements of corrosion rate and corrosion inhibition rate, the concentration of some corrosion inhibitors is increased, which greatly increases the cost of oilfield sewage treatment.
4) Some corrosion inhibitors contain substances harmful to the environment, which are likely to cause environmental pollution problems and do not meet the sustainable development concept of green environmental protection
[0009] 2. In order to ensure the high efficiency of corrosion inhibitors under certain conditions, they often have specificity, which makes it difficult to be compatible with many different environmental conditions

Method used

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  • Imidazoline derivatives as well as synthesis method and application thereof
  • Imidazoline derivatives as well as synthesis method and application thereof
  • Imidazoline derivatives as well as synthesis method and application thereof

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preparation example Construction

[0040] Such as figure 1 As shown, the synthetic method of the imidazoline derivative provided by the embodiment of the present invention comprises the following steps:

[0041] S101: Synthesis of imidazoline intermediates. Heat oleic acid to 160°C in a reaction vessel, add triethylenetetramine and xylene at a molar ratio of 1:1.2:1.2, and perform amidation reaction for three hours; raise the temperature to 230°C, and perform dehydration and cyclization for three hours (using a few minutes during the period) The water device separates the xylene and water), and cools to room temperature to obtain the imidazoline intermediate.

[0042] S102: Synthesis of imidazoline derivatives. Add the imidazoline intermediate to the reaction vessel and raise the temperature to 95°C, add acetophenone, drop hydrochloric acid into the formaldehyde, add the intermediate and acetophenone to the reaction system; react at 95°C for 5 hours to obtain Dark reddish brown viscous imidazoline derivativ...

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PUM

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Abstract

The invention belongs to the technical field of derivative synthesis, and discloses imidazoline derivatives, a synthesis method and application thereof, and synthesis of an imidazoline intermediate. By selecting an appropriate organic acid initiator, different R1 alkyl structures are determined; the basic structural characteristics of the five-membered ring imidazoline are determined by selectingpolyethylene polyamine; the synthesis of the imidazoline derivatives comprises selecting a group with a certain structure to form a hydrophilic group R2. According to the synthesis method of imidazoline derivatives with different structures, especially novel monocyclic imidazoline and polycyclic imidazoline molecules, 5-8 molecular structures of the novel imidazoline derivatives are expected to becompleted, and innovation of cyclization, modification, coupling and other synthesis methods of the imidazoline derivative is achieved. The understanding of the corrosion inhibition mechanism is further deepened through the understanding of synergistic effects of corrosion inhibitor monomers and the synergistic rule. According to the molecular structures, a synergistic effect is deeply researchedfrom interface adsorption kinetics, a synergistic rule is discovered, and compounding technology innovation is realized.

Description

technical field [0001] The invention belongs to the technical field of derivative synthesis, and relates to an imidazoline derivative, a synthesis method and an application thereof. Background technique [0002] At present, my country's oil and gas field development process treats more than 1 billion cubic meters of oilfield sewage every year. Some of the water produced by these oil wells will be re-injected into the formation after sewage treatment. Oilfield sewage contains mineral salts, dissolved gas (CO 2 , H 2 S, O 2 etc.), microorganisms (iron bacteria, sulfate reducing bacteria, saprophytic bacteria, etc.) Oilfield sewage is generally purified and reinjected through equipment such as oil skimmers, filters, booster pumps, and water injection pumps. During these processes, pipelines and equipment are often corroded, seriously affecting the normal production of oil and gas, and causing huge economic losses. In the current sewage treatment process, a certain amount o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07D233/16C23F11/14C02F5/12
CPCC02F5/12C07D233/16C23F11/149
Inventor 冷曼希王新评郑性能叶正荣鲁兴宇傅伟强冉飞王浩祺随明明
Owner SOUTHWEST PETROLEUM UNIV
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